Tristyrylphenol polyoxyethylene ether sulfonate and pesticide suspension concentrate

A technology of polyoxyethylene ether sulfonate and triphenylethylphenol, which is applied in biocides, animal repellents, plant growth regulators, etc., can solve the problem of poor dispersion performance, insufficient performance, and layered structure of pesticide suspensions. It can solve the problems of bottom and other problems, and achieve the effects of excellent anionic and non-ionic performance, improved utilization rate, good emulsification and dispersibility

Pending Publication Date: 2020-11-24
南京太化化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The performance of tristyryl phenol polyoxyethylene ether is insufficient, and the pesticide suspending agent added with tri...

Method used

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  • Tristyrylphenol polyoxyethylene ether sulfonate and pesticide suspension concentrate
  • Tristyrylphenol polyoxyethylene ether sulfonate and pesticide suspension concentrate
  • Tristyrylphenol polyoxyethylene ether sulfonate and pesticide suspension concentrate

Examples

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preparation example Construction

[0034] The preparation method of described tristyrylphenol polyoxyethylene ether sulfonate comprises the following steps:

[0035] (1) Add potassium hydroxide to triphenylethylphenol, vacuum treatment at 130-140°C for 1-2h, raise the temperature to 150-160°C, and continuously add ethylene oxide under the pressure of 0.25-0.3MPa, and the feeding is finished Then continue the aging reaction until the pressure in the system is negative pressure and the pressure is no longer reduced, and the reactant is obtained. (2) The reactant is cooled to 110-130°C, and propylene oxide is continuously added under the pressure of 0.25-0.3MPa, and then After the material is finished, continue the aging reaction until the pressure in the system is negative pressure and the pressure is no longer reduced, and the secondary reactant is obtained. (3) The temperature of the secondary reactant is raised to 150-160 ° C, and the pressure is continued under the pressure of 0.25-0.3MPa. Add ethylene oxide,...

Embodiment 1

[0042] (1) Add 0.4 potassium hydroxide to 406 triphenylethylphenol, vacuum treatment at 130°C for 1 hour, heat up to 160°C, and continuously add 220g of ethylene oxide under a pressure of 0.25MPa, and continue the aging reaction after the feeding is completed, Until the pressure in the system is a negative pressure and the pressure is no longer reduced, the reactant is obtained. (2) The reactant is cooled to 120°C, and 580g of propylene oxide is continuously added under a pressure of 0.3MPa. After the feeding is completed, the aging reaction is continued until The pressure in the system is a negative pressure and the pressure is no longer reduced, and the secondary reactant is obtained. (3) The temperature of the secondary reactant is raised to 160°C, and 220g of ethylene oxide is continuously added under a pressure of 0.25MPa. After the feeding is completed, continue Aging reaction, until the pressure in the system is negative pressure and the pressure no longer decreases, coo...

Embodiment 2

[0044] (1) Add 0.4g of potassium hydroxide to 406g of triphenylethylphenol, vacuum treatment at 130°C for 1.5h, heat up to 160°C, and continue to add 330g of ethylene oxide under a pressure of 0.25MPa, and continue to age after feeding Reaction, until the pressure in the system is negative pressure and the pressure is no longer reduced, the reactant is obtained, (2) the product is cooled to 120°C, and 290g of propylene oxide is continuously added under the pressure of 0.3MPa, and the aging reaction is continued after the feeding is completed. Until the pressure in the system is negative pressure and the pressure is no longer reduced, the secondary reactant is obtained. (3) The temperature of the secondary reactant is raised to 160 ° C, and 330 g of ethylene oxide is continuously added under a pressure of 0.25 MPa. Continue the aging reaction until the pressure in the system is negative pressure and the pressure does not decrease any more, cool down to obtain the product, (4) ta...

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Abstract

The invention discloses tristyrylphenol polyoxyethylene ether sulfonate. A preparation method of the tristyrylphenol polyoxyethylene ether sulfonate comprises the following steps: (1) adding potassiumhydroxide into triphenylethyl phenol, and carrying out a high-temperature continuous aging reaction to obtain a reactant; (2) adding epoxypropane into the reactant for continuous aging reaction to obtain a secondary reactant; (3) adding ethylene oxide into the secondary reactant for continuous aging reaction to obtain a product; and (4) adding sulfamic acid into the product, adding a catalyst urea or dodecylbenzene sulfonic acid, and adding a sodium sulfite saturated solution after reaction so as to obtain the tristyrylphenol polyoxyethylene ether sulfonate. The invention also discloses an application of the tristyrylphenol polyoxyethylene ether sulfonate. A pesticide suspension concentrate comprises the following raw materials: 48% of clothianidin, 5% of the tristyrylphenol polyoxyethylene ether sulfonate, 1% of fatty alcohol-polyoxyethylene ether, 0.5% of magnesium aluminum silicate, 0.02% of xanthan gum, 0.1% of sodium benzoate and 45.38% of water.

Description

technical field [0001] The invention relates to the technical field of pesticide manufacture, in particular to a triphenylethylphenol polyoxyethylene ether sulfonate and a pesticide water suspension. Background technique [0002] Among pesticide adjuvants, tristyrylphenol polyoxyethylene ether nonionic surfactant prepared by ethoxylation of tristyrylphenol and ethylene oxide is widely used, but because tristyrylphenol polyoxyethylene The performance of ether is insufficient. At present, the pesticide suspending agent added with tristyryl phenol polyoxyethylene ether on the market has the problems of low suspension rate, poor dispersion performance, and prone to stratification and bottoming after long-term storage. Contents of the invention [0003] The technical problem to be solved by this invention is: [0004] The performance of tristyryl phenol polyoxyethylene ether is insufficient, and the pesticide suspending agent added with tristyryl phenol polyoxyethylene ether h...

Claims

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Application Information

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IPC IPC(8): C08G65/28C08G65/326A01N25/04A01N25/30A01N51/00
CPCC08G65/2612C08G65/326A01N25/04A01N25/30A01N51/00
Inventor 刘艳秋李燕文钱立天
Owner 南京太化化工有限公司
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