Pp melt-blown material and preparation method thereof

A technology of melt-blown and powder materials, which is applied in the manufacture of rayon, textiles and paper, and single-component polyolefin rayon. Problems, to achieve good uniformity, high product quality rate, and reduce the effect of processing temperature

Pending Publication Date: 2021-04-16
汕头市格派环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the existing pp melt-blown materials are powders polymerized by catalysts containing phthalate plasticizers, and plasticizers are very harmful to the human body. In production, low-melt polypropylene is used to add over The process of oxide degradation generation; low melting means that when polypropylene passes through the barrel of the pelletizing extruder quickly, the peroxide cannot be 100% degraded, the degradation reaction cannot be completely completed, and a large amount of peroxide will remain, and the decomposition and reaction are not complete The residual peroxide will enter the non-woven fabric product under high-temperature melt blown, making the non-woven fabric product smelly or even peculiar; the uniformity of the existing melt-blown raw materials is poor, resulting in the melt-blown non-woven fabric produced The gram weight is unstable, and the filaments are easy to break during the filament forming process; the rate of superior products is low

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0024] A preparation method for pp melt-blown material, comprising the steps of:

[0025] Step 1: Put polypropylene, cooling masterbatch, melt-blown powder, coupling agent, dispersant, antioxidant, lubricant and stabilizer into a high-speed mixer in sequence according to the mass ratio and mass parts. 2000-2500 rpm, stirring temperature 90-110°C, stirring for 10-20min, mixing and stirring evenly to obtain a molten mixture;

[0026] Step 2: Put the molten mixture obtained by mixing and stirring in step 1 into a twin-screw extruder, melt and extrude, granulate, and cool to obtain pp meltblown material.

[0027] Preferably, the twin-screw extruder includes ten temperature zones, the process temperature of zone 1-2 of the extruder barrel is 150-170°C, the temperature of zone 3-6 is 160-180°C, and the temperature of zone 7-8 is 180°C -190°C, the temperature in zone 9-10 is 150-180°C, the extrusion speed of the screw of the extruder is 500-800 rpm, and the cooling temperature of th...

Embodiment 1

[0030] A pp melt-blown material, consisting of the following raw materials and mass fractions: 150 parts of polypropylene, 75 parts of cooling masterbatch, 15 parts of melt-blown powder, 0.5 parts of titanate coupling agent, 0.8 parts of magnesium stearate, bis 0.1 part of pentaerythritol diphosphite, 0.2 part of calcium stearate, and 0.4 part of stabilizer.

[0031] Preferably, the effective peroxide concentration of the cooling masterbatch is 3, the melting index of the cooling masterbatch is 40g / 10min, and the melting index of the meltblown powder is 4010min.

[0032] Preferably, the mass ratio of the cooling masterbatch to the meltblown powder and additives is: 22.84:77.97:0.19.

[0033] Preferably, the peroxide concentration of the pp meltblown material is 6500ppm.

[0034] A pp meltblown material of this embodiment is prepared by the following preparation method, including the following steps:

[0035] Step 1: Put polypropylene, cooling masterbatch, melt-blown powder, ...

Embodiment 2

[0039] A pp melt-blown material, consisting of the following raw materials and mass fractions: 120 parts of polypropylene, 90 parts of cooling masterbatch, 20 parts of melt-blown powder, 1.5 parts of titanate coupling agent, 0.8 parts of polyethylene wax, tetraerythritol Ester, 0.4 parts of triphosphite, 1.1 parts of ethylene bis stearamide, 1.1 parts of stabilizer.

[0040] Preferably, the effective peroxide concentration of the cooling masterbatch is 2%, the melting index of the cooling masterbatch is 30g / 10min, and the melting index of the melt blown powder is 50g / 10min.

[0041]Preferably, the mass ratio of the cooling masterbatch to the meltblown powder and additives is 21:79:0.1.

[0042] Preferably, the peroxide concentration of the pp meltblown material is 6000ppm.

[0043] A pp meltblown material of this embodiment is prepared by the following preparation method, including the following steps:

[0044] Step 1: Put polypropylene, cooling masterbatch, melt-blown powde...

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Abstract

The invention relates to the technical field of melt-blown raw materials, in particular to a pp melt-blown material and a preparation method thereof. The pp melt-blown material is prepared from the following raw materials: polypropylene, a cooling master batch, melt-blown powder, an auxiliary agent and a stabilizer. The peroxide content concentration of the pp melt-blown material is 6000 ppm to 7500 ppm. The pp melt-blown material has the beneficial effects that the cooling master batch, the melt-blown powder and the auxiliaries are adopted according to the proportion, so that the melting number of the polypropylene material is greatly increased, the pp melt-blown material with high melt index and low ash content can be prepared, the processing temperature can be reduced, the requirements of energy conservation and environmental protection are met, and the PP melt-blown material prepared by the method is safe and harmless to human bodies. The pp melt-blown material prepared by the preparation method disclosed by the invention is stable in gram weight, environment-friendly, pollution-free and high in superior product rate, and the melt-blown fabric prepared from the pp melt-blown material disclosed by the invention has high uniformity and consistency and cannot be broken in a filamentation process.

Description

technical field [0001] The invention relates to the technical field of melt-blown raw materials, and more specifically, to a PP melt-blown material and a preparation method thereof. Background technique [0002] Polypropylene (PP) is widely used as a thermoplastic polymer in various fields. Due to the difference in the catalysts and polymerization processes used, the properties of the obtained polymers are very different. In different application fields, various performance indicators The requirements are different, so it is necessary to achieve the required performance indicators through blending modification. At present, cooling masterbatches are mostly used to increase the melt index of polypropylene materials, reduce processing temperature, shorten product molding cycle time, and reduce energy consumption. However, ordinary cooling masterbatches have a greater impact on the overall performance of materials after they are added to the material formula. Among them, those ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L101/12C08K5/14D01F6/46D01F1/10
Inventor 谢派昌
Owner 汕头市格派环保科技有限公司
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