Photoelectric conversion element and manufacturing method thereof
A technology for photoelectric conversion elements and manufacturing methods, which is applied in the fields of electrical components, semiconductor/solid-state device manufacturing, photovoltaic power generation, etc., can solve problems such as current flow, and achieve the effect of reducing the variation of dark current
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[0333] (Preparation of Coating Liquid for Active Layer Formation)
[0334] The coating liquid for forming an active layer according to this embodiment can be prepared by a known method. For example, it can be prepared by the following method: mixing the first solvent and the second solvent to prepare a mixed solvent, adding a p-type semiconductor material and an n-type semiconductor material to the obtained mixed solvent; adding p A method of adding an n-type semiconductor material to a second solvent, and then mixing the first solvent and the second solvent to which each material was added; and the like.
[0335] The first solvent and the second solvent, and the p-type semiconductor material and n-type semiconductor material may be heated to a temperature not higher than the boiling point of the solvents and mixed.
[0336] After mixing the first solvent and the second solvent, and the p-type semiconductor material and n-type semiconductor material, the resulting mixture can...
Embodiment 1
[0373] Production and evaluation of photoelectric conversion elements
[0374] (Manufacture of photoelectric conversion elements)
[0375] An ITO thin film (cathode) was formed to a thickness of 150 nm on a glass substrate by a sputtering method. The surface of this glass substrate was subjected to ozone UV treatment.
[0376] Next, 1% by weight of polyethyleneimine ethoxylate (PEIE) aqueous solution (manufactured by Aldrich, trade name polyethyleneimine, 80% ethoxylated solution) was mixed with 10 g of 3-pentanol. , weight average molecular weight 110000) and 1 g of a solution containing 10% by weight of a zinc oxide / isopropanol dispersion (manufactured by TAYCA, product name: HTD-711Z) to prepare a coating solution for forming an electron transport layer.
[0377] The obtained coating solution for forming an electron transport layer was applied onto an ITO thin film of an ozone UV-treated glass substrate by a spin coating method to form a coating film.
[0378] The glass...
Embodiment 2
[0411] A photoelectric conversion element was produced and evaluated in the same manner as in Example 1 except that 2-propanol was used instead of 3-pentanol used as a solvent in the coating liquid for forming an electron transport layer.
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