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Electrocatalytic oxidation catalyst for landfill leachate as well as preparation method and application of electrocatalytic oxidation catalyst

A landfill leachate, electrocatalytic oxidation technology, applied in the direction of metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, chemical instruments and methods, etc., can solve the problems of a large number of chemicals and achieve fast reaction rates , stable operation, good water quality

Pending Publication Date: 2021-06-25
北京国环莱茵环保科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the use of Fenton oxidation and ozone oxidation requires a large amount of chemicals, or produces a considerable amount of by-products after treatment.

Method used

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  • Electrocatalytic oxidation catalyst for landfill leachate as well as preparation method and application of electrocatalytic oxidation catalyst

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] The preparation of the electrocatalytic oxidation catalyst for landfill leachate specifically comprises the following steps:

[0044] (1) Weigh 70% of the alumina powder, 20% of the activated carbon powder, and 10% of the gelling agent in the mass percentage, and the total mass is 100%. Mix the above powders in a cloth bag evenly, then add them to the granulator, roll until the balls have a particle size of 1mm, and the gelling agent is lime powder;

[0045] (2) Put the catalyst carrier after 1mm balling into a sealed bag in step (1) and let it stand for 12h;

[0046] (3) Calcining the catalyst carrier after standing in the step (2) in a kiln at 100°C for 3 hours;

[0047] (4) taking out the carrier after roasting in step (3) and cooling to room temperature;

[0048] (5) Copper nitrate and lanthanum nitrate are respectively prepared into solutions with a mass concentration of 8%, and mixed with ammonium nitrate to obtain a mixed solution, wherein the masses of copper ni...

Embodiment 2

[0056] A preparation of an electrocatalytic oxidation catalyst for landfill leachate specifically comprises the following steps:

[0057] (1) Weigh 60% of the alumina powder, 30% of the activated carbon powder, and 10% of the gelling agent by weight, and the total mass is 100%. Mix the above powder in a cloth bag evenly, then add it to the granulator, roll until the ball is 2 mm in size, and the gelling agent is cement;

[0058] (2) Put the catalyst carrier after 2mm balling into a sealed bag in step (1) and let it stand for 12h;

[0059] (3) Calcining the catalyst carrier after standing in the step (2) in a kiln at 105° C. for 4 hours;

[0060] (4) taking out the carrier after roasting in step (3) and cooling to room temperature;

[0061] (5) Copper nitrate and lanthanum nitrate are respectively prepared into solutions with a mass concentration of 5%, and mixed with ammonium nitrate to obtain a mixed solution, wherein the masses of copper nitrate and lanthanum nitrate are r...

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Abstract

The invention discloses an electrocatalytic oxidation catalyst for landfill leachate as well as a preparation method and application of the electrocatalytic oxidation catalyst. The electrocatalytic oxidation catalyst for the landfill leachate comprises a carrier and a metal active component, wherein the metal active component comprises copper and one or two of lanthanum or nickel; and the metal active component accounts for 1-11 wt% of the total weight of the carrier. The preparation method comprises the steps of preparing a mixed solution of metal active component salt and ammonium nitrate, dipping the carrier in the mixed solution, roasting, and carrying out nitrogen treatment to obtain the catalyst. The electrocatalytic oxidation catalyst for the landfill leachate has the advantages that the reaction rate is high, the power consumption in the reaction is greatly reduced, harmlessness and recycling can be realized by adopting an electrocatalytic oxidation process, the organic matter removal efficiency is high, the operation cost is low, and the effluent quality is good.

Description

technical field [0001] The present invention relates to the field of landfill leachate treatment, in particular to an electrocatalytic oxidation catalyst for landfill leachate and its preparation method and application. The catalyst can be used to treat landfill leachate concentrate. The present invention is a An advanced oxidation technology applied to the treatment of landfill leachate concentrate in the environmental protection industry. Background technique [0002] The landfill leachate mainly comes from the water produced by the waste itself, the water content of the covering soil layer and the rain and snow water flowing into the landfill area. The water quality is characterized by high concentration of organic pollutants, high concentration of suspended solids, high salt content, and high concentration of ammonia nitrogen. At present, the treatment of landfill leachate mainly adopts the process of "pretreatment + biological system + advanced treatment of membrane sys...

Claims

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Application Information

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IPC IPC(8): B01J23/83C02F1/461C02F1/72C02F103/06
CPCB01J23/83C02F1/4672C02F1/725C02F1/4674C02F2103/06
Inventor 骆建明伍伟曹海燕张瑞艳
Owner 北京国环莱茵环保科技股份有限公司