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Injection molding method for titanium alloy assembly

An injection molding and titanium alloy technology, which is applied in the field of injection molding of titanium alloy components, can solve problems such as difficult welding, increased carbon content, and difficult correction, so as to improve the connection strength and effect, enhance the interface bonding force, and reduce the difficulty of fixing. Effect

Active Publication Date: 2021-12-31
ZHEJIANG UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the high chemical activity of titanium and titanium alloys, it is easy to be polluted by oxygen, nitrogen, and hydrogen. Before welding, it is necessary to carry out surface treatment for degreasing, descaling, and deoxidizing film. The welding process needs to strictly control the concentration of air and water vapor in argon. content, welding is difficult, and the cost is high
The reasons for the difficulty of welding are: 1) The gap between oxygen and nitrogen is solid-fused in titanium, which will distort the titanium lattice and reduce the plasticity and toughness; 2) The increase of hydrogen will make the impact toughness of titanium weld metal drop sharply, and The plasticity drops a little, and the hydride will cause the brittleness of the joint; 3) When welding, the oil stain of the workpiece and the welding wire can increase the carbon content, and when the carbon content exceeds the solubility, hard and brittle TiC is formed, which is distributed in a network and is prone to cracks;
[0003] 4) The elastic modulus of titanium is about half smaller than that of steel, so the welding residual deformation is relatively large, and it is difficult to correct the deformation after welding; 5) The welded joint is prone to overheating structure, and the grains become coarse, especially for β titanium alloys. It is easy to cause a decrease in plasticity and a greater tendency to cold cracking

Method used

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  • Injection molding method for titanium alloy assembly
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  • Injection molding method for titanium alloy assembly

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The present invention comprises the following steps:

[0033] S1, TC4 titanium alloy powder and TC11 titanium alloy powder are mixed with binder to prepare TC4 titanium alloy feed and TC11 titanium alloy feed respectively; binder is selected polyoxymethylene, paraffin, polyethylene;

[0034] Wherein, the mass ratio of each component in the TC4 titanium alloy feed is: TC4 titanium alloy powder: polyoxymethylene: polyethylene: paraffin=83:14:2:1;

[0035] The mass ratio of each component in the TC11 titanium alloy feed is: TC11 titanium alloy powder: polyoxymethylene: polyethylene: paraffin wax = 83:14:2:1;

[0036] S2. Injection molding of the green body: the TC4 titanium alloy is fed into the first mold for the first injection to obtain the TC4 green body; the TC4 green body is sandblasted to improve the surface roughness to Ra 3 μm; the TC4 green body is Put it into the second mold as an insert, perform the second injection on the vertical injection machine, and quick...

Embodiment 2

[0042] The present invention comprises the following steps:

[0043] S1. Prepare TC4 titanium alloy feed and pure titanium feed by mixing TC4 titanium alloy powder and pure titanium with a binder respectively; select polyoxymethylene, paraffin, and polyethylene as the binder. When formulating the feed, adjust the ratio of the binder to the powder so that the powder loading of the TC4 feed is 60%, and the powder loading of the pure titanium feed is 58%;

[0044] Wherein, the mass ratio of each component in the TC4 titanium alloy feed is: TC4 titanium alloy powder: polyoxymethylene: polyethylene: paraffin=83:14:2:1;

[0045] The mass ratio of each component in the pure titanium feed is: pure titanium powder: polyoxymethylene: polyethylene: paraffin = 81.5:15:2.5:1;

[0046]S2. Injection molding of the green body: the TC4 titanium alloy is fed into the first mold for the first injection to obtain the TC4 green body; the TC4 green body is put into the second mold and fixed by dou...

Embodiment 3

[0051] The present invention comprises the following steps:

[0052] S1. Prepare TC4 titanium alloy feed by mixing TC4 powder and binder according to the mass ratio of 80:20. Mix pure titanium powder and binder according to the mass ratio of 80:20 to prepare pure titanium feed; mix TC4 powder, pure titanium powder and binder according to the mass ratio of 40:40:20 to prepare mixed feed. Binder selection polyoxymethylene, paraffin, polypropylene.

[0053] S2. Injection molding of the green body: the TC4 titanium alloy is fed into the first mold for the first injection to obtain the TC4 green body, the injection pressure is 110MPa, the material temperature is 188°C, and the mold temperature is 125°C;

[0054] Put the TC4 green body into the second mold, perform the second injection, quickly fill the mixed feed around the TC4 green body to form a semi-finished green body, where the injection pressure is 110MPa, the material temperature is 188°C, and the mold temperature is 125°C...

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Abstract

The invention relates to an injection molding method for a titanium alloy assembly. The injection molding method comprises the following steps that S1, multiple kinds of fed materials are prepared, wherein multiple kinds of fed materials are prepared according to the quantity of different material parts of a final product; S2, injection molding of a green body is achieved, wherein one kind of fed material is selected and is injected in a corresponding mold to obtain a primary green body, the primary green body is put into the corresponding mold to serve as an insert, another kind of corresponding fed material is selected for secondary injection to obtain a semi-finished green body, if the semi-finished green body at the moment is not a final green body piece for preparing the final product, the semi-finished green body obtained last time continues to be put into the corresponding mold to serve as an insert, and a corresponding fed material is selected to continue to be injected until the final green body piece for preparing the final product is obtained; S3, the final green body piece is degreased, and a degreased blank is obtained; and S4, the degreased blank is sintered, and the final product is obtained. According to the method, the welding process during titanium metal product connection can be replaced to a certain degree, and the connection effect between all components is outstanding.

Description

technical field [0001] The invention relates to the field of injection molding in powder forming technology, in particular to an injection molding method for titanium alloy components. Background technique [0002] Titanium metal products generally include pure titanium products and titanium alloy products. When two titanium metal products need to be connected, welding is usually used for connection. Due to the high chemical activity of titanium and titanium alloys, it is easy to be polluted by oxygen, nitrogen, and hydrogen. Before welding, it is necessary to carry out surface treatment for degreasing, descaling, and deoxidizing film. The welding process needs to strictly control the concentration of air and water vapor in argon. content, welding is difficult, and the cost is high. The reasons for the difficulty of welding are: 1) The gap between oxygen and nitrogen is solid-fused in titanium, which will distort the titanium lattice and reduce the plasticity and toughness...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22F1/00B22F3/22B22F7/06B22F7/02B22F3/10
CPCB22F3/225B22F7/06B22F7/02B22F3/1025B22F3/101
Inventor 苏绍华吴勇军黄玉辉洪子健李小宝刘永伟邬均文王明喜
Owner ZHEJIANG UNIV