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Triptycene derivative modified waterborne acrylic resin and preparation method thereof

A technology of water-based acrylic and its derivatives, which can be used in biocide-containing paints, anti-fouling/underwater coatings, coatings, etc. It can solve the problems of imperfect performance of water-based acrylic resins, and achieve good artificial aging resistance and compatibility Good and stable performance

Inactive Publication Date: 2021-04-09
UNION FOSHAN CHEM +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in some special fields, the performance of water-based acrylic resin is not perfect, and these shortcomings of water-based acrylic resin seriously restrict its application and development, so it is necessary to carry out deeper modification of acrylic emulsion

Method used

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  • Triptycene derivative modified waterborne acrylic resin and preparation method thereof
  • Triptycene derivative modified waterborne acrylic resin and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A tricene derivative-modified water-based acrylic resin, in parts by weight, its components are: 4.0 parts of tricene derivatives, 2.0 parts of hydroxyethyl methacrylate, 0.5 parts of benzoyl peroxide, three parts 4.0 parts of methylolpropane trimethacrylate, 3.5 parts of acrylic acid, 20.0 parts of methyl methacrylate, 15.0 parts of butyl methacrylate, 15.0 parts of lauryl methacrylate, 3.0 parts of vinyltrimethoxysilane, 15.0 parts of diethylene glycol monobutyl ether, 3.0 parts of triethylamine, and 95.0 parts of deionized water.

[0028] In the present embodiment, a preparation method of a tridecene derivative-modified water-based acrylic resin comprises the following steps:

[0029] a), in the titration tank, in parts by weight of the formula, methyl methacrylate, butyl methacrylate, lauryl methacrylate, hydroxyethyl methacrylate, 1 / 3 benzoyl peroxide Stir evenly to obtain mixed solution I;

[0030] b), in the titration tank, by weight of the formula, stir trimet...

Embodiment 2

[0034] A tricene derivative-modified water-based acrylic resin, in parts by weight, the components are: in parts by weight, the components are: 3.0 parts of tricene derivatives, 3.0 parts of hydroxypropyl methacrylate, 0.6 parts of benzoyl peroxide, 6.0 parts of trimethylolpropane trimethacrylate, 4.0 parts of acrylic acid, 8.0 parts of methyl acrylate, 15.0 parts of isobornyl acrylate, 10.0 parts of hexyl acrylate, thirteen carbon methacrylate 10.0 parts of esters, 15.0 parts of octadecyl acrylate, 2.0 parts of vinyltrimethoxysilane, 20.0 parts of propylene glycol methyl ether acetate, 3.0 parts of ammonia water, and 100.0 parts of deionized water.

[0035] The invention provides a preparation method of a tridecene derivative-modified water-based acrylic resin, comprising the following steps:

[0036] a), in the titration tank, in parts by weight of the formula, mix methyl acrylate, isobornyl acrylate, hexyl acrylate, tridecyl methacrylate, octadecyl acrylate, hydroxypropyl m...

Embodiment 3

[0041]A tricene derivative-modified water-based acrylic resin, in parts by weight, the components are: in parts by weight, the components are: 3.5 parts of tricene derivatives, 3.0 parts of hydroxybutyl methacrylate, 0.5 parts of benzoyl peroxide, 4.0 parts of trimethylolpropane trimethacrylate, 3.5 parts of acrylic acid, 16.0 parts of cyclohexyl methacrylate, 25.0 parts of octadecyl acrylate, 3.0 parts of vinyltrimethoxysilane, 14.0 parts of diethylene glycol monobutyl ether, 3.2 parts of triethylamine, and 90.0 parts of deionized water.

[0042] The invention provides a preparation method of a tridecene derivative-modified water-based acrylic resin, comprising the following steps:

[0043] a), in the titration tank, in parts by weight of the formula, cyclohexyl methacrylate, octadecyl acrylate, hydroxybutyl methacrylate, 1 / 3 benzoyl peroxide are stirred to obtain mixed solution I;

[0044] b), in the titration tank, by weight of the formula, stir trimethylolpropane trimetha...

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Abstract

The invention relates to triptycene derivative modified water-based acrylic resin and a preparation method of the triptycene derivative modified water-based acrylic resin. The resin comprises the following components in parts by weight: 2.0 to 6.0 parts of triptycene derivative, 1.0 to 4.0 parts of crosslinking monomer, 0.2 to 0.8 part of benzoyl peroxide, 2.0 to 8.0 parts of trimethylolpropane trimethacrylate, 2.0 to 5.0 parts of acrylic acid, 10.0 to 30.0 parts of acrylate hard monomer, 15.0 to 45.0 parts of acrylate soft monomer, 1.0 to 4.0 parts of vinyl trimethoxy silane, 10.0 to 25.0 parts of cosolvent, 1.5 to 4.5 parts of neutralizer and 50.0 to 120.0 parts of deionized water. The triptycene derivative modified waterborne acrylic resin prepared by the invention has a series of properties such as good artificial aging resistance, acid and alkali resistance, salt fog resistance, corrosion resistance, water resistance, adsorbability, bacteria resistance, sterilization and the like, and a bactericide does not need to be added when the triptycene derivative modified waterborne acrylic resin is made into a coating. The waterborne acrylic resin can be made into single-component and double-component water-based paint.

Description

technical field [0001] The invention relates to a modified water-based acrylic resin, in particular to a tridecene derivative-modified water-based acrylic resin and a preparation method thereof, belonging to the technical field of synthetic water-based resins. Background technique [0002] Over the years, my country's acrylic resin industry has developed rapidly, and product output has continued to expand. The national industrial policy encourages the acrylic resin industry to develop in the direction of high-tech products, and domestic enterprises have gradually increased investment in new investment projects. Investors are paying more and more attention to the acrylic resin industry, which increases the demand for research on the development of the acrylic resin industry. Acrylic resin paint has excellent gloss and color retention as well as good mechanical properties, good chemical stability, strong film-forming ability, heat resistance, chemical resistance and other prop...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/14C08F220/18C08F220/20C08F220/06C08F230/08C08F222/14C08F232/08C09D133/12C09D133/08C09D5/14
CPCC08F220/14C09D5/14C09D143/04C08F220/1811C08F220/1818C08F220/1804C08F220/1812C08F220/20C08F220/06C08F230/08C08F222/14C08F232/08C08F220/1806
Inventor 张武康伦国姚东生
Owner UNION FOSHAN CHEM
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