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A kind of wear-resistant and aging-resistant polyurethane resin and preparation method thereof

A polyurethane resin and anti-aging technology, which is applied in the field of polyurethane and its production equipment, can solve the problems of low corrosion resistance, wear resistance, high temperature resistance, poor aging resistance, and poor wear resistance of polyurethane resin, etc., and achieve aging-resistant yellow High variable grade, good aging resistance, good hydrolysis resistance

Active Publication Date: 2022-01-11
JIAXING HEXIN CHEM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But existing nitrogen filling device has the following problems: 1, when using, it is inconvenient to fix it, so that when using, because of shaking, normal use is affected; 2, when using, there is no When the amount of nitrogen in the nitrogen bottle is insufficient, the device needs to be stopped for replacement before it can continue to be used
However, the existing high-viscosity pumps have the following problems: 1. The existing high-viscosity pumps are too complicated to be disassembled as a whole, which is not convenient for transportation and quick maintenance, and reduces the overall use efficiency; 2. The existing high-viscosity pumps High-viscosity pumps have low overall corrosion resistance, wear resistance and high temperature resistance, so they are prone to damage and reduce the overall service life
[0011] 1. The wear resistance of polyurethane resin is poor, and it is easy to scratch after being made into leather; the aging resistance is poor, especially under the condition of ultraviolet light (sunlight), it is easy to produce yellowing and yellowing;
[0012] 2. The production reaction system of polyurethane resin lacks small and medium-sized continuous production equipment, and cannot well combine mixing, feeding, prepolymerization, polymerization, discharging and storage to form a complete continuous polyurethane production equipment;
[0013]3. The above-mentioned defects still exist in the links of mixing, feeding, prepolymerization, polymerization, discharging and storage of polyurethane production equipment, which cannot satisfy the requirements of polyurethane The production requirements cannot guarantee the quality of the produced polyurethane

Method used

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  • A kind of wear-resistant and aging-resistant polyurethane resin and preparation method thereof
  • A kind of wear-resistant and aging-resistant polyurethane resin and preparation method thereof
  • A kind of wear-resistant and aging-resistant polyurethane resin and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0106] A wear-resistant and aging-resistant polyurethane resin, made of the following raw materials in parts by weight: 1,6-hexanediol polyadipate diol: 10-15 parts, polycarbonate diol: 12-18 parts , 1,6-hexanediol: 3-5 parts, trimethylolpropane: 2-4 parts, hexamethylene diisocyanate: 8-10 parts, antioxidant: 0.35-0.55 parts, organic bismuth catalyst: 0.15 to 0.25 parts, isophorone diamine: 0.5 to 0.8 parts, KH-560: 0.15 to 0.25 parts, solvent: 45 to 75 parts; the hexamethylene diisocyanate is DesmodurN 3300A from Bayer Germany and Germany The mixture of Bayer's Desmodur BL3175A has a mass ratio of 1:1.8-2.1; the solvent is a mixture of dimethylformamide and acetone, and the mass ratio of the two is 1:2-4.

[0107] The present invention also provides a method for preparing the wear-resistant and aging-resistant polyurethane resin, which uses a reaction system for polyurethane production to carry out continuous production and preparation, including the following steps:

[0108...

Embodiment 2

[0116] A wear-resistant and aging-resistant polyurethane resin, made of the following raw materials in parts by weight: 1,6-hexanediol polyadipate diol: 10 parts, polycarbonate diol: 12 parts, 1,6 - Hexylene glycol: 3 parts, trimethylolpropane: 2 parts, hexamethylene diisocyanate: 8 parts, antioxidant: 0.35 parts, organic bismuth catalyst: 0.15 parts, isophorone diamine: 0.5 parts , KH-560: 0.15 parts, solvent: 45 parts; the hexamethylene diisocyanate is a mixture of DesmodurN 3300A of Bayer Germany and Desmodur BL3175A of Bayer Germany, and the mass ratio of the two is 1:1.8; The solvent is a mixture of dimethylformamide and acetone, and the mass ratio of the two is 1:2.

[0117] In this embodiment, the preparation method of the wear-resistant and aging-resistant polyurethane resin adopts a reaction system for polyurethane production for continuous production and preparation, including the following steps:

[0118] 1) each raw material of the wear-resistant and aging-resista...

Embodiment 3

[0166] The difference from Example 2 is that a wear-resistant and aging-resistant polyurethane resin is made of the following raw materials in parts by weight: poly-1,6-hexanediol adipate diol: 15 parts, polycarbonate binary Alcohol: 18 parts, 1,6-hexanediol: 5 parts, trimethylolpropane: 4 parts, hexamethylene diisocyanate: 10 parts, antioxidant: 0.55 parts, organic bismuth catalyst: 0.25 parts, iso Phornediamine: 0.8 parts, KH-560: 0.25 parts, solvent: 75 parts; the hexamethylene diisocyanate is a mixture of Desmodur N3300A of Bayer Germany and Desmodur BL3175A of Bayer Germany, the mass ratio of the two 1:2.1; the solvent is a mixture of dimethylformamide and acetone, and the mass ratio of the two is 1:4.

[0167] In this embodiment, the preparation method of the wear-resistant and aging-resistant polyurethane resin adopts a reaction system for polyurethane production for continuous production and preparation, including the following steps:

[0168] 1) each raw material of ...

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Abstract

The invention discloses a wear-resistant and aging-resistant polyurethane resin, which is made of the following raw materials in parts by weight: 1,6-hexanediol polyadipate diol: 10-15 parts, polycarbonate diol: 12-18 parts, 1,6-hexanediol: 3-5 parts, trimethylolpropane: 2-4 parts, hexamethylene diisocyanate: 8-10 parts, antioxidant: 0.35-0.55 parts, Organic bismuth catalyst: 0.15-0.25 parts, isophorone diamine: 0.5-0.8 parts, KH‑560: 0.15-0.25 parts, solvent: 45-75 parts. The wear-resistant and aging-resistant polyurethane resin of the present invention has the advantages of good wear resistance; high aging-resistant yellowing series, good aging resistance; and good hydrolysis resistance; the wear-resistant and aging-resistant polyurethane resin of the present invention can be directly used Coated on textile fabrics or non-woven fabrics, the coated textile fabrics or non-woven fabrics also have good wear resistance; high aging resistance to yellowing, good aging resistance; and good hydrolysis resistance, etc. .

Description

technical field [0001] The invention relates to the technical field of polyurethane and its production equipment, in particular to a wear-resistant and aging-resistant polyurethane resin and a preparation method thereof. Background technique [0002] The full name of polyurethane is polyurethane, a polymer compound. Polyurethane has two types: polyester type and polyether type. They can be made into polyurethane plastics (mainly foam plastics), polyurethane fibers (called spandex in China ), polyurethane rubber and elastomers. [0003] The main raw materials of polyurethane include diphenylmethane diisocyanate (MDI), toluene diisocyanate (TDI), and polypropylene glycol (PPG), all of which have become international commodities. The production technology and equipment of these raw materials are very complicated. [0004] Polyurethane resin is generally formed by the reaction of polyisocyanate and polyol containing active hydrogen atoms and groups. The reaction between the tw...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G18/66C08G18/42C08G18/44C08G18/32C08G18/12C08G18/08C08K5/5435
CPCC08G18/6651C08G18/4238C08G18/44C08G18/3206C08G18/12C08G18/08C08K5/5435C08G18/3234
Inventor 纪尚超石磊陈晓春陈海龙赵磊王伟晏雪生
Owner JIAXING HEXIN CHEM IND