Method for preparing amorphous film with gradient structure based on high-temperature ion irradiation

An ion irradiation, amorphous thin film technology, used in ion implantation plating, final product manufacturing, sustainable manufacturing/processing, etc. The advantages of strength are weakened, and the strength of amorphous alloys is reduced, so as to achieve the effect of unique superiority, high strength and good plastic deformation ability.

Active Publication Date: 2021-11-30
XI AN JIAOTONG UNIV
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Problems solved by technology

Although this approach can greatly improve the plastic deformation ability of amorphous alloys, there are still two unavoidable defects: first, the composition, grain size and volume fraction of the crystal phase formed in amorphous alloys are not easy to control Secondly, although the prepared amorphous / crystalline composites have better plastic deformation ability than single-phase amorphous alloys, their strength tends to decline, that is, the advantages of high strength of amorphous alloys are weakened.
This method has the same problem as the above method: while improving the plastic deformation ability of the amorphous alloy, it will lead to a decrease in the strength of the amorphous alloy

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  • Method for preparing amorphous film with gradient structure based on high-temperature ion irradiation
  • Method for preparing amorphous film with gradient structure based on high-temperature ion irradiation
  • Method for preparing amorphous film with gradient structure based on high-temperature ion irradiation

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Embodiment Construction

[0025] The present invention designs a method based on high temperature ion irradiation treatment for W 65 Ni 35 (at.%) A method for modifying the structure of the amorphous film to make it present a gradient structure of "hard on the surface and tough on the core". On the basis of the high-quality amorphous film prepared by magnetron sputtering, through the joint action of high temperature and ion irradiation, a large number of helium bubbles are injected into the sample, but the amorphous structure is still maintained, and obvious cracks appear on the surface. crystal phase. The samples with this gradient structure showed significantly better hardness and plastic deformation ability than the samples before irradiation. It specifically includes the following steps:

[0026] 1) The single-sided polished single crystal silicon (100) substrate is ultrasonically cleaned with acetone, alcohol and distilled water respectively, then dried by a hair dryer, placed on the substrate ...

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Abstract

The invention discloses a method for preparing an amorphous film with a gradient structure based on high-temperature ion irradiation. The structure is characterized in that on the basis of adopting a high-quality amorphous film plated by magnetron sputtering, high-temperature ion irradiation treatment is assisted, so that the surface of a sample is crystallized, and the interior of the sample is kept in an amorphous structure; and therefore, the high-strength and high-plasticity amorphous film with the gradient structure is prepared. The gradient amorphous thin film structure prepared by the method can be easily realized by controlling the temperature and the implantation dosage of an ion irradiation experiment, so that the possibility is provided for preparing a controllable amorphous thin film material with high mechanical property.

Description

technical field [0001] The invention belongs to the technical field of nanometer metal thin film materials, in particular to a method for preparing a high-strength, high-plastic gradient-structure amorphous film based on high-temperature ion irradiation. Background technique [0002] Amorphous alloys are different from crystalline materials in that they have the characteristics of long-range disorder and short-range order. This feature makes the strength and plastic deformation of amorphous alloys significantly different from crystalline materials. On the one hand, the strength of amorphous alloys is significantly higher than that of crystalline materials, making amorphous alloys one of the hot spots in the research and development of engineering materials. On the other hand, due to the lack of plastic deformation carriers such as dislocations in the crystal, the plastic deformation of amorphous alloys is usually concentrated in highly localized shear bands, which largely li...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C14/16C23C14/58C23C14/35C22F3/00C22C45/10
CPCC23C14/165C23C14/5826C23C14/352C22F3/00C22C45/10C22C2200/02Y02P70/50
Inventor 黄平王飞黄丽
Owner XI AN JIAOTONG UNIV
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