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A kind of biomedical beta titanium alloy and preparation method thereof

A beta titanium alloy, biomedical technology, applied in the field of biomedical beta titanium alloy and its preparation, can solve problems such as stuck neck, and achieve the effects of less impurities, high alloy purity, good weldability and formability

Active Publication Date: 2022-04-19
GUANGDONG INST OF NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the selection and design of β-Ti functional material systems for metal 3D printing, the controllable preparation of personalized medical multifunctional materials, the research on the surface and interface of bone tissue biomaterials, systematic clinical verification and customized responses are still urgently needed to be overcome. The "stuck neck" problem

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  • A kind of biomedical beta titanium alloy and preparation method thereof
  • A kind of biomedical beta titanium alloy and preparation method thereof
  • A kind of biomedical beta titanium alloy and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] The raw material components of a biomedical β-titanium alloy are as follows in terms of mass percentage: Mo: 11.25%; Fe: 1.75%; Zr: 5.82%; Ta: 0.21%; the balance is Ti.

[0036] The preparation method is as follows:

[0037] (1) take preparation raw material, comprise Zr, Mo, Ta, Fe, Ti and very small amount of unavoidable C and Si, each component content is as shown in table 1, and each component purity is 99.2wt%; Each raw material After being melted in a crucible, it is forged into a rod with a diameter of 29.2 mm and a length of 150 mm for preparation of spherical powder.

[0038] (2) Use the plasma rotating electrode atomization method to make powder, heat it to 1700°C in a vacuum environment, obtain the molten alloy after smelting for 65 minutes, and use high-purity argon gas for spray granulation to collect alloy powder with a particle size of 12-75 μm. The key The parameters and detailed steps of the powder making process are as follows: firstly vacuum the insi...

Embodiment 2

[0041] The raw material components of a biomedical β-titanium alloy are as follows in terms of mass percentage: Mo: 9.57%; Fe: 2.35%; Zr: 7.88%; Ta: 0.46%; and the balance is Ti.

[0042] The preparation method is as follows:

[0043] (1) take preparation raw material, comprise Zr, Mo, Ta, Fe, Ti and very small amount of unavoidable C and Si, each component content is as shown in table 1, and each component purity is 99.2wt%; Each raw material After being melted in a crucible, it is forged into a rod with a diameter of 29.2 mm and a length of 150 mm for preparation of spherical powder.

[0044] (2) Use the plasma rotating electrode atomization method to make powder, heat it to 1600°C in a vacuum environment, obtain the molten alloy after smelting for 75 minutes, and use high-purity argon gas for spray granulation to collect alloy powder with a particle size of 12-75 μm. The key The parameters and detailed steps of the powder making process are as follows: firstly vacuum the i...

Embodiment 3

[0047] The raw material components of a biomedical β-titanium alloy are as follows in terms of mass percentage: Mo: 13.25%; Fe: 3.05%; Zr: 3.67%; Ta: 0.82%; the balance is Ti.

[0048] The preparation method is as follows:

[0049] (1) take preparation raw material, comprise Zr, Mo, Ta, Fe, Ti and very small amount of unavoidable C and Si, each component content is as shown in table 1, and each component purity is 99.2wt%; Each raw material After being melted in a crucible, it is forged into a rod with a diameter of 29.2 mm and a length of 150 mm for preparation of spherical powder.

[0050] (2) Use the plasma rotating electrode atomization method to make powder, heat it to 1700°C in a vacuum environment, obtain the molten alloy after smelting for 65 minutes, and use high-purity argon gas for spray granulation to collect alloy powder with a particle size of 12-75 μm. The key The parameters and detailed steps of the powder making process are as follows: firstly vacuum the insi...

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Abstract

The invention discloses a biomedical β-titanium alloy and a preparation method thereof. Its chemical composition and mass percentage are: Mo: 9.20-13.50%; Fe: 1.00-3.20%; Zr: 3.50-8.20%; Ta: 0-1.00% %; the balance is Ti. The β-titanium alloy described in the present invention is suitable for laser additive manufacturing technology, and a dense equiaxed grain structure with extremely fine grains and a small part of columnar grain structure are formed in the prepared part, which not only plays a role in fine grain strengthening, but also Greatly improve the hardness and corrosion resistance of alloy materials. The present invention also provides a method for preparing a non-toxic, low-elasticity, and wear-resistant biomedical β-titanium alloy material. The powder prepared from the above-mentioned alloy components is prepared by using laser additive manufacturing technology to prepare a corresponding high-hardness, high-strength, and durable material. A β-titanium alloy with good abrasiveness and extremely low cytotoxicity. In addition, the prepared material has good weldability and is a special metal alloy powder suitable for laser additive manufacturing.

Description

technical field [0001] The invention relates to the technical field of metal materials, in particular to a biomedical β-titanium alloy and a preparation method thereof. Background technique [0002] Medical titanium alloy has good biocompatibility and is currently the preferred material for medical implants. In recent years, metal 3D printing based on digital optical image acquisition and personalized tissue repair technology have sparked a new research boom in medical titanium alloys. However, the currently commonly used medical titanium alloy implant (Ti6Al4V ELI) has a large difference in elastic modulus from that of human bone tissue, and toxic ions are released after long-term implantation, which restricts the benign combination of titanium alloy and bone tissue and its service life. Long-term safety. Therefore, the development of new titanium alloys that are more suitable for human bone implants has become the focus and hot direction of current research and developme...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C14/00B22F1/00B22F9/14B22F10/20B33Y70/00A61L27/06A61L27/50
CPCC22C14/00B22F9/14B22F10/20B33Y70/00A61L27/06A61L27/50Y02P10/25C22C1/0458B22F10/28B22F2998/00B22F10/36B33Y10/00B33Y50/02B22F1/052B22F1/065A61L27/04A61L2430/02B22F10/25B22F1/05B22F2301/205B22F2304/10
Inventor 闫星辰常成褚清坤马文有刘敏
Owner GUANGDONG INST OF NEW MATERIALS