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Titanium alloy surface pore-forming method, titanium alloy-plastic composite and preparation method

A titanium alloy and composite technology, applied in the coating and other directions, can solve the problems of poor pore shape and size, unfavorable composite materials, complicated processes, etc., and achieve the effects of reliable physical bonding, firm bonding and simple process.

Pending Publication Date: 2021-12-31
深圳市鑫鸿达清洗技术有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The purpose of this application is to provide a method for forming holes on the surface of titanium alloys, a titanium alloy-plastic composite and its preparation method, aiming to solve the complex process of existing methods for forming holes on the surface of titanium alloys and involving large pollution. The substance, and the shape and size of the pores are not good, which is not conducive to the problem that the plastic material forms a stable composite material with the titanium alloy through the pore structure

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  • Titanium alloy surface pore-forming method, titanium alloy-plastic composite and preparation method
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  • Titanium alloy surface pore-forming method, titanium alloy-plastic composite and preparation method

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preparation example Construction

[0067] The second aspect of the embodiment of the present application provides a method for preparing a titanium alloy-plastic composite, comprising the following steps:

[0068] S20. The molten plastic material is bonded to the surface of the hole-forming titanium alloy through an injection molding process, and solidified to obtain a titanium alloy-plastic composite; wherein, the hole-forming titanium alloy is made by the above-mentioned hole-forming method on the surface of the titanium alloy .

[0069] In the preparation method of the titanium alloy-plastic composite body provided by the second aspect of the embodiment of the present application, the molten plastic material is bonded to the surface of the titanium alloy after the pore-forming treatment of the above-mentioned embodiment through an injection molding process. The surface of the alloy has slender micropores with "small mouth and large bottom", and the wall of the micropores has a jagged shape feature. Through t...

Embodiment 1

[0086] A kind of titanium alloy-plastic composite body, its preparation comprises the steps:

[0087] ① Prepare about 1 liter of electrolyte solution containing 8% sodium chloride, 40% glycerol, 25% 1,4-butanediol and 27% water, and keep the temperature at 40°C for anode electrolytic treatment. Then prepare the alkaline solution (containing OH) that comprises 150g / L sodium hydroxide and 20g / L sodium gluconate - about 3.75mol / L), and keep the temperature at 70°C for ash removal treatment.

[0088] ② After the titanium alloy test block was degreased and cleaned, it was clamped with a titanium hanger and placed in the electrolyte of Example 1 as the anode, and the graphite plate as the cathode. The electrolysis was performed twice at a constant voltage of 20V, each time for 20 minutes. After each electrolysis, wash with water first, then soak in the alkaline solution of Example 1 for deashing for 3 minutes, and then wash with water. After the electrolysis is completed, it is ba...

Embodiment 2

[0091] A kind of titanium alloy-plastic composite body, its preparation comprises the steps:

[0092] ① Prepare about 1 liter of electrolyte solution containing 5% ferric chloride, 85% N-methylpyrrolidone and 10% water, and keep the temperature at 60°C for anode electrolysis treatment. In this embodiment, ferric chloride is not only a corrosion agent but also a corrosion inhibitor. As a corrosion agent, chloride ions can be provided to corrode titanium alloys, and as a corrosion inhibitor, Fe can be provided. 3+ Promote the passivation of titanium alloy surface, where Fe 3+ The content is 1.7%. Then prepare the alkaline solution (containing OH) that comprises 150g / L sodium hydroxide and 20g / L sodium gluconate - about 3.75mol / L), and keep the temperature at 70°C for ash removal treatment.

[0093] ② After the titanium alloy test block is degreased and cleaned, it is clamped with a titanium hanger and placed in the above electrolyte as the anode, and the graphite plate as the...

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Abstract

The invention belongs to the technical field of composite materials, and particularly relates to a titanium alloy surface pore-forming method, a titanium alloy-plastic composite and a preparation method thereof. The titanium alloy surface pore-forming method comprises the steps that anodic electrolysis treatment is conducted on the titanium alloy, the titanium alloy with holes formed is obtained, and electrolyte comprises 1-15 wt% of chloride and / or bromide, 40-90 wt% of organic solvent, 0-15 wt% of auxiliaries and the balance of water; and the organic solvent comprises one or more of polyhydric alcohols, amides, ethers, lactones, sulfones and sulfoxides. According to the titanium alloy surface pore-forming method, the process is simple, a complex pretreatment or aftertreatment process is not needed, no fluorine-containing compound is used, harm to personnel and the environment is small, long and thin micropores can be formed in the titanium alloy surface, the inner walls of the micropores are in a sawtooth shape, and a firm anchor bolt structure can be formed between the titanium alloy and a plastic material.

Description

technical field [0001] The application belongs to the technical field of composite materials, and in particular relates to a method for forming holes on the surface of a titanium alloy, a titanium alloy-plastic composite and a preparation method thereof. Background technique [0002] Making heterogeneous materials with different physical and chemical properties into composites can not only retain the respective performance characteristics of each material, but also obtain some new properties through the composite effect. Metal has the advantages of high strength, stable size, and excellent texture, while plastic has the advantages of light weight, insulation, impact resistance, chemical corrosion resistance, and small electromagnetic shielding. Making metal and plastic composite materials can not only reduce product weight, reduce cost, reduce electromagnetic shielding, but also retain the high-strength performance and excellent appearance of metal, so it is widely used in e...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25F3/08B29C45/14
CPCC25F3/08B29C45/14B29C2045/14868
Inventor 张益良莫志源郭晓军
Owner 深圳市鑫鸿达清洗技术有限公司