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Turbidity and chromaticity correction method for automatic water quality monitor

An automatic monitoring and chromaticity correction technology, applied in the measurement of color/spectral properties, material analysis by observing the influence of chemical indicators, and analysis by chemical reaction of materials, etc., to achieve high efficiency, short time-consuming, Accurate effect

Pending Publication Date: 2022-01-04
WUYI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to overcome the deficiencies of the existing turbidity and chromaticity pretreatment means for water samples, provide a turbidity and chromaticity correction method for automatic monitoring of water quality, and realize the turbidity when measuring water quality parameters by spectrophotometry Chroma correction

Method used

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  • Turbidity and chromaticity correction method for automatic water quality monitor
  • Turbidity and chromaticity correction method for automatic water quality monitor
  • Turbidity and chromaticity correction method for automatic water quality monitor

Examples

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Embodiment 1

[0024] This embodiment provides a method for correcting total nickel turbidity and chromaticity for automatic monitoring of water quality, comprising the following steps:

[0025] 1. Solution preparation

[0026] The steps of preparing nickel standard solution are as follows:

[0027] 1) Accurately weigh 0.1000g of metallic nickel (content above 99.9%), dissolve it in 10mL (1+1) nitric acid solution, heat and evaporate to near dryness, add (1+99) nitric acid solution to dissolve after cooling, and then transfer to 100mL capacity bottle, dilute to the marked line with ultrapure water to obtain 1000mg / L nickel standard stock solution.

[0028] 2) Accurately pipette 2ml of the 1000mg / L nickel standard stock solution into a 100mL volumetric flask, dilute to the marked line with ultrapure water, and shake well to obtain a nickel standard intermediate solution with a concentration of 20mg / L.

[0029] 3) Accurately pipette 0.1mL, 0.5mL, 2.5mL, 5.0mL, 12.5mL, and 25.0mL of the nicke...

Embodiment 2

[0053] This embodiment provides a method for correcting total copper turbidity and chromaticity for automatic monitoring of water quality, comprising the following steps:

[0054] 1. Solution preparation

[0055] Prepare copper standard solution steps as follows:

[0056] 1) Accurately weigh 0.2000g of metallic copper (content above 99.9%), place it in a 250mL Erlenmeyer flask, add 20.0mL ultrapure water and 10.0mL (1+1) nitric acid solution, heat and dissolve until the reaction speed slows down Heat slightly to dissolve all the copper, boil the solution to drive off nitrogen oxides, add ultrapure water to dissolve after cooling, then transfer to a 1000mL volumetric flask, dilute to the mark with ultrapure water, and you can get 200mg / L copper standard stock solution.

[0057] 2) Accurately pipette 10.0ml of the 200mg / L copper standard stock solution into a 100mL volumetric flask, dilute to the marked line with ultrapure water, and shake well to obtain a copper standard inte...

Embodiment 3

[0083] This embodiment provides a method for correcting total phosphorus turbidity and chromaticity for automatic monitoring of water quality, comprising the following steps:

[0084] 1. Solution preparation

[0085] The steps to prepare phosphorus standard solution are as follows:

[0086] 1) Accurately weigh 0.2197±0.0001g of potassium dihydrogen phosphate dried at 110°C for 2 hours and let it cool in a desiccator, add a small amount of ultrapure water to dissolve, transfer to a 100mL volumetric flask, add about 800mL of ultrapure water, 5.0mL (1+1) sulfuric acid, continue to dilute to the mark with ultrapure water, you can get 50mg / L phosphorus standard stock solution.

[0087] 2) Accurately pipette 10.0ml of the 50mg / L phosphorus standard stock solution into a 250mL volumetric flask, dilute to the mark with ultrapure water, and shake well to obtain a phosphorus standard solution with a concentration of 2mg / L.

[0088] 3) Accurately pipette 1mL, 2.0mL, 6.0mL, 10.0mL, 20.0...

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Abstract

The invention discloses a turbidity and chromaticity correction method for an automatic water quality monitor, and belongs to the technical field of water quality detection. The method comprises the following steps: during colorimetric determination of the absorbance of a water sample, firstly determining the absorbance A1 of the water sample to be detected before color development, adding a color developing agent, then determining the absorbance A2 of the water sample to be detected after the color developing agent is added, recording the volumes V1 and V2 of the water sample to be detected before and after the color developing agent is added, and correcting the absorbance before color development according to the inversely proportional relationship between the absorbance and the volume of the water sample to be detected, wherein the correction formula is A1 '= A1 * (V1 / V2); taking the difference value of A2 and A1', namely delta A = A2-A1 ' as the corrected absorbance A of the reaction system, and finally calculating the concentration of the corresponding index according to the standard curve. The turbidity and chromaticity correction is realized when the water quality parameters based on the chromogenic reaction are measured by the spectrophotometric method. The test method disclosed by the invention is simple and convenient in operation steps, and does not need to pre-treat a water sample; the test result is high in accuracy, high in efficiency and short in time consumption; the method is suitable for automatic monitoring instruments and does not increase extra cost.

Description

technical field [0001] The invention relates to a turbidity and chromaticity correction method for an automatic water quality monitor, belonging to the technical field of water quality detection. Background technique [0002] The automatic water quality monitor is an online analysis device that can automatically sample and quantitatively analyze. For example, it is widely used in the online automatic monitoring of surface water and sewage, mainly including automatic monitoring of total nitrogen, ammonia nitrogen, chemical oxygen demand, total phosphorus, heavy metals, etc. instrument. The detection of these parameters is mostly based on the color reaction between the substance to be detected and a specific chromogenic agent, and quantitative analysis is carried out by spectrophotometry. However, the actual water sample itself may have a certain degree of turbidity and chromaticity, which will greatly interfere with the accuracy of water quality detection based on spectropho...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N21/31G01N21/78
CPCG01N21/31G01N21/78
Inventor 刘长宇李必冬黄才宝阮嘉惠郏建波徐晓龙
Owner WUYI UNIV