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Main gate electrode for double-sided battery imbricate assembly

A double-sided battery and busbar electrode technology, applied in the field of electrodes, can solve the problems of unsolvable technical problems, reduced open voltage, large silver consumption, etc., and achieves perfect conductive phase network contact, high conversion efficiency, and reduced fragmentation rate. Effect

Pending Publication Date: 2021-12-03
JIANGSU ZHENGNENG ELECTRONICS TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the traditional shingled component process, after the battery electrode aluminum paste, back silver, main grid, and front silver are printed and sintered, the battery is cut, and the shingled conductive adhesive is pasted on the main grid electrode using the printing process. After drying and curing, the Battery bonding; this design has the following defects: 1. Shingled conductive adhesive is used on the main grid, which consumes a lot of silver. The single consumption of the main grid is 20-30mg.
2. The thickness of the battery is 160 dimensional density, and the thickness of the conductive agent superimposed on the main grid is 20-40 μm thick, resulting in a high fragmentation rate
3. In the main grid area of ​​the battery printing, there will be minority carrier recombination after sintering, resulting in a decrease in opening voltage
[0003] The patent with the application number CN202010489313.3 discloses a silver paste for the front busbar electrode of crystalline silicon solar cells, including spherical silver powder A, spherical silver powder B, flake silver powder, glass powder, additives and adhesives; The particle size distribution of the spherical silver powder A is: D10 is 0.5-1.5 μm, D50 is 1.0-2.5 μm, and D90 is 2.0-3.0 μm; the tap density of the spherical silver powder A is 4.5-7.5g / cm3; The particle size distribution of the spherical silver powder B is: D10 is 0.1-0.5 μm, D50 is 0.3-0.8 μm, and D90 is 1.0-3.5 μm; the tap density of the spherical silver powder B is 2.0-3.5g / cm3; the sheet The particle size distribution of the silver powder is as follows: D50 is 2.0-5.0 μm; the tap density of the flake silver powder is 2.0-3.5g / cm3; although the spherical silver powder A, spherical silver powder B and The combination of flaky silver powder and glass powder can improve the conductivity and peel strength of the product, but it still cannot solve the above technical problems

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A busbar electrode for double-sided battery shingled components, including the following components by weight: 30% of flake powder, 65% of spherical powder, 2% of thermosetting acrylic resin; curing agent: 0.5% of silicone oil, 0.5% of dispersant, and Variable agent 0.1%; active solvent 2%.

[0033] A busbar electrode for a double-sided battery shingled assembly, the preparation method of the slurry used is as follows:

[0034] S1. Put flake powder, ball powder, thermosetting acrylic resin, silicone oil, dispersant, thixotropic agent and active solvent into the double planetary vacuum mixer in proportion;

[0035] Powder particle size D10 1.0μm, D50 1.4μm, D90 2.5μm specific surface area 0.7m 2 / kg, the burning loss value is 0.5%, and the tap density is 4.5g / ml.

[0036] Spherical silver powder particle size D10 0.4μm, D50 0.5μm, D90 1.1μm Specific surface area 0.9m 2 / kg, the burning loss value is 0.7%, and the tap density is 3g / ml.

[0037] The silicone oil is KF-...

Embodiment 2

[0043] A bus grid electrode for double-sided battery shingled components, including the following components by weight: 23.45% of flake powder, 66% of spherical powder, 4% of thermosetting acrylic resin, 1% of hydrogenated bisphenol F resin; curing agent: 0.75% of silicone oil 1 %, dispersant 0.4%, thixotropic agent 0.4%; active solvent 3%.

[0044] A busbar electrode for a double-sided battery shingled assembly, the preparation method of the slurry used is as follows:

[0045] S1. Put flake powder, ball powder, thermosetting acrylic resin, hydrogenated bisphenol F resin, silicone oil, dispersant, thixotropic agent and active solvent into the double planetary vacuum mixer in proportion;

[0046] Flake powder particle size D10 1.1μm, D50 1.5μm, D90 2.7μm specific surface area 0.9m 2 / kg, the burning loss value is 0.7%, and the tap density is 5.5g / ml.

[0047] Spherical silver powder particle size D10 0.5μm, D50 0.6μm, D90 1.2μm Specific surface area 1.2m 2 / kg, the burning lo...

Embodiment 3

[0054] A bus grid electrode for a double-sided battery shingled assembly, comprising the following components by weight: 20.2% of flake powder, 64% of spherical powder, 6% of thermosetting acrylic resin, 2% of hydrogenated bisphenol F resin; curing agent: 1% of silicone oil 1.5% %, dispersant 0.6%, thixotropic agent 0.7%; active solvent 4%.

[0055] A busbar electrode for a double-sided battery shingled assembly, the preparation method of the slurry used is as follows:

[0056] S1. Put flake powder, ball powder, thermosetting acrylic resin, hydrogenated bisphenol F resin, silicone oil, dispersant, thixotropic agent and active solvent into the double planetary vacuum mixer in proportion;

[0057] Powder particle size D10 1.3μm, D50 1.7μm, D90 3.0μm specific surface area 1.1m 2 / kg, the burning loss value is 0.9%, and the tap density is 6.0g / ml.

[0058] Spherical silver powder particle size D10 0.7μm, D500.8μm, D90 1.4μm specific surface area 1.4m2 / kg, burning loss value 1.0%...

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Abstract

The invention discloses a main gate electrode for a double-sided battery imbricate assembly, and relates to the field of electrodes. The main gate electrode comprises the following components in percentage by weight: 20-30% of flake powder, 60-72% of ball powder, 2-6% of thermosetting acrylic resin and 0-2% of hydrogenated bisphenol F resin, the curing agent comprises 0.5 to 1 percent of silicone oil, 0.2 to 0.6 percent of dispersing agent and 0.1 to 0.7 percent of thixotropic agent; and 2-4% of an active solvent. According to the main gate electrode for the double-sided battery imbricate assembly, the cost of the assembly battery can be reduced, the fragmentation rate of the imbricate assembly is reduced. Meanwhile, minority carrier recombination does not exist in the main gate area of the battery, and the conversion efficiency of the battery is improved.

Description

technical field [0001] The invention belongs to the field of electrodes, and in particular relates to a main grid electrode for a double-sided battery shingled assembly. Background technique [0002] In the traditional shingled component process, after the battery electrode aluminum paste, back silver, main grid, and front silver are printed and sintered, the battery is cut, and the shingled conductive adhesive is pasted on the main grid electrode using the printing process. After drying and curing, the Battery bonding; this design has the following defects: 1. The shingled conductive adhesive is used on the main grid, which consumes a lot of silver. The single consumption of the main grid is 20-30mg. 2. The thickness of the battery is 160 dimensional density, and the thickness of the conductive agent superimposed on the main grid is 20-40 μm thick, resulting in a high fragmentation rate. 3. In the main grid area of ​​the battery printing, there will be minority carrier rec...

Claims

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Application Information

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IPC IPC(8): H01B1/22H01B13/00H01L31/0224
CPCH01B1/22H01B13/00H01L31/022425H01L31/022433
Inventor 冷青松张群丰昭李鹏刘瑞鸿
Owner JIANGSU ZHENGNENG ELECTRONICS TECH CO LTD
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