A kind of preparation method of lithium battery separator
A lithium battery separator and diaphragm technology, which is applied in the field of preparation of lithium battery separators, can solve problems such as poor thermal stability and environmental pollution, and achieve the effects of high production efficiency, reduced production costs, and simple preparation methods
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Embodiment 1
[0021] The preparation method of the lithium battery separator of the present embodiment includes the following steps:
[0022] (1) Add the organic polymer base material into the organic solvent, the organic polymer base material is polyolefin, and then stir to fully mix the organic polymer base material in the organic solvent to obtain the first colloidal solution; the polyolefin used in this step It is polyethylene (PE), and the organic solvent adopts a mixture of polyvinylidene fluoride and N-methylpyrrolidone with a weight ratio of 1:1. In the first colloidal solution, the weight ratio of polyethylene accounts for 80%, and the weight ratio of organic solvent accounts for 20%.
[0023] (2) Add the inorganic material into the first colloidal solution, mix and stir evenly, the stirring time is 0.5h, the stirring temperature is 80°C, and the mixture is obtained by ball milling in a ball mill. The ball milling speed is 3000r / min, and the ball milling time is 20min. A mixture o...
Embodiment 2
[0030] The preparation method of the lithium battery separator of the present embodiment includes the following steps:
[0031] (1) Add the organic polymer base material into the organic solvent, the organic polymer base material is polyolefin, and then stir to fully mix the organic polymer base material in the organic solvent to obtain the first colloidal solution; the polyolefin used in this step For polypropylene, the organic solvent adopts a mixture of polyvinylidene fluoride and N-methylpyrrolidone with a weight ratio of 0.4:0.6. In the first colloidal solution, the weight ratio of polypropylene accounts for 90%, and the weight ratio of organic solvent accounts for 10%.
[0032] (2) Add the inorganic material into the first colloidal solution, mix and stir evenly, the stirring time is 1 h, the stirring temperature is 20 ℃, and the mixture is obtained by ball milling in a ball mill. A mixture of aluminum oxide, aluminum nitride, and aluminum silicate, the mass ratio of alu...
Embodiment 3
[0039] The preparation method of the lithium battery separator of the present embodiment includes the following steps:
[0040] (1) Add the organic polymer base material into the organic solvent, the organic polymer base material is polyolefin, and then stir to fully mix the organic polymer base material in the organic solvent to obtain a first colloidal solution; the polyolefin used in this step For polyimide, the organic solvent adopts a mixture of polyvinylidene fluoride and N-methylpyrrolidone with a weight ratio of 0.6:0.4. In the first colloidal solution, the weight ratio of polyimide accounts for 70%, and the weight ratio of organic solvent accounts for 70%. 30%.
[0041] (2) Add the inorganic material into the first colloidal solution, mix and stir evenly, the stirring time is 1 h, the stirring temperature is 80 °C, and the mixture is obtained by ball milling in a ball mill. The mixture of aluminum silicate and sodium silicate, the mass ratio of aluminum silicate and ...
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