A kind of high-efficiency halogen-free flame retardant cable material and preparation method thereof

A high-efficiency technology for flame-retardant cable materials, applied in circuits, electrical components, plastic/resin/wax insulators, etc., can solve the problem that the product structure, wire gauge size and flame retardancy cannot be satisfied at the same time, and the elongation rate cannot reach 300%. , The tensile strength of the cable material cannot be reached, etc., to achieve the effects of small influence on mechanical properties, excellent processing performance, and small addition ratio

Active Publication Date: 2022-08-02
潍坊中旭高分子材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the most widely used halogen-free flame retardants on the market are generally inorganic flame retardants such as magnesium hydroxide and aluminum hydroxide, which have the advantages of low price, abundant sources, good smoke suppression effect, and no corrosive gas and other Harmful substances and other advantages, but the addition of such flame retardants is generally 50%-70%, otherwise the flame retardant effect is poor
However, as the amount of addition increases, the mechanical properties of the product will decrease and the processing performance will be relatively poor. The tensile strength of the cable material will not reach 13.8mpa, and the elongation will not reach the requirement of 300%. Wire gauge wire can pass the VW-1 test standard, and small wire gauge wire products with a small outer diameter still cannot pass the VW-1 test standard, and cannot meet the requirements of product structure, wire gauge size and flame retardancy at the same time

Method used

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  • A kind of high-efficiency halogen-free flame retardant cable material and preparation method thereof
  • A kind of high-efficiency halogen-free flame retardant cable material and preparation method thereof
  • A kind of high-efficiency halogen-free flame retardant cable material and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0037] The diethylphosphinate (poly)amino polyalkylene aluminum phosphate and the nitrogen-based compound were added to the high-speed mixer according to the ratio of Example 1 in Table 1, and after stirring evenly, the material was discharged to obtain a high-efficiency halogen-free flame retardant.

Embodiment 2

[0039] The diethylphosphinate (poly)amino polyalkylene aluminum phosphate and nitrogen-based compound were added to the high-speed mixer according to the ratio of Example 2 in Table 1, and after stirring evenly, the material was discharged to obtain a high-efficiency halogen-free flame retardant.

Embodiment 3

[0041] The diethylphosphinate (poly)amino polyalkylene aluminum phosphate and the nitrogen-based compound were added to the high-speed mixer according to the ratio of Example 3 in Table 1, and after stirring evenly, the material was discharged to obtain a high-efficiency halogen-free flame retardant.

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Abstract

The invention discloses a high-efficiency halogen-free flame-retardant cable material and a preparation method thereof. The high-efficiency halogen-free flame-retardant cable material comprises the following components in terms of mass fraction: ethylene-vinyl acetate copolymer: 15% to 30%, and polyethylene resin: 30%-50%, high-efficiency halogen-free flame retardant 30%-40%, organosilicon compound 1%-3%, anti-aging agent 2%-5%. Among them, the high-efficiency halogen-free flame retardant is composed of diethylphosphinate (poly)amino polyalkylene aluminum phosphate and nitrogen-based compounds. The high-efficiency halogen-free flame retardant used in the invention replaces the traditional aluminum hydroxide flame retardant, and has the characteristics of low filling amount and good flame retardant effect, and does not release a large amount of corrosive gas during combustion, and meets the mechanical requirements of wire and cable. performance requirements. The wire prepared with the cable material of the present invention has the properties of high temperature resistance of 150°C and low temperature of -40°C, and also has the characteristics of halogen-free environmental protection, scratch resistance and high mechanical properties, and meets the standard requirements of UL VW-1 high flame retardant performance. , the market application prospect is broad.

Description

technical field [0001] The invention relates to the technical field of irradiation cross-linked halogen-free flame-retardant XLPE materials, in particular to a high-efficiency halogen-free flame-retardant cable material that meets the UL VW-1 grade standard and a preparation method thereof. Background technique [0002] XLPE is the abbreviation of the English name of cross-linked polyethylene. Polyethylene is a linear molecular structure that is easily deformed at high temperatures. Cross-linked polyethylene is cross-linked by a cross-linking agent, and the linear structure is transformed into a network structure. The XLPE of the net-like three-dimensional structure has excellent heat resistance, strong deformation resistance, good insulation, good mechanical and strong chemical resistance. The product after adding flame retardant can effectively prevent, delay and terminate the flame when attacked by external fire source, so as to achieve the purpose of flame retardant. ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/06C08L23/08C08K5/5317C08K5/3492H01B3/44
CPCC08L23/06H01B3/441C08L2201/02C08L2201/22C08L2203/202C08L2205/03C08L23/0853C08K5/5317C08K5/34928
Inventor 张杰田仁春董敬中
Owner 潍坊中旭高分子材料有限公司
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