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Multivalent heterojunction iron-based catalyst and application thereof

An iron-based catalyst and heterojunction technology, applied in catalysts, carbon compound catalysts, physical/chemical process catalysts, etc., can solve the problems of high energy consumption, poor selectivity of low-carbon olefins, and high cost, and achieve the goal of changing the adsorption structure, improving the Conversion rate, effect of particle size reduction

Pending Publication Date: 2021-11-23
LUOYANG NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when iron-based catalysts were used, the selectivity of lower olefins in the product was poor (<58%)
Although metal oxide / zeolite composite catalysts (such as ZnO-ZrO2 / SAPO-34) have high selectivity to light olefins (~80%), but low carbon dioxide conversion (<20%)
At present, carbon dioxide hydrogenation catalysts generally have short service life, high requirements on operation and equipment, high energy consumption and high cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A polyvalent heterojunction iron-based catalyst for producing low-carbon olefins by hydrogenation of carbon dioxide, which consists of the following components in parts by mass: 60 parts of magnetite powder, 20 parts of nano-magnesium powder, 10 parts of plant ash, and quartz powder 10 servings.

[0019] The particle size of the magnetite powder is below 200 mesh.

[0020] The particle size of the magnesium powder is all below 100 nm.

[0021] A polyvalent heterojunction iron-based catalyst for preparing light olefins by hydrogenation of carbon dioxide, comprising the following preparation steps:

[0022] 1) Add the following materials in parts by mass in the ball mill tank in turn: 60 parts of magnetite powder, 20 parts of magnesium powder, 10 parts of plant ash, 10 parts of quartz powder, the mass ratio of balls and materials in the ball mill tank is 55:1 , and then replace the air in the ball mill jar with hydrogen, and after the air in the ball mill jar is complet...

Embodiment 2

[0029] A polyvalent heterojunction iron-based catalyst for producing low-carbon olefins by hydrogenation of carbon dioxide, which consists of the following components in parts by mass: 75 parts of magnetite powder, 15 parts of nano-magnesium powder, 5 parts of plant ash, and quartz powder 5 servings.

[0030] The particle size of the magnetite powder is below 200 mesh.

[0031] The particle size of the magnesium powder is all below 100 nm.

[0032] A polyvalent heterojunction iron-based catalyst for preparing light olefins by hydrogenation of carbon dioxide, comprising the following preparation steps:

[0033] 1) Add the following materials in parts by mass in the ball mill tank in turn: 75 parts of magnetite powder, 15 parts of magnesium powder, 5 parts of plant ash, 5 parts of quartz powder, the mass ratio of balls and materials in the ball mill tank is 55:1 , and then replace the air in the ball mill jar with hydrogen, and after the air in the ball mill jar is completely ...

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Abstract

The invention provides a multivalent heterojunction iron-based catalyst and application thereof, belonging to the technical field of catalyst preparation. The multivalent heterojunction iron-based catalyst is prepared from the following components in parts by mass: 60-75 parts of magnetite ore powder serving as a catalyst, 15-20 parts of nanometer magnesium powder serving as a reducing agent, 5-10 parts of plant ash serving as a hydrogenation additive and 5-10 parts of quartz powder serving as a grinding aid. The catalyst is low in raw material cost, simple in preparation method and mild in use condition. When the catalyst is used, the catalyst is pre-activated by hydrogen with a certain concentration, so the selectivity of low-carbon olefin and the conversion rate of carbon dioxide can be remarkably improved.

Description

technical field [0001] The invention belongs to the technical field of catalyst preparation, and relates to an iron-based catalyst, in particular to a multivalent state heterojunction iron-based catalyst and its application. Background technique [0002] With the continuous increase of carbon dioxide content, the global greenhouse effect becomes more and more significant. Hydrofining carbon dioxide to produce high-quality chemical products such as low-carbon olefins can not only reduce carbon dioxide emissions, but also provide solutions for the sustainable development of the chemical industry. Due to the high energy barrier of direct hydrogenation of carbon dioxide to low-carbon olefins, poor selectivity of low-carbon olefins, low added value of by-products such as methane and carbon monoxide, and poor economic benefits, high-efficiency catalysts are required. Existing hydrogenation of carbon dioxide to produce low-carbon olefins generally adopts two schemes: reverse water...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J27/232B01J23/745B01J35/02C07C1/12C10G2/00C07C11/02B01J35/00
CPCB01J27/232B01J23/745B01J23/78C10G2/50C07C1/12C10G2400/20C07C2523/745C07C2527/232B01J35/40C07C11/02Y02P30/40
Inventor 陈海鹏马宁宁王晨玮王幽娇刘晨磊申嘉淼
Owner LUOYANG NORMAL UNIV