Phosphorus-containing scale inhibitor for industrial circulating water and preparation method and application thereof
A technology of industrial circulating water and scale inhibitor, applied in the field of scale inhibitor, can solve the problems of unsatisfactory scale inhibition effect of industrial circulating water, polluted environment, phosphorus content, and phosphorus content exceeding the standard, saving labor and equipment cost, The effect of saving scale inhibition time and reducing dosage
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Embodiment 1
[0053] A kind of phosphorus-containing scale inhibitor for industrial circulating water, its raw material comprises by weight:
[0054] 13 parts of zinc salt,
[0055] AA-AMPS copolymer 40 parts,
[0056] 13 parts of 2-phospho-1,2,4-tricarboxylic acid butane,
[0057] 4.2 parts of hydroxyethylidene diphosphonic acid,
[0058] 1.75 parts of methyl benzotriazole,
[0059] 16 parts of hydrochloric acid;
[0060] The AA-AMPS copolymer is formed by copolymerizing acrylic acid and 2-acrylamide-2-methylpropanesulfonic acid.
[0061] Preferably, the zinc salt is a mixture of zinc hydroxyethylidene diphosphonate and zinc chloride.
[0062] Preferably, the mass ratio of zinc hydroxyethylidene diphosphonate and zinc chloride in the mixture of zinc hydroxyethylidene diphosphonate and zinc chloride is 1:0.72.
[0063] Preferably, the mass concentration of the hydrochloric acid is 18.5%.
[0064] Preferably, the molar ratio of monomer units acrylic acid to 2-acrylamide-2-methylpropan...
Embodiment 2
[0071] A kind of phosphorus-containing scale inhibitor for industrial circulating water, its raw material comprises by weight:
[0072] 18 parts of zinc salt,
[0073] AA-AMPS copolymer 50 parts,
[0074] 17 parts of 2-phospho-1,2,4-tricarboxylic acid butane,
[0075] 5.8 parts of hydroxyethylidene diphosphonic acid,
[0076] Tolyl benzotriazole 1.95 parts,
[0077] 20 parts of hydrochloric acid;
[0078] The AA-AMPS copolymer is formed by copolymerizing acrylic acid and 2-acrylamide-2-methylpropanesulfonic acid.
[0079] Preferably, the zinc salt is a mixture of zinc hydroxyethylidene diphosphonate and zinc chloride.
[0080] Preferably, the mass ratio of zinc hydroxyethylidene diphosphonate and zinc chloride in the mixture of zinc hydroxyethylidene diphosphonate and zinc chloride is 1:0.77.
[0081] Preferably, the mass concentration of the hydrochloric acid is 20.5%.
[0082] Preferably, the molar ratio of monomer units acrylic acid to 2-acrylamide-2-methylpropanesul...
Embodiment 3
[0089] A kind of phosphorus-containing scale inhibitor for industrial circulating water, its raw material comprises by weight:
[0090] 15 parts of zinc salt,
[0091] AA-AMPS copolymer 45 parts,
[0092] 2-phospho-1,2,4-tricarboxylic acid butane 15 parts,
[0093] 5 parts of hydroxyethylidene diphosphonic acid,
[0094] 1.8 parts of methyl benzotriazole,
[0095] 18 parts of hydrochloric acid;
[0096] The AA-AMPS copolymer is formed by copolymerizing acrylic acid and 2-acrylamide-2-methylpropanesulfonic acid.
[0097] Preferably, the zinc salt is a mixture of zinc hydroxyethylidene diphosphonate and zinc chloride.
[0098] Preferably, the mass ratio of zinc hydroxyethylidene diphosphonate and zinc chloride in the mixture of zinc hydroxyethylidene diphosphonate and zinc chloride is 1:0.74.5.
[0099] Preferably, the mass concentration of the hydrochloric acid is 19.5%.
[0100] Preferably, the molar ratio of monomer units acrylic acid to 2-acrylamide-2-methylpropanesul...
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