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Rapid detection method for hexavalent chromium in water environment based on machine learning

A technology of machine learning and detection methods, applied in machine learning, material analysis through observation of the influence of chemical indicators, instruments, etc., can solve the problems of inconvenient real-time monitoring and expensive instruments, and achieve simple detection, strong practicability, The effect of improving detection efficiency

Inactive Publication Date: 2020-09-18
FUZHOU UNIV
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  • Claims
  • Application Information

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Problems solved by technology

[0003] Traditional methods for detecting hexavalent chromium include: flow injection spectrometry, fluorescence spectrometry, atomic absorption spectrometry, etc. These methods have the characteristics of high sensitivity and good reproducibility, but due to factors such as expensive instruments and the need for professionals to operate, they are not Facilitate on-site real-time monitoring

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  • Rapid detection method for hexavalent chromium in water environment based on machine learning
  • Rapid detection method for hexavalent chromium in water environment based on machine learning
  • Rapid detection method for hexavalent chromium in water environment based on machine learning

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Embodiment Construction

[0034] The present invention will be further described in detail below in conjunction with the accompanying drawings and specific embodiments.

[0035] The invention provides a machine learning based Cr in water environment 6+ rapid detection methods such as figure 1 shown, including the following steps:

[0036] (1) In acidic medium, configure a series of concentration gradients of Cr 6+ standard solution.

[0037] In this embodiment, the acidic medium is dilute hydrochloric acid, pH=2.

[0038] (2) Prepare the DPCI solution with diphenylcarbazide (DPCI) as the chromogen.

[0039] In this embodiment, DPCI is dissolved in absolute ethanol to obtain a DPCI solution, that is, a developer solution. In the DPCI solution, the mass volume concentration of DPCI is 1.7% (that is, 1.7g is dissolved in 100 mL of absolute ethanol).

[0040] (3) Cr from the series of concentration gradients 6+ The standard solution selects multiple groups of Cr 6+ The solution was reacted with the...

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Abstract

The invention relates to a method for quickly detecting Cr < 6 + > in a water environment based on machine learning. The method comprises the steps of preparing a series of Cr < 6 + > standard solutions with concentration gradients in an acid medium; preparing a DPCI solution by taking DPCI as a color developing agent; selecting a plurality of groups of Cr < 6 + > solutions from the Cr < 6 + > standard solution to respectively react with the DPCI solution, measuring the absorbance, and determining the linear range of color development; preparing Cr < 6 + > solutions with corresponding concentrations on the basis of the obtained linear ranges, subjecting all the solutions to color development reaction with the DPCI solution, and after color development is stable, placing the solutions in adark box to take a plurality of pictures; based on the obtained pictures, obtaining multiple types of picture sample sets corresponding to the concentrations so as to establish a regression model forprediction; and based on the established regression model, carrying out Cr < 6 + > concentration detection on a to-be-detected sample solution. The method is beneficial to simply and quickly detecting the concentration of Cr < 6 + > in an unknown sample solution.

Description

technical field [0001] The invention belongs to the field of environmental detection, in particular to a machine learning-based detection of Cr in a water environment 6+ rapid detection method. Background technique [0002] Industrial pollution is mostly discharged into the environment through waste residue, waste water, and waste gas. Hexavalent chromium in the water environment will be continuously enriched through the food chain and eventually enter the body of humans and animals, thereby causing great harm to the environment and human health. Many studies have confirmed that hexavalent chromium compounds are toxic, carcinogenic and induce gene mutation. Chromium compounds can damage the synthesis of deoxyribonucleic acid, among which potassium dichromate is particularly prominent. Chromium compounds also have carcinogenic, mutagenic and cytogenetic effects. Toxicity; hexavalent chromium can precipitate certain proteins in human blood, causing anemia, nephritis, neuritis...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N21/31G01N21/78G06F17/18G06N20/00
CPCG01N21/31G01N21/78G06N20/00G06F17/18
Inventor 罗芳付琪林振宇郭隆华邱彬
Owner FUZHOU UNIV