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A kind of antibacterial coarse aggregate and preparation method thereof

The technology of coarse aggregate and aggregate is applied in the field of antibacterial coarse aggregate and its preparation, and can solve the problems of affecting the antibacterial performance of photocatalytic antibacterial concrete, the error of the mixing amount of nanometer photocatalytic materials, and the less distribution of nanometer photocatalytic materials, etc. Achieve the effect of improving bacterial erosion resistance, good bacteriostatic and sterilizing effects, reducing uneven dispersion and material loss

Inactive Publication Date: 2021-08-31
FUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] (1) The method of physical adsorption is mainly by attaching nano-photocatalytic materials on the surface and pores of lightweight aggregates, while the nano-photocatalytic materials on the surface of lightweight aggregates have poor erosion and wear resistance, which easily leads to nano-photocatalytic materials. The loss of catalytic materials; the nano-photocatalytic materials attached to the lightweight aggregate are less and unevenly distributed, which seriously affects the antibacterial performance of photocatalytic antibacterial concrete
[0004] (2) At present, most of the nano-photocatalytic materials in concrete are directly mixed into the cement paste. If only the nano-photocatalytic materials are mixed into the cement paste, the contact area between the nano-photocatalytic materials and bacteria in the concrete will be limited. increase, thus hindering the improvement of photocatalytic antibacterial performance
[0005] (3) Since nano-photocatalytic materials are easy to adsorb and agglomerate, it is difficult to mix them evenly with cement and sand when directly mixed into cement or sand
Even if it is added after being uniformly dispersed in water, in addition to the dispersibility cannot be guaranteed, more nano-photocatalytic materials remain on the inner wall or bottom of the container, and the material loss is more, which not only produces a large error in the amount of nano-photocatalytic materials incorporated, It also affects the bactericidal effect during use

Method used

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Examples

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Effect test

preparation example Construction

[0033] A preparation method of antibacterial coarse aggregate, carried out according to the following steps:

[0034] Step 1: Change the mass to M 1 The antibacterial agent is evenly dispersed in tap water to obtain a modified liquid; the modified liquid is evenly sprayed on the surface of the basalt fiber, and placed in an oven to heat and dry, so that the antibacterial agent is attached to the surface of the basalt fiber to obtain a modified fiber;

[0035] said M 1 =(0.03~0.04) M 0 ,in M 0 is the mass of basalt fiber; the V 3 =(30~100) V 4 ,in V 4 for quality M 1 The bulk volume of the antimicrobial agent;

[0036] Step 2: Change the mass to M 2 The antibacterial agent is equally divided into three parts, which are recorded as the first part of antibacterial agent, the second part of antibacterial agent, and the third part of antibacterial agent; M 2 = M - M 1 ,in M is the total mass of the antibacterial agent;

[0037] Step 3: Evenly disperse the fi...

Embodiment 1

[0049] In this example, the raw material ratio of the aggregate matrix by weight is: 16 parts of ordinary Portland cement, 0.85 parts of metakaolin, 46 parts of quartz sand, 0.1 part of basalt fiber, 0.02 part of antibacterial agent, and 8.5 parts of deionized water . The particle size of the quartz sand is 0.25-4.75 mm.

[0050] Described antibacterial main material is the equal mass combination of nanometer titanium dioxide, nano graphite phase carbon nitride, nano zirconium dioxide; Described antibacterial auxiliary material is nano hexagonal boron nitride; The weight ratio of described antibacterial main material and antibacterial auxiliary material is 1: 0.16.

[0051] Described antibacterial agent is made up of antibacterial main material and antibacterial auxiliary material; Described antibacterial agent is that antibacterial main material and antibacterial auxiliary material are added volume simultaneously V 1 Ultrasonic dispersion in tap water for 12-25 minutes (fr...

Embodiment 2

[0063] In this example, the raw material ratio of the aggregate matrix by weight is: 18 parts of ordinary Portland cement, 0.95 parts of metakaolin, 54 parts of quartz sand, 0.11 parts of basalt fiber, 0.025 parts of antibacterial agent, and 9.5 parts of deionized water .

[0064] The preparation method of the antibacterial coarse aggregate of this embodiment is the same as that of Embodiment 1.

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PUM

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Abstract

The invention relates to an antibacterial coarse aggregate and a preparation method thereof. The antibacterial coarse aggregate is composed of an aggregate matrix and an isolation layer; 0.8-2 parts of kaolin, 40-68 parts of quartz sand, 0.1-0.15 parts of basalt fiber, 0.02-0.04 parts of antibacterial agent, 7.5-13 parts of deionized water; the isolation layer is arranged on the surface of the aggregate matrix. After the antibacterial coarse aggregate prepared by the present invention is mixed into concrete, the number of active sites of nano photocatalytic materials in concrete can be significantly increased, and the antibacterial performance of concrete can be improved; the anti-scouring and anti-wear properties of nano photocatalytic materials in antibacterial coarse aggregate The performance is good, which ensures the stability and durability of the antibacterial performance of photocatalytic antibacterial concrete.

Description

technical field [0001] The invention belongs to the technical field of building materials, in particular to an antibacterial coarse aggregate and a preparation method thereof. Background technique [0002] Aggregate is a granular material that plays the role of skeleton and filling in mortar or concrete, and is one of the necessary building materials for the preparation of mortar or concrete. Aggregate is generally divided into fine aggregate and coarse aggregate. River sand and lake sand are generally used as fine aggregates, and crushed stones and pebbles are generally used as coarse aggregates. Because the concrete is exposed to the air for a long time, bacteria are prone to exist in the surface or cracks, which will cause erosion and damage to the concrete. In order to solve the above problems, existing solutions include spraying bactericides, coating bactericidal paints, and photocatalytic sterilization. The effect of photocatalytic sterilization is affected by facto...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/04C04B28/02C04B111/20
CPCC04B28/02C04B28/04C04B2111/2092C04B14/106C04B14/06C04B14/46C04B14/305C04B14/325C04B14/306C04B14/327C04B18/141C04B22/064
Inventor 杨政险卢林张勇郭婷
Owner FUZHOU UNIV