Aluminum alloy profile quenching additive and quenching process

A technology of aluminum alloy profiles and additives, applied in the field of quenching liquid, can solve the problems of high toxicity of diisobutyl ketone, blackening of quenching agent, strong irritation, etc., to ensure consistent quality, reduce maintenance times, and excellent flame retardancy Effect

Active Publication Date: 2021-07-09
ANHUI LANT ALUMINUM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, PAG is not a perfect quenching agent. After all, the quenching of the workpiece is an ultra-high temperature process. Although the PAG polymer itself is relatively stable, it will hardly be oxidized and decomposed under normal conditions, and will not react with acid-base substances. It is neutral itself, but during use, due to the adhesion of PAG on the surface of the workpiece, it will be taken out. On the other hand, there are PAG, air and ultra-high temperature workpieces at the interface of the workpiece contacting the quenching agent. These three Under these conditions, complex reactions will occur on the surface, and PAG will be oxidized and decomposed, especially when the workpiece is large, the loss of PAG will be more, and the oxidized PAG will cause the quenching agent to turn black, and it will become a foul smell after a long time
[0006] The prior art has improved PAG. For example, 201110334830.4 discloses the addition of stabilizers containing polysiloxane solution, diisobutyl ketone, alkenyl succinic acid-zinc naphthenate, barium sulfonate, polyethylene glycol, etc., mainly It involves the performance of the workpiece, but the patent does not involve the state of PAG itself, and the diisobutyl ketone used is highly toxic, volatile, and strongly irritating to the eyes and nose. Repeated contact will cause nausea, dizziness, and liver and kidney damage. damage
Dalian Sairui Metal Products has published a series of patent applications, adding various components to the quenching liquid, such as preservatives, defoamers, fungicides, rust inhibitors, etc., but did not pay attention to the service life of the quenching liquid
In addition, CN105132642 also discloses a function recovery agent for quenching liquid, which uses triethanolamine, monoethanolamine, N, N'-methylenedimorpholine, triazine, boric acid and other substances. On the one hand, the composition of the recovery agent is complex and large It is an organic small molecular compound. On the other hand, the patent does not test whether the quenching agent can maintain the original performance after the recovery agent is used.

Method used

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  • Aluminum alloy profile quenching additive and quenching process
  • Aluminum alloy profile quenching additive and quenching process
  • Aluminum alloy profile quenching additive and quenching process

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1D

[0022] Example 1DOPO Derivative Synthesis

[0023]

[0024] 0.12 mol of DOPO, 0.1 mol n, N, N-trimethyl - pair of vinyl chloride (upper structure), 1 l-dichloromethane, stirred backflow for 2 h, after completion of the reaction, and the reaction was completed, and the reaction was completed, the reaction was completed. Liquid, evaporatedized 650 ml of dichloromethane, cooled crystallization, filtration, vacuum drying to give a white solid, yield 98%, HPLC purity 99.2%. 1 H-NMR (D-CCL) 3 PPM): 7.42 (m, 1H), 7.2 ~ 7.3 (m, 4H), 7.11 (S, 1H), 7.06 (m, 2H), 6.98 (M, 2H), 6.8 ~ 6.9 (M, 2H), 5.2 (m, 2H), 3.13 (m, 9H), 2.6 (m, 2H), 1.6 (m, 2H).

Embodiment 2

[0026] A total of 15 parts by weight of PAG stock, 85 parts by weight of deionized water were disposed of 100 parts by weight of the quenching agent. The quenching liquid uses in the production line of the company: The profile exit temperature is controlled at 550 ° C, continuously treats 2 tons of aluminum alloy profiles, and the surface of the profile begins to be bent, the streaks, etc., the quenching liquid is black, there is a odor, there is apodoa after 2 weeks later Flavor generation.

Embodiment 3

[0028] A total of 15 parts by weight of PAG stock, 8 parts by weight of the quenching additive, 77 parts by weight of deionized water;

[0029] Among them, 100 parts by weight of the quenching additive, 40 parts by weight of the polydimethylsiloxane, 30 parts by weight of benzalkonium chloride, and 30 parts by weight, DOPO derivative;

[0030] The hardening liquid is used in the company's production line: the export temperature of the profile is controlled at 550 ° C, and the aluminum alloy profile is continuously treated. The profile is good, but it has unequality (experimenting in the quenching liquid concentration), quenching color Slightly deep, no odor, no odor production after 2 weeks; supplement PAG, water, and additives to the initial value, the profile can be stably discharged.

[0031] Example 3

[0032] 20 parts by weight of PAG stock, 8 parts by weight of the quenching additive, 72 parts by weight of deionized water;

[0033] Among them, 100 parts by weight of the quen...

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PUM

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Abstract

In order to solve the problems in the prior art, the aluminum alloy profile quenching process is provided, at least a quenching agent is not prone to blackening and stinking mainly by using a specific quenching agent additive, so that the service cycle is long, the maintenance frequency is reduced, and the quality consistency of products is guaranteed.

Description

Technical field [0001] The present invention belongs to the field of hardening liquid, and more particularly to the associated quenching process using a quenching agent additive. Background technique [0002] The quenching agent is a metal material or alloy, in particular the cooling medium used in the quenching stage of the aluminum alloy material; the commonly used quenching medium has water, oil, melted salts, air, and the like. The scope of oil quenching agent is relatively special. For aluminum alloys, it is quenching smoke every time, with severe burning, there is a large number of fires, and there will be huge losses, resulting in a pungent smell Serious environmental pollution; for aluminum alloys, the surface is not easy to clean, easy to contaminate, affect the beauty of the finished product, and additional cleaning treatment steps. Water-based quenching agent corresponding to it, the most widely used PAG quenching agent-polyane hydrated medium, polyalkylene glycol (PAG...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21D1/60
CPCC21D1/60
Inventor 雷忠平熊茂清张雄孙建
Owner ANHUI LANT ALUMINUM
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