Europium-doped ultra-wideband red fluorescent material as well as preparation method and application thereof
A red fluorescent, ultra-broadband technology, applied in the field of europium-doped ultra-broadband red fluorescent materials and its preparation, can solve the problems of difficult realization of broadband red light emission, and achieve environmental protection and pollution-free preparation process, high luminous efficiency, and low raw material price cheap effect
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[0031] One of the above Eu 2+ -Eu 3+ The preparation method of the co-existing silicate red fluorescent powder adopts a high-temperature solid-phase method, and its basic steps are as follows:
[0032] Step (1), according to general chemical formula K 3 gSi 2 o 7: The stoichiometric ratio of the corresponding elements in xEu Weigh each raw material: a compound containing potassium ions, a compound containing gadolinium ions, a compound containing silicon ions, a compound containing europium ions; wherein, 0.002≤x≤0.2, Eu means Eu 2+ and Eu 3+ Ions that coexist in two different chemical valence states;
[0033] Step (2), mixing and fully grinding the raw materials in step (1), placing them in an air atmosphere for calcination, and then naturally cooling to normal temperature;
[0034] Preferably, the calcination temperature is 600-1000°C, and the calcination time is 2-24 hours;
[0035] Step (3), after the mixture calcined in step (2) is fully ground again, placed in a r...
Embodiment 1
[0040] Embodiment 1: preparation K 3 gSi 2 o 7 :0.002Eu
[0041] According to chemical formula K 3 gSi 2 o 7 : The stoichiometric ratio of each element in 0.002Eu, weigh K respectively 2 CO 3 : 0.4146g, Gd 2 o 3 : 0.3625g, SiO 2 : 0.2400g, Eu 2 o 3 : 0.000704g, placed in an agate mortar and fully ground, placed in a crucible after being uniformly ground, and calcined in an air atmosphere at a calcination temperature of 800°C for 6 hours, and after naturally cooling to room temperature, the sample was taken out. After the calcined sample mixture was thoroughly ground again, it was calcined in a reducing atmosphere at a temperature of 1200°C for 4 hours, and then naturally cooled to room temperature to obtain the target product K 3 gSi 2 o 7 :0.002Eu.
[0042] See attached figure 1 In a, is the X-ray diffraction pattern of the phosphor powder sample prepared according to the scheme of this embodiment. The XRD test results show that the main phase of the prepared...
Embodiment 2
[0045] Embodiment 2: preparation K 3 gSi 2 o 7 :0.005Eu
[0046] According to chemical formula K 3 gSi 2 o 7 : The stoichiometric ratio of each element in 0.005Eu, weigh K respectively 2 CO 3 : 0.4146g, Gd 2 o 3 : 0.3625g, SiO 2 : 0.2400g, Eu 2 o 3 : 0.00176g, placed in an agate mortar and fully ground, placed in a crucible after being uniformly ground, and calcined in an air atmosphere at a calcination temperature of 750°C and a calcination time of 10 hours. After naturally cooling to room temperature, the sample was taken out. After the calcined sample mixture was thoroughly ground again, it was calcined in a reducing atmosphere at a temperature of 1150 ° C for 8 hours, and then naturally cooled to room temperature to obtain the target product K 3 gSi 2 o 7 :0.005Eu.
[0047] See attached figure 1 In b, is the X-ray diffraction pattern of the phosphor powder sample prepared according to the scheme of this embodiment. The XRD test results show that the main p...
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