A synthesis method for improving the voltage drop of positive electrode material, positive electrode material and application
A synthesis method and positive electrode material technology, applied in positive electrodes, chemical instruments and methods, batteries, etc., can solve the problems of material energy density reduction, cycle performance and voltage attenuation, and achieve improved voltage drop, improved voltage drop, and voltage drop Reduced effect
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Embodiment 1
[0043] This embodiment provides a synthesis method for improving the voltage drop of the positive electrode material. The synthesis method specifically includes the following steps:
[0044] (1) Positive electrode precursor Ni 0.25 mn 0.75 (OH) 2 Mix it with nickel acetate at a mass ratio of 100:1, put it in an air atmosphere after mixing, raise the temperature to 400°C at a heating rate of 2°C / min, keep it warm for 5h, and complete one sintering to obtain the first sintered material;
[0045] (2) Lithium hydroxide and the first sintered material are fed according to the molar ratio of Li:(Ni+Mn)=1.3, and then the dopant zirconia is added, and the amount of zirconia added accounts for the total mass of lithium hydroxide and the first sintered material 2000ppm of 2000ppm; after mixing, put it in the air atmosphere, raise the temperature to 800°C at a heating rate of 2°C / min, keep it for 10h, and complete the second sintering to obtain the second sintered material;
[0046] (...
Embodiment 2
[0048] This embodiment provides a synthesis method for improving the voltage drop of the positive electrode material. The synthesis method specifically includes the following steps:
[0049] (1) Positive electrode precursor Ni 0.25 mn 0.75 (OH) 2 Mix it with nickel carbonate at a mass ratio of 50:1, put it in an air atmosphere after mixing, raise the temperature to 300°C at a heating rate of 5°C / min, keep it warm for 7h, and complete one sintering to obtain the first sintered material;
[0050] (2) Lithium hydroxide and the first sintered material are fed according to the molar ratio of Li:(Ni+Mn)=1.35, and then the dopant yttrium oxide is added, and the amount of yttrium oxide added accounts for the total mass of lithium hydroxide and the first sintered material 1500ppm; after mixing, put it in the air atmosphere, raise the temperature to 900°C at a heating rate of 1°C / min, keep it for 8h, and complete the second sintering to obtain the second sintering material;
[0051] ...
Embodiment 3
[0053] This embodiment provides a synthesis method for improving the voltage drop of the positive electrode material. The synthesis method specifically includes the following steps:
[0054] (1) Positive electrode precursor Ni 0.25 mn 0.75 (OH) 2 Mix it with nickel acetate at a mass ratio of 70:1, put it in an air atmosphere after mixing, raise the temperature to 350°C at a heating rate of 4°C / min, keep it warm for 6h, and complete one sintering to obtain the first sintered material;
[0055] (2) Lithium hydroxide and the first sintered material are fed according to the molar ratio of Li:(Ni+Mn)=1.4, and then the dopant lanthanum oxide is added, and the amount of lanthanum oxide added accounts for the total mass of lithium hydroxide and the first sintered material 1700ppm of 1700ppm; after mixing, put it in the air atmosphere, raise the temperature to 860°C at a heating rate of 2°C / min, keep it for 9h, and complete the second sintering to obtain the second sintered material;...
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