A kind of micro-current unidirectional wet drug-carrying sustained-release fiber membrane and preparation method thereof
A technology of unidirectional moisture transfer and fiber membrane, which is applied in fiber processing, medical science, bandages, etc., can solve the problems of no sustained release effect, high cost of fiber membrane, and inability to export tissue fluid, etc., to achieve simple and easy to obtain raw materials, easy operation, Effects in simple steps
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[0026] The present invention also provides the preparation method of the micro-current unidirectional moisture-conducting drug-carrying sustained-release fiber membrane described in the above scheme, comprising the following steps:
[0027] The polyvinyl alcohol-glutaraldehyde mixed aqueous solution is electrospinned, and the obtained fiber membrane is placed in an HCl atmosphere for cross-linking to obtain a hydrophilic fiber membrane;
[0028] Electrospinning the polyvinylidene fluoride solution containing the drug, and using the hydrophilic fiber membrane for receiving, so that the drug-loaded hydrophobic fiber membrane is deposited on the surface of the hydrophilic fiber membrane to obtain the microcurrent unidirectional wet-carrying drug-loaded sustained release fibrous membrane.
[0029] In the present invention, the polyvinyl alcohol-glutaraldehyde mixed aqueous solution is electrospinned, and the obtained fiber membrane is placed in an HCl atmosphere for cross-linking ...
Embodiment 1
[0034] The glutaraldehyde-polyvinyl alcohol mixed aqueous solution was used for electrospinning. The concentration of polyvinyl alcohol in the mixed aqueous solution was 10%, and the concentration of glutaraldehyde was 1.5%. Electrospinning parameters: the spinning voltage was 15kV, and the advancing speed was 0.8ml / h, the receiving distance is 20cm, the rotation speed of the drum is 60rpm, and the spinning time is 1h. The obtained fiber membrane had a water contact angle of 0°, a fiber diameter of 224 ± 35 nm, and a fiber membrane thickness of 75 ± 15 μm.
[0035] The fiber membrane obtained by electrospinning was placed in a vacuum reactor, and the fiber membrane was cross-linked with HCl vapor for 3 hours to obtain a cross-linked polyvinyl alcohol fiber membrane (ie, a hydrophilic fiber membrane), and a cross-linked polyethylene The water contact angle of the alcohol fiber membrane is 0°, and it is insoluble in water.
[0036] The cross-linked polyvinyl alcohol fiber film ...
Embodiment 2
[0041] The glutaraldehyde-polyvinyl alcohol mixed aqueous solution was used for electrospinning. The concentration of polyvinyl alcohol in the mixed aqueous solution was 13%, and the concentration of glutaraldehyde was 1.7%. Electrospinning parameters: the spinning voltage was 18kV, and the advancing speed was 1ml / h, the receiving distance is 20cm, the rotation speed of the drum is 60rpm, and the spinning time is 1h. The water contact angle of the obtained fiber membrane was 0°, the fiber diameter was 313 ± 41 nm, and the fiber membrane thickness was 81 ± 12 μm.
[0042] The fiber membrane obtained by electrospinning was placed in a vacuum reactor, and the fiber membrane was cross-linked with HCl vapor for 3 hours to obtain a cross-linked polyvinyl alcohol fiber membrane (ie, a hydrophilic fiber membrane), and a cross-linked polyethylene The water contact angle of the alcohol fiber membrane is 0°, and it is insoluble in water.
[0043] The cross-linked polyvinyl alcohol fiber...
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