Pretreatment method for high-calcium and high-magnesium fine-grained disseminated scheelite

A scheelite and pretreatment technology, applied in solid separation, recycling technology, mechanical material recovery, etc., can solve the problems of waste of rare metal resources, large loss of scheelite, low recovery rate, etc. dosage, improving beneficiation efficiency and reducing the amount of ore

Active Publication Date: 2020-09-29
INST OF RESOURCES UTILIZATION & RARE EARTH DEV GUANGDONG ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the method of full flotation after removing magnetic minerals by magnetic separation, due to the agglomeration of minerals and the influence of high-calcium-magnesium-rich gangue minerals, leads to a large loss of scheelite in tailings, low recovery rate, and poor effect. , the obtained scheelite concentrate contains WO 3 less than 20%
[0006] Based on the above reasons, the magnesia skarn-type scheelite, which is high-calcium and high-magnesium fine-grained scheelite, has not been developed and utilized at present, resulting in a waste of rare metal resources.

Method used

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  • Pretreatment method for high-calcium and high-magnesium fine-grained disseminated scheelite
  • Pretreatment method for high-calcium and high-magnesium fine-grained disseminated scheelite

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Effect test

Embodiment 1

[0029] Pretreatment of scheelite ore, the composition of scheelite ore is: 0.155% WO 3 , 30% CaCO 3 , 15% MgO, refer to figure 1 , preprocess as follows:

[0030] The first stage of grinding: Add 100 g / ton of sodium hexametaphosphate to the raw scheelite ore (that is, add 100 grams of sodium hexametaphosphate per ton of scheelite ore), and prepare sodium hexametaphosphate into an aqueous solution For adding, the mass percent concentration of the sodium hexametaphosphate aqueous solution is 1%. Then the slurry is adjusted to a mass concentration of 62.5%, and the ore is ground to a scheelite monomer dissociation degree of 70%.

[0031] The first gravity separation and classification: adjust the pulp concentration after grinding to 23.5% of the mass concentration, carry out gravity separation and classification in the spiral chute, and obtain spiral concentrate, spiral medium ore and spiral tailings; the spiral concentrate has a high content of scheelite, and the spiral Tailin...

Embodiment 2

[0039] Pretreatment of scheelite ore, the composition of scheelite ore is: 0.447% WO 3 , 35% CaCO 3 , 28% MgO, refer to figure 1 , preprocess as follows:

[0040] The first stage of grinding: Add 800 g / ton of sodium hexametaphosphate to raw scheelite ore (that is, add 800 grams of sodium hexametaphosphate per ton of scheelite ore), and add sodium hexametaphosphate into an aqueous solution. The mass percent concentration of the sodium phosphate aqueous solution is 0.5%. Then the slurry is adjusted to a mass concentration of 67.5%, and the ore is ground to a scheelite monomer dissociation degree of 78%.

[0041] The first gravity separation and classification: adjust the pulp concentration after grinding to a mass concentration of 28.5%, carry out spiral chute gravity separation and classification to obtain spiral concentrate, spiral medium ore and spiral tailings; spiral concentrate has high scheelite content, spiral Tailings are mainly gangue minerals.

[0042] The second...

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Abstract

The invention belongs to the technical field of mineral treatment, and particularly discloses a method for pretreating high-calcium and high-magnesium fine-grained disseminated scheelite. The method comprises the steps: raw scheelite is subjected to two times of gravity-separation classification after being subjected to primary grinding, primary concentrating and secondary concentrating are combined for secondary grinding, and then magnetic-separation treatment is conducted; secondary tailings are de-slimed to obtain a spillover flow, the spillover flow, fine slime and primary tailings are enriched, and fine slime concentrate is obtained; the fine slime concentrate enters into magnetic-separation treatment; and ore pulp of secondary grinding and the fine slime concentrate are combined to be subjected to magnetic-separation treatment, and pretreated concentrate is obtained. According to the pretreatment method, the technical problem that the high-calcium and high-magnesium slime is agglomerated, and consequently the fine-grained disseminated scheelite is difficult to recover is solved, most gangue minerals and slime are abandoned through pretreatment, the amount of ore entering intosubsequent scheelite flotation is decreased, the beneficiation feed grade of WO3 in the flotation ore is increased, and the using quantity of a reagent during subsequent flotation is greatly decreased.

Description

technical field [0001] The invention relates to the technical field of mineral treatment, in particular to a pretreatment method for high-calcium and high-magnesium fine-grained scheelite. Background technique [0002] Tungsten is mainly used in the manufacture of various alloy steels. It is an essential element in the production of gun barrels, high-temperature alloys for engines, rocket nozzles, armor-piercing projectiles, electromagnetic guns, etc. It is known as the "King of War Metals" and is an important strategic mineral for the country. resource. my country is rich in tungsten resources, but after years of over-exploitation, the easy-to-mining wolframite resources are close to exhaustion, and scheelite, which accounts for 70% of the country's tungsten resources, has large reserves, but 85% of the resources are due to low grade and particle size. Fine and high recycling cost, so it is difficult to develop and utilize. [0003] Magnesia skarn-type scheelite has the ch...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B03B9/00B03B1/00B03B1/04B03B9/06
CPCB03B9/00B03B1/00B03B1/04B03B9/06Y02W30/52
Inventor 邓丽红周晓彤付广钦关通尚兴科
Owner INST OF RESOURCES UTILIZATION & RARE EARTH DEV GUANGDONG ACAD OF SCI
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