Novel high-strength phosphorus magnesium silicate cement and preparation method thereof

A magnesium phosphosilicate, high-strength technology, applied in the field of new building materials, can solve the problems of short setting and hardening time, inability to pour and form, and high price of magnesium phosphate cement, achieve good mechanical properties and water resistance, and enhance mechanical properties and resistance. Water performance, the effect of reducing production energy consumption and production costs

Active Publication Date: 2022-03-22
QINGHAI INST OF SALT LAKES OF CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the conventional preparation method of magnesium phosphate cement, the dead-burned magnesia used is obtained by secondary calcination of light-burned magnesia at a temperature above 1500°C. Due to the high energy consumption and high price of dead-burned magnesia, the large-scale promotion of magnesium phosphate cement is hindered. application
The reaction speed of magnesium phosphate cement is mainly affected by the reactivity of magnesium oxide. Because of the high reactivity of magnesium oxide calcined at low temperature, the setting and hardening time of magnesium phosphate cement is too short to be poured.

Method used

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Effect test

preparation example Construction

[0019] Another aspect of the embodiments of the present invention also provides a method for preparing a novel high-strength phospho-magnesium silicate cement, comprising: mixing a first active magnesium oxide, a second active magnesium oxide, an active silica-containing raw material, and phosphoric acid. A new type of high-strength magnesium silicate cement is prepared by mixing monohydrogen salt and basic magnesium sulfate whiskers.

[0020] In some embodiments, the preparation method specifically includes: mixing the first active magnesium oxide, the second active magnesium oxide, the raw material containing active silicon dioxide and basic magnesium sulfate whiskers to obtain mixed powder; After the mixed powder and the monohydrogen phosphate solution are mixed, the cement hardens to obtain the novel high-strength magnesium phosphosilicate cement.

[0021] In some more specific embodiments, the preparation process of the novel high-strength magnesium phosphosilicate cement...

Embodiment 1

[0040] 50g light calcined powder magnesia was calcined at 1000 ℃ for 2 hours to obtain the first active magnesia; 50g light calcined powder magnesia and 2.5g potassium dihydrogen phosphate were mixed and ground, and calcined at 1000 ℃ for 2 hours to obtain the second active oxidation Magnesium, then two kinds of active magnesium oxide are mixed uniformly according to the mass ratio of 1:1 to obtain mixed powder. Calculated according to a certain water-cement ratio, the active magnesium oxide is mixed with 40% mass fraction of silica fume, 1 g of basic magnesium sulfate whiskers, and mixed with 50 g of potassium monohydrogen phosphate to prepare a slurry, shape, at 20 ± 3 ° C and relative humidity of 50 After curing at ±5% for 24 hours, a cement-based material, that is, a new type of high-strength magnesium phosphosilicate cement is obtained. The setting time is 92min, the compressive strength is 28.6Mpa after 1 day, 76.3Mpa after 3 days, 103Mpa after 7 days, 110.5Mpa after 28 ...

Embodiment 2

[0042] 50g light calcined powder magnesia was calcined at 1000 ℃ for 2 hours to obtain the first active magnesia; 50g light calcined powder magnesia and 2.5g potassium dihydrogen phosphate were mixed and ground, and calcined at 1000 ℃ for 2 hours to obtain the second active oxidation Magnesium, then two kinds of active magnesium oxide are mixed uniformly according to the mass ratio of 1:1 to obtain mixed powder. According to the calculation of a certain water-cement ratio, the active magnesium oxide was mixed with 40% mass fraction of silica fume, 1g of basic magnesium sulfate whiskers, and mixed with 33.3g of potassium monohydrogen phosphate to prepare a slurry, and molded at 20±3°C and relative humidity. After curing at 50±5% for 24 hours, a cement-based material, that is, a new type of high-strength magnesium phosphosilicate cement is obtained. The setting time is 115min, the compressive strength is 18.5Mpa after 1 day, 46.8Mpa after 3 days, 79.5Mpa after 7 days, 85.0Mpa af...

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Abstract

The invention discloses novel high-strength phosphorus magnesium silicate cement and a preparation method thereof. The novel high-strength magnesium phosphate silicate cement comprises first active magnesium oxide, second active magnesium oxide, a raw material containing active silicon dioxide, monohydrogen phosphate and basic magnesium sulfate whiskers, and the first active magnesium oxide is obtained by calcining a magnesium-containing raw material at 900-1000 DEG C; the second active magnesium oxide is obtained by mixing a magnesium-containing raw material with phosphate and calcining at 1000-1600 DEG C; according to the preparation method of the novel high-strength magnesium phosphate silicate cement provided by the invention, the low-temperature calcined magnesium oxide raw material is used, so that the production energy consumption and the production cost are reduced, and the problem of too fast cement setting caused by the low-temperature calcined raw material is solved. Meanwhile, the basic magnesium sulfate whisker is added, so that the mechanical property and the water resistance of the cement can be enhanced, and the prepared novel high-strength magnesium phosphosilicate cement has good mechanical property and water resistance.

Description

technical field [0001] The invention relates to a magnesium phosphate cement, in particular to a novel high-strength magnesium phosphosilicate cement and a preparation method thereof, belonging to the technical field of novel building materials. Background technique [0002] Magnesium phosphate cement is an air-hardening cementitious material, which is made of dead-burned magnesium oxide, dihydrogen phosphate and retarder in a certain proportion at room temperature. The reaction process is similar to that of Portland cement. The mechanical properties, compactness and acid and alkali corrosion resistance of magnesium phosphate cement hydration products are relatively high, which are close to those of ceramics, so they are also called "chemically bonded ceramics" or "ceramic cements". In the conventional preparation method of magnesium phosphate cement, the dead-burned magnesium oxide used is obtained from the secondary calcination of light-burned magnesium oxide at above 1500...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B12/02
CPCC04B12/02
Inventor 吴成友张慧芳戴宇吴志坚
Owner QINGHAI INST OF SALT LAKES OF CHINESE ACAD OF SCI
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