Check patentability & draft patents in minutes with Patsnap Eureka AI!

Phosphorus-containing scale inhibitor for industrial circulating water and preparation method and application thereof

A technology of industrial circulating water and scale inhibitor, applied in the field of scale inhibitor, can solve the problems of unsatisfactory scale inhibition effect of industrial circulating water, polluted environment, phosphorus content, and phosphorus content exceeding the standard, saving labor and equipment cost, The effect of saving scale inhibition time and reducing dosage

Pending Publication Date: 2021-02-05
嘉兴沃特泰科环保科技股份有限公司
View PDF5 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] 1. The anti-scaling effect on industrial circulating water is not ideal, and it is usually necessary to increase the dosage, which will lead to high costs and pollute the environment (the phosphorus content in sewage exceeds the standard);
[0007] 2. For scale inhibition of industrial circulating water, the demand for scale inhibitors for industrial circulating water is high, and the scale inhibition effect is high, otherwise it will not only lead to high costs, pollute the environment (the phosphorus content in sewage exceeds the standard), and may Equipment failure due to fouling, and even accidents

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Phosphorus-containing scale inhibitor for industrial circulating water and preparation method and application thereof
  • Phosphorus-containing scale inhibitor for industrial circulating water and preparation method and application thereof
  • Phosphorus-containing scale inhibitor for industrial circulating water and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] A kind of phosphorus-containing scale inhibitor for industrial circulating water, its raw material comprises by weight:

[0054] 13 parts of zinc salt,

[0055] AA-AMPS copolymer 40 parts,

[0056] 13 parts of 2-phospho-1,2,4-tricarboxylic acid butane,

[0057] 4.2 parts of hydroxyethylidene diphosphonic acid,

[0058] 1.75 parts of methyl benzotriazole,

[0059] 16 parts of hydrochloric acid;

[0060] The AA-AMPS copolymer is formed by copolymerizing acrylic acid and 2-acrylamide-2-methylpropanesulfonic acid.

[0061] Preferably, the zinc salt is a mixture of zinc hydroxyethylidene diphosphonate and zinc chloride.

[0062] Preferably, the mass ratio of zinc hydroxyethylidene diphosphonate and zinc chloride in the mixture of zinc hydroxyethylidene diphosphonate and zinc chloride is 1:0.72.

[0063] Preferably, the mass concentration of the hydrochloric acid is 18.5%.

[0064] Preferably, the molar ratio of monomer units acrylic acid to 2-acrylamide-2-methylpropan...

Embodiment 2

[0071] A kind of phosphorus-containing scale inhibitor for industrial circulating water, its raw material comprises by weight:

[0072] 18 parts of zinc salt,

[0073] AA-AMPS copolymer 50 parts,

[0074] 17 parts of 2-phospho-1,2,4-tricarboxylic acid butane,

[0075] 5.8 parts of hydroxyethylidene diphosphonic acid,

[0076] Tolyl benzotriazole 1.95 parts,

[0077] 20 parts of hydrochloric acid;

[0078] The AA-AMPS copolymer is formed by copolymerizing acrylic acid and 2-acrylamide-2-methylpropanesulfonic acid.

[0079] Preferably, the zinc salt is a mixture of zinc hydroxyethylidene diphosphonate and zinc chloride.

[0080] Preferably, the mass ratio of zinc hydroxyethylidene diphosphonate and zinc chloride in the mixture of zinc hydroxyethylidene diphosphonate and zinc chloride is 1:0.77.

[0081] Preferably, the mass concentration of the hydrochloric acid is 20.5%.

[0082] Preferably, the molar ratio of monomer units acrylic acid to 2-acrylamide-2-methylpropanesul...

Embodiment 3

[0089] A kind of phosphorus-containing scale inhibitor for industrial circulating water, its raw material comprises by weight:

[0090] 15 parts of zinc salt,

[0091] AA-AMPS copolymer 45 parts,

[0092] 2-phospho-1,2,4-tricarboxylic acid butane 15 parts,

[0093] 5 parts of hydroxyethylidene diphosphonic acid,

[0094] 1.8 parts of methyl benzotriazole,

[0095] 18 parts of hydrochloric acid;

[0096] The AA-AMPS copolymer is formed by copolymerizing acrylic acid and 2-acrylamide-2-methylpropanesulfonic acid.

[0097] Preferably, the zinc salt is a mixture of zinc hydroxyethylidene diphosphonate and zinc chloride.

[0098] Preferably, the mass ratio of zinc hydroxyethylidene diphosphonate and zinc chloride in the mixture of zinc hydroxyethylidene diphosphonate and zinc chloride is 1:0.74.5.

[0099] Preferably, the mass concentration of the hydrochloric acid is 19.5%.

[0100] Preferably, the molar ratio of monomer units acrylic acid to 2-acrylamide-2-methylpropanesul...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a phosphorus-containing scale inhibitor for industrial circulating water. The phosphorus-containing scale inhibitor comprises the following raw materials in parts by weight: 13-18 parts of zinc salt, 40-50 parts of an AA-AMPS copolymer, 13-17 parts of 2-phosphonobutane-1,2,4-tricarboxylic acid, 4.2-5.8 parts of 1-hydroxyethylidene-1, 1-diphosphonic acid, 1.75-1.95 parts ofmethylbenzotriazole and 16-20 parts of hydrochloric acid. The AA-AMPS copolymer is formed by copolymerizing acrylic acid and 2-acrylamino-2-methyl propanesulfonic acid. According to the phosphorus-containing scale inhibitor for the industrial circulating water, disclosed by the invention, by finely selecting the raw materials and optimizing the content of each raw material, the prepared phosphorus-containing scale inhibitor for the industrial circulating water has a very excellent scale inhibition effect on the industrial circulating water, so that the scale inhibition time can be greatly saved, the utilization rate and the circulating efficiency of the circulating water are greatly improved, the dosage of the scale inhibitor can be reduced, and the scale inhibition cost of industrial circulating water can be saved.

Description

technical field [0001] The invention relates to the field of scale inhibitors, in particular to a phosphorus-containing scale inhibitor for industrial circulating water and a preparation method and application thereof. Background technique [0002] Industrial circulating water is mainly used in cooling water systems, so it is also called circulating cooling water. Because industrial cooling water accounts for more than 90% of the total water consumption. Domestic circulating water is mainly used in water heaters. [0003] There are two types of circulating cooling water: closed type (closed type) and open type. In the closed cooling water system, the cooling water is not exposed to the air, the water loss is very small, and the contents of various minerals and ions in the water generally do not change. In the open circulating water system, the recooling of water is carried out through the cooling tower, so the cooling water must be in contact with the air during the recir...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C02F5/10C02F5/12C02F5/14C02F5/08C02F103/02
CPCC02F5/105C02F5/125C02F5/145C02F2103/023
Inventor 钟奇军周卫华陈谦王小东
Owner 嘉兴沃特泰科环保科技股份有限公司
Features
  • R&D
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More