PPS/PBT composite material for NMT and preparation method thereof
A composite material and PPS resin technology, which is applied in the field of PPS/PBT composite materials for NMT and its preparation, can solve the problems of poor compatibility between glass fiber and PBT, inconsistent longitudinal and transverse shrinkage rates, and brittle fracture of materials. Consistent shrinkage in all directions, increased firmness, and enhanced binding ability
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preparation example 1
[0038] A modified chitosan, the preparation method of which is:
[0039] Mix 10 g of glycerin-chitosan and 40 g of dehydrated dimethyl sulfoxide, add 1 g of polycaprolactone containing isocyanate groups, and then react at 40 ° C for 2 days to prepare a reaction solution, using absolute ethanol and formaldehyde The mixed solution of ether precipitates the reaction solution, and uses dichloromethane to purify the precipitate through Soxhlet extraction to obtain modified chitosan; the weight ratio of absolute ethanol and methyl ether in the mixed solution is 1:1, The CAS number of the methyl ether is 115-10-6.
[0040] The preparation method of the glycerin-chitosan is as follows: after mixing 1 g of chitosan and 40 g of acetic acid solution with a mass concentration of 1%, stirring at 50° C. for 1 day, dialyzing the reaction solution for three days with a dialysis bag, and then dialysis the reaction solution by rotary evaporation. Concentrate the dialysate, and then freeze-dry ...
preparation example 2
[0044] Preparation Example 2 is based on Preparation Example 1, and the only difference from Preparation Example 1 is that the weight ratio of glycerol-chitosan, dimethyl sulfoxide and polycaprolactone containing isocyanate groups is 1:4:0.3 .
preparation example 3
[0046]Preparation Example 3 is based on Preparation Example 1, and the only difference from Preparation Example 1 is that the weight ratio of glycerol-chitosan, dimethyl sulfoxide and polycaprolactone containing isocyanate groups is 1:4:0.2 .
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Abstract
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