Battery electrode pole piece and preparation method thereof, battery and terminal
A battery electrode and pole piece technology, which is applied in the direction of battery electrodes, electrode manufacturing, electrode carriers/collectors, etc., can solve the problems of increased local polarization differences of batteries, lower battery rate performance, lower charge and discharge platforms, etc., to achieve improved Cycling stability, high coating amount, effect of reducing polarization
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[0070] The embodiment of the present application also provides a method for preparing the above battery electrode sheet 100, including:
[0071] S101. Mix the electrode active material, functional microspheres, conductive agent and binder to make a slurry; the functional microspheres include a shell and a liquid wrapped in the shell, the shell includes a polymer elastomer, and the liquid includes a liquid with a boiling point of 80 Liquids within the range of ℃ to 250℃ and not containing active hydroxyl groups;
[0072] S102 , coating the slurry on the current collector, and rolling after drying to obtain the battery electrode sheet 100 .
[0073] In the embodiment of the present application, in step S101, the selection of the electrode active material, functional microspheres, conductive agent and binder is as described above, and will not be repeated here. Wherein, the electrode active material, the binder, the functional microsphere and the conductive agent are mixed accor...
Embodiment 1
[0101] Preparation of battery negative pole piece:
[0102] (1) Add the negative electrode active material, binder, functional microspheres and conductive agent into deionized water according to the mass ratio of 95.5:3.0:0.7:0.8, mix evenly and adjust the viscosity to the specification range to prepare the slurry; the negative electrode The active material is graphite, the binder includes carboxymethyl cellulose and styrene-butadiene rubber, the conductive agent is acetylene black, the functional microspheres are polyacrylonitrile-acrylate wrapped diethyl carbonate (DEC), the particle size is 8 μm, and the shell is The body thickness is 2 μm;
[0103] (2) Coat the slurry prepared above on the surface of the 8 μm copper foil current collector, control the coating speed at 3 m / min, dry in an oven to remove water, and perform cold pressing. Among them, the temperature of the first section of oven drying is 60°C, the time is 1.5min, the temperature of the second section is 70°C,...
Embodiment 2
[0109] Compared with Example 1, the difference of Example 2 is that the liquid filled inside the functional microspheres is dimethyl carbonate (DMC). The lithium ion battery adopts the battery negative electrode sheet prepared in Example 2.
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