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Silicon carbide whisker reinforced porous magnesium oxide-carbon ceramic filter and preparation method thereof

A technology of porous magnesium oxide and silicon carbide whiskers, which is applied in chemical instruments and methods, ceramic products, separation methods, etc., can solve the problem of poor adsorption capacity of small-sized inclusions, reduced filter thermal shock stability, and strength to be further enhanced and other problems, to achieve the effect of improving the performance of slurry, improving the thermal shock stability and strength, and improving the material strength and thermal shock stability

Active Publication Date: 2021-06-01
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the multi-porous structure of the product can increase the contact area with the inclusions, the holes left in the product skeleton after the polyurethane burns out make the product's strength need to be further enhanced to be suitable for the field of large-flux molten steel purification.
[0008] It can be seen that the dense skeletal surface structure of the magnesia ceramic filter prepared by using fused or dead-burned magnesia as raw material will seriously lead to poor adsorption capacity for small-sized inclusions, and due to the large thermal expansion of magnesia The coefficient reduces the thermal shock stability of the filter, causing the filter to be easily damaged; the magnesia filter prepared by using porous magnesia fine powder containing micro-nanopores as raw material, the porous structure of the porous magnesia raw material can buffer part of the heat Stress can improve the thermal shock stability of the product, and at the same time, the porous structure of the skeleton surface of the product can improve the filtering effect on inclusions, but the strength of the product needs to be further improved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0052] Step 1. Preparation of Porous Magnesium Oxide Particles

[0053] Step 1.1. Put the magnesite particles into the medium temperature furnace, first heat up to 650~800°C at a rate of 2~6°C / min, and keep the temperature for 2.5~4.5h; then heat up to 1150~1150°C at a rate of 2.2~4.6°C / min 1350 ℃, heat preservation for 2 to 7 hours, and cooling to obtain porous magnesium oxide agglomerates.

[0054] Step 1.2, according to the mass ratio of the porous magnesium oxide agglomerate:aluminum sol is 100:(24~32), first put the porous magnesium oxide agglomerate into the vacuum mixer, evacuate to 2~3kPa, and then add The aluminum sol is stirred for 15 to 30 minutes, and the vacuum system is closed to obtain a mixture.

[0055] Step 1.3, drying the mixture at 110-120°C for 18-36h, then placing it in a high-temperature furnace, heating up to 1650-1750°C at a rate of 3-5°C / min, maintaining the temperature for 3-7h, and cooling, Porous magnesium oxide particles are obtained.

[0056] ...

Embodiment 1

[0083] A silicon carbide whisker reinforced porous magnesia-carbon ceramic filter and a preparation method thereof. The preparation method of the present embodiment is:

[0084] Step 1. Preparation of Porous Magnesium Oxide Particles

[0085] Step 1.1. Put the magnesite particles into a medium-temperature furnace, first heat up to 650°C at a rate of 2°C / min, and keep for 2.5 hours; then heat up to 1150°C at a rate of 2.2°C / min, hold for 2 hours, and cool to obtain porous Magnesium oxide agglomerates.

[0086] Step 1.2, according to the mass ratio of the porous magnesium oxide agglomerate:aluminum sol is 100:24, first put the porous magnesium oxide agglomerate into a vacuum mixer, evacuate to 2kPa, then add the aluminum sol, stir After 15 min, the vacuum system was turned off to obtain a mixture.

[0087] Step 1.3: The mixture was dried at 110°C for 18h, then placed in a high-temperature furnace, heated to 1650°C at a rate of 3°C / min, maintained for 3h, and cooled to obtain po...

Embodiment 2

[0110] A silicon carbide whisker reinforced porous magnesia-carbon ceramic filter and a preparation method thereof. The preparation method of the present embodiment is:

[0111] Step 1. Preparation of Porous Magnesium Oxide Particles

[0112] Step 1.1. Put the magnesite particles into a medium-temperature furnace, first heat up to 700°C at a rate of 3°C / min, and hold for 3 hours; then heat up to 1200°C at a rate of 2.5°C / min, hold for 3.5 hours, and cool to obtain porous Magnesium oxide agglomerates.

[0113] Step 1.2, according to the mass ratio of the porous magnesium oxide agglomerate:aluminum sol is 100:26, first put the porous magnesium oxide agglomerate into a vacuum mixer, evacuate to 2.4kPa, and then add the aluminum sol, After stirring for 20 min, the vacuum system was turned off to obtain a mixture.

[0114] Step 1.3: The mixture was dried at 120°C for 25h, then placed in a high-temperature furnace, heated to 1680°C at a rate of 4°C / min, kept for 5h, and cooled to...

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PUM

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Abstract

The invention relates to a silicon carbide whisker reinforced porous magnesium oxide-carbon ceramic filter and a preparation method thereof. According to the technical scheme, the preparation method comprises the steps of with modified porous magnesium fine powder, modified coal tar pitch powder, monatomic silicon powder and sodium carboxymethyl cellulose as raw materials, adding a water reducing agent, a defoaming agent, aluminum sol and deionized water, and conducting stirring to obtain ceramic slurry with thixotropy; immersing the pretreated polyurethane foam into ceramic slurry with thixotropy, taking out the immersed polyurethane foam, conducting extruding, curing and drying, and carrying out heat preservation under the conditions of carbon burying and 1150-1250 DEG C, and conducting cooling; and immersing the cooled porous magnesium oxide-carbon ceramic filter presintered body in ceramic slurry with thixotropy, carrying out vacuum standing, carrying out centrifugal treatment, conducting drying, carrying out heat preservation at 1400-1500 DEG C under a carbon burying condition, and conducting cooling to prepare the silicon carbide whisker reinforced porous magnesium oxide-carbon ceramic filter. The prepared product is excellent in filtering effect, high in strength and good in thermal shock resistance.

Description

technical field [0001] The invention belongs to the technical field of porous magnesia-carbon ceramic filters. In particular, it relates to a porous magnesia-carbon ceramic filter reinforced by silicon carbide whiskers and a preparation method thereof. Background technique [0002] Non-metallic oxide inclusions in molten metal (steel liquid, magnesium melt and magnesium alloy melt, etc.) seriously affect the quality of metal materials and endanger the properties of metal materials. How to reduce the content of non-metallic oxide inclusions in molten metal , improving the quality of metal materials has become an urgent problem to be solved in the field of high-quality metal material manufacturing. [0003] Using a porous ceramic filter with a three-dimensional mesh structure to filter out non-metallic inclusions in molten metal is an important way to effectively purify molten metal and improve the quality of metal materials. At the same time, porous ceramic filters are used ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/80C04B38/06C04B35/04C04B35/622C04B35/66B01D39/20
CPCC04B38/0615C04B35/04C04B35/622B01D39/2093C04B2235/422C04B2235/428C04B2235/5276C04B2235/9607C04B35/803
Inventor 鄢文彭望定鄢俊杰陈哲梁雄李光强
Owner WUHAN UNIV OF SCI & TECH