PET heat-sealing film coating antifogging agent, PET antifogging easy-to-uncover film and preparation method and application thereof

A technology of heat-sealing film and anti-fogging agent, which can be used in coatings, polyurea/polyurethane coatings, etc., and can solve the problems of difficult opening, large heat-sealing, and non-compliance with environmental protection requirements.

Inactive Publication Date: 2021-08-17
HAINAN SHINER IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this laminating method has the following disadvantages: 1) It is difficult to remove the film. Because the thickness of the laminating film is thicker, generally 20-70 μm, and the thickness is uneven, it is easy to cause the heat seal to be too large during use, which is not easy to open, and the thickness of the laminating film Unevenness leads to large fluctuations in heat-sealing strength, and it is easy to tear the cover film; 2) The base material of the laminating film is paper, which is relatively poor in transparency or completely opaque; 3) The same material that does not meet environmental protection requirements, because the general The boxes used to hold fresh fruits are all made of PET
However, the base material used for the coating is paper and the material of the coating is PP and the composite film is PE or CPP, which does not meet the requirements of environmental protection and unified material recycling.

Method used

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  • PET heat-sealing film coating antifogging agent, PET antifogging easy-to-uncover film and preparation method and application thereof

Examples

Experimental program
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Effect test

preparation example Construction

[0044] The invention provides a method for preparing a PET anti-fog and easy-to-remove film, comprising the following steps:

[0045] Unwind the BOPET single-sided heat-sealable film, corona-treat the heat-sealed surface, then apply the PET heat-sealable film described in the above technical solution, apply anti-fogging agent, dry, detect and rewind to obtain PET anti-fog easy Peel off the film.

[0046] The method provided by the present invention is simple and cost-effective, and the antifogging agent can be directly coated on the heat cover of the BOPET single-sided heat-sealing film; Fogs have good cold and hot anti-fog effects, and are more cost-effective.

[0047] In the present invention, the BOPET single-sided heat-sealed film roll is preferably unfolded under a tension of 50-120N. The film roll runs forward continuously through a plurality of guide rollers, and uses two identical stations to work alternately, using automatic splicing and fast Change the film to achi...

Embodiment 1

[0061] BOPET heat-sealing film is formed by three-layer melt co-extrusion, and the three-layer material is divided into upper surface layer, core layer and heat-sealing layer;

[0062] The upper surface layer is also called anti-adhesive layer, which is made of the following raw materials by weight percentage: 42% of bright polyester chips, 8% of smooth masterbatch, and 50% of anti-adhesive masterbatch;

[0063] The raw material of the core layer is bright polyester chips;

[0064] 25% terephthalic acid; 45% ethylene glycol; 25% isophthalic acid; 2.5% triethyl phosphate heat stabilizer; PC-64 phosphorus titanium chelate catalyst 2.0% and anti-blocking agent SiO 2 0.5% mixed to obtain a heat seal mix.

[0065] Dry the anti-adhesive layer material, core layer material and heat-sealing mixture separately, three-layer melt co-extrusion, cast casting, longitudinal stretching, transverse stretching, traction winding, slitting, and obtain BOPET single-sided thermal Sealing film, w...

Embodiment 2

[0071] The difference with embodiment 1 is:

[0072] Acrylic acid graft modified polyester polyol 11%; hexamethylene diisocyanate 3.6%; acetone 5%; dimethylol propionic acid 3.2%; 3-allyloxy-2-hydroxy-1-propanesulfonate Sodium acid salt 3.0%; Maleic anhydride 2.0%; Isopropanol 3.2%; Ethylene glycol 3.5%; Sodium persulfate initiator 1.0%; Dibutyltin dilaurate catalyst 1.0%; %; palm wax anti-sticking agent 2.0%; SiO 2 1.0% anti-blocking agent and 60% soft water are mixed to obtain an anti-fogging agent.

[0073] The present invention adopts haze meter and gloss meter to test the haze and the glossiness of the PET anti-fog easy-to-remove film prepared in Example 2; the haze of the PET anti-fog easy-to-remove film prepared in Example 1 is 1.25%, and the gloss is 98.9GU.

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Abstract

The invention provides a PET heat-sealing film coating antifogging agent, a PET antifogging easy-to-uncover film and a preparation method and application thereof. The antifogging agent comprises the following components in percentage by mass: 8-11% of acrylic acid grafted modified polyester polyol; 2-4 % of hexamethylene diisocyanate; 3-5% of acetone; 3-4% of dimethylolpropionic acid; 1.5-3.5% of 3-allyloxy-2-hydroxy-1-sodium propanesulfonate salt; 1.1-2.2% of maleic anhydride; 2.5%-3.5% of isopropyl alcohol; 2.0-3.5 % of ethylene glycol; 0.1-1.0 % of an initiator; 0.2%-1.2% of a catalyst; 0.3%-0.5% of a defoaming agent; 1.5-2.5 % of palm wax anti-sticking agent; 0.5%-1.0% of a SiO2 anti-sticking agent; and 60-70% of soft water. The antifogging agent adopting the components has a good antifogging effect, and also has good heat sealing strength with a PET box body, so that the effect of easy uncovering is achieved; and the environment-friendly requirement is met.

Description

technical field [0001] The invention belongs to the technical field of food box packaging, and in particular relates to a PET heat-sealing film coated with an antifogging agent, a PET antifogging easy-to-remove film, a preparation method and application thereof. Background technique [0002] At present, the high-quality packaging boxes used in fresh food packaging on the market require high transparency, easy-to-open lid, cold and hot anti-fog functions, etc. Therefore, PET film is used to heat seal PET transparent boxes. However, since PET light film and PET box are not easy to be heat-sealed and bonded, and after bonding, they need to have hot and cold anti-fog functions, which has caused many technical obstacles to product development and application. [0003] The domestic traditional food box packaging sealing for fresh food is achieved by coating or compounding the film surface and then heat sealing with the PET box. However, this laminating method has the following di...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/14C09D7/61C08G18/65C08G18/63C08G18/34C08G18/32C08G18/38C08J7/054C08J7/052C08L67/02
CPCC09D175/14C09D7/61C08G18/631C08G18/348C08G18/3206C08G18/6541C08G18/6511C08G18/288C08J7/0427C08J7/054C08J7/052C08J2367/02C08J2475/14C08K3/36Y02W30/80
Inventor 李朝辉黎坛王俊峰王恩飞
Owner HAINAN SHINER IND
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