A process and device for gypsum calcination in conjunction with co-coupled carbon thermal reduction

A gypsum and calcination technology, which is applied in the process and device field of gypsum calcination and CO coupled carbon-thermal reduction, can solve problems such as ecological environment and human health impact, waste of sulfur resources, etc. Sex-enhancing effect

Active Publication Date: 2021-12-17
SHANDONG UNIV
View PDF0 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] SO in current flue gas 2 Emissions (acid rain, PM2.5) have a serious impact on the ecological environment and human health, and at the same time cause a serious waste of sulfur resources

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A process and device for gypsum calcination in conjunction with co-coupled carbon thermal reduction

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] A process and device for gypsum calcination coordinated with CO coupled carbon thermal reduction, mainly including:

[0057] The gypsum is stored in the gypsum bin, and the feeding amount is precisely controlled by the feeder to be transported to the gypsum preheater for preheating and drying. The high-temperature heat source comes from the calcination flue gas discharged from the gypsum calcination section; the temperature of the gypsum after preheating and drying is 600- 1050°C, first enter the upper part of the gypsum calcining section, which is divided into upper and lower layers. During the last gypsum calcining process, it entered the lower part of the gypsum calcining section through the overflow pipe for secondary calcination to ensure sufficient solid residence time to obtain higher quicklime Yield, the temperature of the gypsum calcination section is 700-1200°C; the quicklime product produced by calcination is cooled to 20-50°C and stored in the quicklime stora...

Embodiment 2

[0059] A system for gypsum calcination coordinated with CO coupled carbon thermal reduction, including: calcination furnace, gypsum bin 1, gypsum preheater 2, carbon material bin 8, reheater 10, high-temperature filter 11, sulfur recovery device 12, quicklime storage Bin 14; the calciner is divided into SO from top to bottom 2 Reduction section 3, gypsum calcining section 4, external heat source 5, coke gasification section 6 and gas mixing section 7; the feed port of the gypsum calcining section 4 is connected to the gypsum preheater 2 and the gypsum bin 1 in sequence, and the gypsum The discharge port of the calcining section 4 is connected with the quicklime storage bin 14; the SO 2 The reduction section 3 is connected with the carbon material warehouse 8, and the SO 2 Reduction section 3 is also connected with high temperature separator 1, reheater 10, high temperature filter 11 and sulfur recovery device 12 in sequence; said reheater 10 is also connected with the air inl...

Embodiment 3

[0061]A system for gypsum calcination coordinated with CO coupled carbon thermal reduction, including: calcination furnace, gypsum bin 1, gypsum preheater 2, carbon material bin 8, reheater 10, high-temperature filter 11, sulfur recovery device 12, quicklime storage Bin 14; the calciner is divided into SO from top to bottom 2 Reduction section 3, gypsum calcining section 4, external heat source 5, coke gasification section 6 and gas mixing section 7; the feed port of the gypsum calcining section 4 is connected to the gypsum preheater 2 and the gypsum bin 1 in sequence, and the gypsum The discharge port of the calcining section 4 is connected with the quicklime storage bin 14; the SO 2 The reduction section 3 is connected with the carbon material warehouse 8, and the SO 2 Reduction section 3 is also connected with high temperature separator 1, reheater 10, high temperature filter 11 and sulfur recovery device 12 in sequence; said reheater 10 is also connected with the air inle...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
Login to view more

Abstract

The invention relates to a process and device for gypsum calcination coordinated with CO coupled carbon thermal reduction. Circulating exhaust gas contains high concentration of CO 2 , react with coke to generate CO, part of CO is used to reduce gypsum and SO 2 , the other part is used for supplementary heat in the gypsum reduction and calcination process; after calcination, the flue gas contains high concentration of SO 2 ; Calcined flue gas reacts in the temperature range of 600-1000°C to generate elemental sulfur vapor under the catalysis of activated carbon materials. Sulfur is recovered after the elemental sulfur vapor is cooled and dedusted. Part of the reduced exhaust gas after sulfur recovery enters the flue gas purification system for purification and then is emptied, and the other part is returned to the system as circulating exhaust gas to provide high-concentration CO for the system. 2 . The circulating exhaust gas in the system is preheated by reducing the temperature of the reducing gas. The oxygen-enriched oxygen supplemented by the gypsum reduction and calcination process is preheated by cooling the calcined product quicklime and exothermic. The gypsum is dried and preheated by the calcination flue gas. This system realizes the energy level Utilization; in order to achieve the heat balance of the system, an external heat source is needed to supplement the heat of the system.

Description

technical field [0001] The invention belongs to the field of resource utilization of solid waste, and in particular relates to a process and a device for gypsum calcining in cooperation with CO coupled carbon thermal reduction. Background technique [0002] The information disclosed in this background section is only intended to increase the understanding of the general background of the present invention, and is not necessarily taken as an acknowledgment or any form of suggestion that the information constitutes the prior art already known to those skilled in the art. [0003] At present, the production of industrial by-product gypsum in my country is about 118 million tons, and the comprehensive utilization rate is only 38%. Among them, desulfurization gypsum is about 43 million tons, with a comprehensive utilization rate of about 56%; phosphogypsum is about 50 million tons, with a comprehensive utilization rate of about 20%; other by-product gypsum is about 25 million ton...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): C01B17/02C04B2/10
CPCC01B17/0264C04B2/10C04B2/106Y02P20/129
Inventor 马春元夏霄张立强崔琳赵希强李军
Owner SHANDONG UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap