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Preparation method of high-thermal-conductivity composite material based on graphitized polydopamine coated metal particles

A polydopamine and metal particle technology, applied in the field of composite materials, can solve problems such as low thermal conductivity, and achieve the effects of high thermal conductivity, simple process and improved thermal conductivity.

Inactive Publication Date: 2021-01-29
TIANJIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to overcome the deficiencies in the prior art, have significant anisotropic thermal conductivity for existing graphene material, promptly only have high thermal conductivity (greater than 1000W / (m·K) along graphene plane ) and in the thickness direction perpendicular to its horizontal plane, the thermal conductivity is too low (less than 10W / (m K)), and a method for preparing a graphene-based composite material with high thermal conductivity along the horizontal direction and thickness direction is provided , the thermal conductivity of the prepared composite material along the plane is as high as 800W / (m·K), and the thermal conductivity along the thickness direction is above 80W / (m·K).

Method used

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  • Preparation method of high-thermal-conductivity composite material based on graphitized polydopamine coated metal particles
  • Preparation method of high-thermal-conductivity composite material based on graphitized polydopamine coated metal particles

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] 1. Weigh 100mg of metal nanoparticles (gold nanorods), disperse them in 10ml of dopamine hydrochloride solution (1mg / ml), stir ultrasonically for 30min, introduce 12.1mg of tris to initiate dopamine polymerization, and react at room temperature Afterwards, the polydopamine-coated metal particles (modified gold nanorods) were obtained by centrifugal separation.

[0023] 2. Weigh 0.5g of functionalized graphene and 0.1g of modified gold nanorods, and disperse them in 50ml of distilled water respectively. Subsequently, the water dispersion of the modified gold nanorods is gradually added to the graphene dispersion under constant stirring, so that the modified gold nanorods are fully combined with the functionalized graphene sheet. The dispersion liquid is vacuum filtered to remove the water solvent to obtain a composite membrane material, and then the composite material is dried supercritically to obtain a graphene / gold nanorod composite material.

[0024]3. Put the obtai...

Embodiment 2

[0026] 1. Weigh 100 mg of metal nanoparticles (gold nanosheets), disperse them in 15 ml of dopamine hydrochloride solution (1 mg / ml), and after ultrasonic stirring for 30 min, introduce 15.5 mg of tris to initiate dopamine polymerization, and react at room temperature Afterwards, the polydopamine-coated metal particles (modified gold nanosheets) were obtained by centrifugal separation.

[0027] 2. Weigh 0.5g of functionalized graphene and 0.1g of modified gold nanosheets, and disperse them in 50ml of distilled water respectively. Subsequently, the water dispersion of the modified gold nanosheets is gradually added to the graphene dispersion under continuous stirring, so that the modified gold nanosheets and the functionalized graphene sheets are fully combined. The dispersion liquid is vacuum filtered to remove the water solvent to obtain a composite membrane material, and then the composite material is dried supercritically to obtain a graphene / modified gold nanosheet composi...

Embodiment 3

[0030] 1. Weigh 100mg of metal nanoparticles (silver nanorods), disperse them in 10ml of dopamine hydrochloride solution (1mg / ml), stir ultrasonically for 30min, introduce 12.1mg of tris to initiate dopamine polymerization, and react at room temperature Afterwards, the polydopamine-coated metal particles (modified silver nanorods) were obtained by centrifugal separation.

[0031] 2. Weigh 0.5g of functionalized graphene and 0.1g of modified silver nanorods, and disperse them in 50ml of distilled water respectively. Subsequently, the water dispersion of the modified silver nanorods is gradually added to the graphene dispersion under continuous stirring, so that the modified silver nanorods and the functionalized graphene sheets are fully combined. The dispersion liquid is vacuum filtered to remove the water solvent to obtain a composite membrane material, and then the composite material is dried supercritically to obtain a graphene / modified silver nanorod composite material.

...

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Abstract

The invention discloses a preparation method of a high-thermal-conductivity composite material based on graphitized polydopamine coated metal particles. The method comprises the following steps of: blending metal particles coated with a layer of thickness-controllable polydopamine with a carbon-based filler by using high thermal conductivity of graphene in the in-plane direction, isotropic thermalconductivity of metal and adhesivity of polydopamine, connecting a graphene sheet layer by using the adhesion of polydopamine, and finally, graphitizing polydopamine and melting metal particles through high-temperature compression treatment, thereby obtaining the high-thermal-conductivity composite material. According to the preparation method, high thermal conductivity of metal and graphitized polydopamine is utilized, and an efficient thermal conduction channel is built between graphene layers, so that the high thermal performance of the material in the thickness direction is effectively improved, the defect of poor thermal conductivity of the material in the thickness direction is overcome, and the high-performance thermal conduction material is prepared.

Description

technical field [0001] The invention belongs to the technical field of composite materials, and relates to a method for preparing a graphene / metal particle composite material with high thermal conductivity, in particular to a carbon-based composite material with high thermal conductivity along the thickness direction and the horizontal direction. method. Background technique [0002] With the miniaturization and densification of electronic appliances, the requirements for thermal conductivity and electrical performance of related components are getting higher and higher. For example, the current common tablet computer and electronic appliances have increasingly diversified functions while the volume is continuously reduced. The ensuing problem is that electronic devices will generate a lot of heat during high-speed operation, and long-term use will cause the heat accumulation of electronic products to appear as an obvious heating phenomenon to the outside, which will cause ...

Claims

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Application Information

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IPC IPC(8): C09K5/14B82Y30/00B82Y40/00
CPCB82Y30/00B82Y40/00C09K5/14
Inventor 封伟张志兴张飞冯奕钰秦盟盟
Owner TIANJIN UNIV
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