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Heat-resistant environment-friendly flame-retardant cable insulation material and preparation method thereof

A technology for flame retardant cables and insulating materials, applied in the field of cables, can solve the problems that polyolefin materials are difficult to have high flame retardant level, high cost, high cost of irradiation equipment, and achieve excellent processing performance and mechanical properties, low cost, The effect of superior heat resistance and flame retardant properties

Inactive Publication Date: 2020-12-29
TEBIAN ELECTRIC APP CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the extrusion speed of irradiated cross-linked polyolefin materials is slow, and the production efficiency is not high, and after the wire is made, it needs to be irradiated to reach the 125°C level, the process is complicated, and the cost of irradiation equipment is high; Silane-crosslinked polyolefin materials need to be divided into two steps to achieve crosslinking. The process is relatively complicated. The cable insulation material needs to be extruded separately to make materials, and then mixed when producing wires and cables. The produced cables must be boiled or steamed. cross-linking reaction
In short, the use process of cross-linked cable insulation materials is complicated and the cost is high. It is difficult to recycle the material after cross-linking. In addition, it is difficult to make cross-linked polyolefin materials into high flame-retardant grades.

Method used

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  • Heat-resistant environment-friendly flame-retardant cable insulation material and preparation method thereof
  • Heat-resistant environment-friendly flame-retardant cable insulation material and preparation method thereof
  • Heat-resistant environment-friendly flame-retardant cable insulation material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] This embodiment provides a heat-resistant, environmentally friendly and flame-retardant cable insulation material, the formula raw materials of which include:

[0045] polyvinyl chloride resin,

[0046] heat-resistant plasticizer,

[0047] flame retardant,

[0048] Heat stabilizers,

[0049] filler,

[0050] Antioxidant,

[0051] Processing aids,

[0052] lubricant,

[0053] Colorant,

[0054] Wherein, the heat-resistant plasticizer includes: trioctyl trimellitate (TOTM) and / or tridecyl trimellitate.

[0055] This embodiment also provides a method for preparing the above-mentioned heat-resistant and environmentally friendly flame-retardant cable insulation material, which includes the following steps:

[0056] Add the above-mentioned formula raw materials of heat-resistant, environmentally friendly and flame-retardant cable insulation materials into the mixer and mix them, and discharge them at 110-125°C; carry out extrusion and mastication through a twin-screw ...

Embodiment 2

[0059] This embodiment provides a heat-resistant, environmentally friendly and flame-retardant cable insulation material, the weight ratio of the formula raw materials is as follows:

[0060]

[0061]

[0062] It should be noted that the polyvinyl chloride resin in this embodiment is a suspension-process polyvinyl chloride resin, a mixture of polyvinyl chloride resins with a degree of polymerization of 2500 and 2000, and the weight ratio of the two is 50:50.

[0063] It should be noted that the heat-resistant plasticizer in this embodiment is a mixture of trioctyl trimellitate, tridecyl trimellitate, and epoxy soybean oil, and the weight ratio of the three is 20:25:4 .

[0064] It should be noted that the flame retardant in this embodiment is a mixture of antimony trioxide, zinc borate, and magnesium hydroxide, and the weight ratio of the three is 8:8:10.

[0065]It should be noted that the heat stabilizer in this example is an organic calcium-zinc composite stabilizer....

Embodiment 3

[0088] This embodiment provides a heat-resistant, environmentally friendly and flame-retardant cable insulation material, the weight ratio of the formula raw materials is as follows:

[0089]

[0090] It should be noted that the polyvinyl chloride resin in this embodiment is a suspension polyvinyl chloride resin, a mixture of polyvinyl chloride resins with a degree of polymerization of 2500 and 2000, and the weight ratio of the two is 40:60.

[0091] It should be noted that the heat-resistant plasticizer in this embodiment is a mixture of trioctyl trimellitate, tridecyl trimellitate, and epoxy soybean oil, and the weight ratio of the three is 15:30:4 .

[0092] It should be noted that the flame retardant in this embodiment is a mixture of antimony trioxide, zinc aluminate, and aluminum hydroxide, and the weight ratio of the three is 6:6:15.

[0093] It should be noted that the heat stabilizer in this example is an organic calcium-zinc composite stabilizer.

[0094] It sho...

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Abstract

The invention discloses a heat-resistant environment-friendly flame-retardant cable insulation material and a preparation method thereof. The heat-resistant environment-friendly flame-retardant cableinsulation material is prepared from polyvinyl chloride resin, a heat-resistant plasticizer, a flame retardant, a heat stabilizer, a filler, an antioxidant, a processing aid, a lubricant and a coloring agent, and the heat-resistant plasticizer comprises trioctyl trimellitate and / or tridecyl trimellitate. The cable insulation material disclosed by the invention is suitable for photovoltaic wires and cables and building wire high-end cotton covered wires, can resist the temperature of 125 DEG C, is a thermoplastic cable insulation material, has excellent heat resistance and flame retardance, hasexcellent processing technology performance and mechanical performance, can ensure fixed laying and use of the cables at the temperature of -40 DEG C to 125 DEG C, and is low in cost. According to acable made of the cable insulation material, the working temperature of the cable made of a common cable insulation material can be expanded to 125 DEG C from not lower than 70 DEG C or 105 DEG C, theflame retardant grade is improved to bunching combustion from single vertical combustion, and the environmental protection requirement meets the European Union standard requirement.

Description

technical field [0001] The invention belongs to the technical field of cables, and in particular relates to a heat-resistant, environment-friendly and flame-retardant cable insulating material and a preparation method thereof. Background technique [0002] At present, the highest temperature-resistant grade of PVC cable insulation materials on the market is 105°C, and polyolefin cable insulation materials are used for environmentally friendly cable insulation materials with higher temperature-resistant grades. Among them, there are two kinds of insulating materials with a heat resistance of 125°C: one is a polyolefin material cross-linked by radiation, and the other is a polyolefin material cross-linked by two-step silane. However, the extrusion speed of irradiated cross-linked polyolefin materials is slow, and the production efficiency is not high, and after the wire is made, it needs to be irradiated to reach the 125°C level, the process is complicated, and the cost of irr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L91/00C08K13/02C08K5/12C08K3/38C08K3/22C08K3/24
CPCC08L27/06C08L2205/03C08L2205/025C08L2201/02C08L2201/08C08L2203/202C08K2003/387C08K2003/2224C08L91/00C08K13/02C08K5/12C08K3/2279C08K3/38C08K3/22C08K3/24
Inventor 魏超冯国兴周宗平苗欢陆兴武
Owner TEBIAN ELECTRIC APP CO LTD
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