Method for assisting dual wires in additive in-situ synthesis of NiTi shape memory alloy based on electron beam scanning

A technology of electron beam scanning and in-situ synthesis, which is applied in the field of additive manufacturing, can solve the problems of damage to the functional properties of NiTi alloys, low structure density, and uneven mixing of molten metals, etc., to achieve flexible and efficient preparation, high energy density, and improved The effect of uniformity

Active Publication Date: 2021-12-10
TSINGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, at present, porosity, oxidation, and uneven structure are technical problems that need to be solved urgently in the in-situ synthesis of NiTi alloy components in additive manufacturing.
Existing work has shown that it is difficult to flexibly control the Ni / Ti atomic ratio in real time with the powder-based additive process, and its parts currently have obvious pore defects, low tissue density, and poor mechanical properties; pure Ni and pure When in situ synthesis of NiTi alloy by Ti wire arc, due to the lack of effective molten pool stirring means, the molten metal is mixed unevenly inside the molten pool, resulting in uneven microstructure and structural properties that cannot meet the requirements of use; and the increase in non-vacuum conditions Due to the limited atmosphere protection ability, impurity elements such as O, C, and N can easily enter the deposition layer and form harmful phases such as oxides and carbides, which will damage the functional properties of NiTi alloys.

Method used

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  • Method for assisting dual wires in additive in-situ synthesis of NiTi shape memory alloy based on electron beam scanning
  • Method for assisting dual wires in additive in-situ synthesis of NiTi shape memory alloy based on electron beam scanning
  • Method for assisting dual wires in additive in-situ synthesis of NiTi shape memory alloy based on electron beam scanning

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] This embodiment provides a method for in-situ synthesis of NiTi shape memory alloys based on electron beam scanning-assisted twin-wire additives. It includes the following steps:

[0046] (1) Carry out three-dimensional modeling and layering of the target NiTi alloy component, plan a total of 10 layers of paths, each path is a straight line of 80mm, and adopt a reciprocating printing method, that is, the end point of the first layer is the beginning of the second layer points, and so on.

[0047] (2) Select pure Ni wire with a purity of 99.99%, and pure Ti wire with a purity of 99.5% as printing raw materials, with a diameter of 2mm and a diameter tolerance of 0.02%.

[0048] (3) A NiTi alloy plate with a Ni atomic ratio of 50.8% was selected as the additive substrate, with a size of 200 mm (length) × 25 mm (width) × 15 mm (height). The surface was polished and cleaned before printing to remove impurities, so that The surface is bright.

[0049] (4) Start the equipme...

Embodiment 2

[0056] This embodiment provides a method for in-situ synthesis of NiTi shape memory alloys based on electron beam scanning-assisted twin-wire additives. It includes the following steps:

[0057] (1) Carry out three-dimensional modeling and layering of the target NiTi alloy components, and plan a total of 15 layers of paths, each path is a straight line of 70mm, and the reciprocating printing method is adopted, that is, the end point of the first layer is the beginning of the second layer points, and so on.

[0058] (2) Select pure Ni wire with a purity of 99.99%, and pure Ti wire with a purity of 99.5% as printing raw materials, with a diameter of 1.6mm and a diameter tolerance of 0.02%.

[0059] (3) A NiTi alloy plate with a Ni atomic ratio of 50.6% was selected as the additive substrate, with a size of 150 mm (length) × 30 mm (width) × 15 mm (height). The surface was polished and cleaned before printing to remove impurities, so that The surface is bright.

[0060] (4) Sta...

Embodiment 3

[0067] This embodiment provides a method for manufacturing NiTi shape memory alloy based on electron beam scanning assisted fuse additive manufacturing. It includes the following steps:

[0068] (1) Carry out three-dimensional modeling and layering of the target NiTi alloy components, plan a total of 20 layers of paths, each path is a 60mm straight line, and adopt a reciprocating printing method, that is, the end point of the first layer is the beginning of the second layer points, and so on.

[0069] (2) Select pure Ni wire with a purity of 99.99%, and pure Ti wire with a purity of 99.99% as printing raw materials, with a diameter of 1.2mm and a diameter tolerance of 0.02%.

[0070] (3) A NiTi alloy plate with a Ni atomic ratio of 51% was selected as the additive substrate, with a size of 200 mm (length) × 25 mm (width) × 15 mm (height). The surface was polished and cleaned before printing to remove impurities, so that The surface is bright.

[0071] (4) Start the equipmen...

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Abstract

The invention provides a method for assisting dual wires in additive in-situ synthesis of a NiTi shape memory alloy based on electron beam scanning. The method comprises the following steps: determining a deposition path of a target NiTi alloy component; taking a pure Ni wire and a pure Ti wire as printing wire materials, taking a NiTi alloy plate as an additive substrate, and performing fixing; determining the spatial positions of the pure Ni wire and the pure Ti wire in a vacuum chamber; starting a vacuum pump set; setting electron beam fuse wire additive manufacturing parameters, and controlling electron beam deflection scanning; and determining the wire feeding speed of the pure Ni wire and the pure Ti wire according to the target NiTi alloy component, performing layer-by-layer printing according to the set deposition path, and obtaining the target NiTi alloy component after all layers are completed. According to the method, the NiTi alloy component which is high in purity, homogeneous, compact and excellent in performance can be flexibly and efficiently prepared according to the requirements of the components.

Description

technical field [0001] The invention belongs to the technical field of additive manufacturing, and in particular relates to a method for in-situ synthesis of NiTi shape memory alloys based on electron beam scanning-assisted twin-wire additives. Background technique [0002] As an advanced smart material, NiTi alloy has excellent shape memory effect and superelasticity, and has been widely valued and used in aerospace and biomedical fields. However, due to the poor processability of NiTi alloys, the traditional manufacturing process cannot meet the production needs of complex and customized NiTi alloy structures. Emerging frontier research areas. However, when using pre-alloyed raw materials to add materials, there are problems such as high manufacturing cost, unavoidable element burning, narrow composition range and single functional properties, which have long restricted its development. [0003] In recent years, the idea of ​​additive manufacturing in situ synthesis of N...

Claims

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Application Information

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IPC IPC(8): B22F10/20B22F10/366B22F10/50B33Y10/00B33Y70/00C22C19/03
CPCB22F10/20B22F10/366B22F10/50C22C19/03B33Y10/00B33Y70/00Y02P10/25
Inventor 常保华蒲泽都东王开明刘冠张东起
Owner TSINGHUA UNIV
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