Polarizing plate with retardation layer and image display device using the same
A technology for image display devices and retardation layers, which is applied in identification devices, lighting devices, optics, etc., can solve the problems of reduction, reduction of optical characteristics, and insufficient optical characteristics of polarizing plates, etc., and achieve excellent handling and excellent optical characteristics. Effect
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Embodiment 1
[0192] 1. Production of polarizing film
[0193] As the thermoplastic resin substrate, an amorphous isophthalic acid copolymer polyethylene terephthalate film (thickness: 100 μm) having a water absorption rate of 0.75% and a Tg of about 75° C. was used. Corona treatment is performed on one side of the resin base material.
[0194]100 weight of PVA-based resin obtained by mixing polyvinyl alcohol (degree of polymerization 4200, degree of saponification 99.2 mol%) and acetoacetyl-modified PVA (manufactured by Nippon Synthetic Chemical Industry Co., Ltd., trade name "GOHSEFIMER Z410") at a ratio of 9:1 After adding 13 parts by weight of potassium iodide to the part, it was dissolved in water to prepare an aqueous PVA solution (coating liquid).
[0195] The above-mentioned PVA aqueous solution was apply|coated to the corona-treated surface of a resin base material, and it dried at 60 degreeC, and formed the PVA-type resin layer of thickness 8 micrometers, and produced the laminat...
Embodiment 2-1
[0214] 1. Production of polarizing film
[0215] The coating thickness of the PVA aqueous solution (coating solution) was changed to 13 μm, the thickness of the obtained polarizing film was 4.6 μm, and the concentration of the dyeing bath was adjusted so that the monomer transmittance (Ts) of the polarizing film was 43.0%, Except for this, it carried out similarly to Example 1, and formed the polarizing film on the resin base material.
[0216] 2. Production of polarizing plate
[0217] Except having used the polarizing film obtained in said 1., it carried out similarly to Example 1, and produced the polarizing plate which has the structure of a protective layer / adhesive layer / polarizing film. The single-piece transmittance of the polarizing plate (substantially a polarizing film) was 43.0%, and the degree of polarization was 99.995%. Furthermore, A 550 / A 210 is 1.65, A 470 / A 600 is 0.87, and the quadrature b value is -3.0.
[0218] 3. Production of retardation film ...
Embodiment 2-2
[0223] 1. Production of polarizing film
[0224] A polarizing film was formed on a resin substrate in the same manner as in Example 2-1, except that the concentration of the dyeing bath was adjusted so that the monomer transmittance (Ts) of the polarizing film was 44.0%.
[0225] 2. Production of polarizing plate
[0226] Except having used the polarizing film obtained in said 1., it carried out similarly to Example 1, and produced the polarizing plate which has the structure of a protective layer / adhesive layer / polarizing film. The single transmittance of the polarizing plate (substantially a polarizing film) was 44.0%, and the degree of polarization was 99.96%. Furthermore, A 550 / A 210 is 1.48, A 470 / A 600 is 0.87, and the quadrature b value is -5.0.
[0227] 3. Production of polarizing plate with retardation layer
[0228] In the same manner as in Example 1, the surface of the polarizing film of the polarizing plate obtained in the above 2. was pasted with the reta...
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Abstract
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