Waterborne acrylic emulsion, waterborne halftone printing ink and preparation method thereof
A water-based acrylic and printing ink technology, applied in ink, applications, household appliances, etc., can solve the problems of poor printing effect of half-tone layered plates, solvent pollution of packaging, and large environmental pollution, etc., to meet high-end exquisite printing, meet The market is environmentally friendly and the effect of good reproducibility
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[0054] The embodiment of the present invention also provides a preparation method of water-based acrylic emulsion B-338, comprising the following steps:
[0055] (1) Methyl methacrylate, styrene, butyl methacrylate, acrylic acid, N-hydroxyacrylic acid amide, and hydroxyethyl methacrylate are mixed to obtain a monomer mixture;
[0056] (2) Weigh 1-30% of the total amount of emulsifier and 1-5% of the total amount of water in the formula, place them in a pre-emulsification tank, and stir; weigh 1-30% of the total amount of monomer mixture, slowly add Carry out pre-emulsification in the emulsification kettle, and the emulsification time is 30-60min, to obtain the pre-emulsified seed liquid, and set aside;
[0057] (3) Weigh the remaining emulsifier, water with a total amount of 15-30%, and the remaining monomer mixture, slowly add it to the pre-emulsification tank for pre-emulsification, and the emulsification time is 30-60min to obtain a pre-emulsified monomer liquid, which is s...
Embodiment 1
[0061] This embodiment provides a water-based acrylic emulsion B-338, comprising the following raw material components in parts by weight:
[0062] 82 parts of monomer compound, 2 parts of emulsifier, 0.6 part of initiator, 0.3 part of sodium bicarbonate, 50 parts of water, 0.5 part of emulsion stabilizer, 0.5 part of crosslinking agent; the monomer compound includes: methyl methacrylate 30 parts, 30 parts of styrene, 16 parts of butyl methacrylate, 2 parts of acrylic acid, 1.5 parts of N-hydroxyacrylic acid amide, 2.5 parts of hydroxyethyl methacrylate; The initiator is potassium sulfate; The emulsifier is Sodium lauryl sulfate; the cross-linking agent is a propylene imine derivative cross-linking agent.
[0063] The preparation method of the present embodiment water-based acrylic emulsion B-338 comprises the following steps:
[0064] (1) Methyl methacrylate, styrene, butyl methacrylate, acrylic acid, N-hydroxyacrylic acid amide, and hydroxyethyl methacrylate are mixed to ob...
Embodiment 2
[0071] This embodiment provides a water-based acrylic emulsion B-338, comprising the following raw material components in parts by weight:
[0072] 82 parts of monomer compound, 2.5 parts of emulsifier, 0.5 part of initiator, 0.2 part of sodium bicarbonate, 45 parts of water, 0.6 part of emulsion stabilizer, 1 part of crosslinking agent; the monomer compound includes: methyl methacrylate 35 parts, 25 parts of styrene, 18 parts of butyl methacrylate, 1.5 parts of acrylic acid, 1 part of N-hydroxyacrylic acid amide, 1.5 parts of hydroxyethyl methacrylate; The initiator is potassium sulfate; The emulsifier is Sodium lauryl sulfate; the cross-linking agent is a propylene imine derivative cross-linking agent.
[0073] The preparation method of the present embodiment water-based acrylic emulsion B-338 comprises the following steps:
[0074] (1) Methyl methacrylate, styrene, butyl methacrylate, acrylic acid, N-hydroxyacrylic acid amide, and hydroxyethyl methacrylate are mixed to obt...
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