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Carbon quantum dot/polymer dielectric composite material and preparation method and application thereof

A technology of carbon quantum dots and composite materials, which can be applied to fixed capacitor dielectrics and components of fixed capacitors, etc., can solve the problems of difficult mass production and complex core-shell structure nanowire technology, and achieves the goal of improving energy storage density and efficiency. Effect

Pending Publication Date: 2022-01-07
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, although low-content core-shell nanowires have been widely used in improving the performance of dielectric materials, the process of core-shell nanowires is complicated and difficult to mass-produce.

Method used

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  • Carbon quantum dot/polymer dielectric composite material and preparation method and application thereof
  • Carbon quantum dot/polymer dielectric composite material and preparation method and application thereof
  • Carbon quantum dot/polymer dielectric composite material and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] In Example 1, four groups of carbon quantum dots / polymer dielectric composite materials are provided, with PEI as the matrix, wherein the mass fractions of carbon quantum dots are 0.05wt%, 0.2wt%, 0.5wt%, and 1.0wt%, respectively.

[0045] The specific preparation method is:

[0046] The carbon quantum dots with an average diameter of 2.5 nm were prepared according to the mass ratio of the carbon quantum dots, respectively dispersed in N-methylpyrrolidone by ultrasound, dispersed for 10 min, and then added into PEI particles and heated at 70 °C. Stir for 12h. Finally, the solution was cast on a glass plate, dried at 80 °C for 24 h, and the glass plate was peeled off to obtain 4 groups of thin films with a thickness ranging from 11 to 16 μm, which were carbon quantum dots / polymer dielectric composites.

Embodiment 2

[0054] Carbon quantum dots with an average diameter of 2.5 nm were dispersed in ethanol solution by ultrasonic for 10 min, then melt-blended with PP at high temperature at 190 °C, and finally processed by biaxial stretching. In the electrical composite material, in the carbon quantum dots / polymer dielectric composite material, the mass fraction of carbon quantum dots is 0.2 wt %.

[0055] Figure 4 It is a photo of the carbon quantum dot / PP composite material obtained in Example 2, wherein Figure 4 (a) is a photograph of the product and Figure 4 (b) is a photograph of the biaxial stretching process. It can be seen that the sample has no obvious defects and the surface is smooth.

Embodiment 3

[0060] Carbon quantum dots with an average diameter of 2.5 nm were dispersed in N-methylpyrrolidone by ultrasound for 10 min, then PMMA particles were added and stirred at 70 °C for 12 h. Finally, the solution was cast on a glass plate, dried at 80°C for 24 hours, and the glass plate was peeled off. The obtained film was the carbon quantum dot / polymer dielectric composite material. The carbon quantum dot / polymer dielectric composite material, the carbon quantum dot / polymer dielectric composite material, The mass fraction of dots is 0.5 wt%. In the obtained composite dielectric film, the carbon quantum dots are uniformly dispersed, and the obtained dielectric film has no defects.

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Abstract

The invention discloses a carbon quantum dot / polymer dielectric composite material and a preparation method and application thereof. The dielectric composite material is composed of a polymer matrix and carbon quantum dots uniformly dispersed in the polymer matrix, and the mass fraction of the carbon quantum dots in the dielectric composite material is 0.01-10.0 wt%. The polymer in the polymer matrix is selected from at least one of PP, PMP, PS, ABS, PE, PET, PMMA, PEI, PI, PVDF, P (VDF-HFP), P (VDF-CTFE) and P (VDF-TrFE-CTFE). The preparation method comprises the following steps of ultrasonically dispersing the carbon quantum dots in a good solvent of a polymer matrix, then adding the polymer particles, stirring to obtain a mixed solution, and casting and molding the mixed solution, or ultrasonically dispersing the carbon quantum dots in an organic solvent, then melting and blending with the polymer particles to obtain a mixture, and stretching or pressing to obtain the thin film. The carbon quantum dot / polymer dielectric composite material is used for a dielectric capacitor, and the energy storage density and efficiency of the dielectric capacitor can be greatly improved.

Description

technical field [0001] The invention belongs to the technical field of preparation of polymer-based dielectric composite materials, and particularly relates to a carbon quantum dot / polymer dielectric composite material and a preparation method and application thereof. Background technique [0002] Dielectric capacitors have high power density (~10 8 W / kg), fast charge and discharge speed (<1μs) and long cycle life (~50,000 times), etc., have broad prospects in pulse power applications, such as electromagnetic guns, laser guns and electromagnetic ejection in the field of national defense and military. At the same time, it also has important application value in the civil field, such as power transmission and transformation projects (converter valve of HVDC transmission system), new energy vehicles (inverter) and 5G communication (base station power supply), etc. At present, most of the capacitors and dielectric materials for capacitors involved in high-end applications re...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G4/06
CPCH01G4/06
Inventor 张斗谢浩然罗行侯红帅纪效波
Owner CENT SOUTH UNIV