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Method for repairing arsenic-polluted soil by using zeolite-based mineral repairing material

A remediation material and soil remediation technology, applied in the field of arsenic-contaminated soil remediation, can solve problems such as environmental pollution, harm to human health, and aggravation of arsenic soil pollution, and achieve the effects of improving environmental safety, non-biological toxicity, and improving stabilization effect.

Active Publication Date: 2022-04-15
NANJING INST OF ENVIRONMENTAL SCI MINIST OF ECOLOGY & ENVIRONMENT OF THE PEOPLES REPUBLIC OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, with the advancement of industry and the application of pesticides, the pollution of arsenic to the soil is increasing, which not only pollutes the environment, but also endangers human health.
[0004]At present, there is no remediation method that can significantly stabilize arsenic-contaminated soil. Therefore, a remediation method that can significantly stabilize arsenic-contaminated soil is needed , thereby improving the environmental safety of the soil

Method used

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  • Method for repairing arsenic-polluted soil by using zeolite-based mineral repairing material
  • Method for repairing arsenic-polluted soil by using zeolite-based mineral repairing material
  • Method for repairing arsenic-polluted soil by using zeolite-based mineral repairing material

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Experimental program
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Effect test

Embodiment 1

[0033] A method for remediating arsenic-contaminated soil using zeolite-based mineral remediation materials, comprising the following steps:

[0034] S101. Preparation of zeolite-based mineral restoration materials

[0035] Included by mass percentage: 2.37% potassium oxide, 7.39% lithium oxide, 0.62% magnesium oxide, 0.037% manganese oxide, 2.36% sodium oxide, 0.021% phosphorus pentoxide, 71.76% silicon dioxide, 0.27% titanium dioxide, the balance It is zeolite composite microsphere; present embodiment is basically the same as embodiment 1, and its difference is that potassium oxide, lithium oxide, magnesium oxide, manganese oxide, sodium oxide, phosphorus pentoxide, dioxide Silicon and titanium dioxide are mixed and pressed to form mixed particles with a particle size of 2mm, and then the mixed particles are mixed with zeolite composite microspheres to obtain a zeolite-based mineral restoration material. The mixed particles made by mixing the above ratio can significantly im...

Embodiment 2

[0047] This embodiment is basically the same as Embodiment 1, except that in the step S102, the zeolite-based mineral restoration material is first mixed with sulfur iron, and then added to the arsenic-contaminated soil;

[0048] Wherein, the mixing method is: adding sulfur iron to the zeolite-based mineral restoration material drop by drop, stirring continuously during the dropping process, after the sulfur iron and the zeolite-based mineral restoration material are mixed, statically Set aside for 12 minutes; adding drop by drop and standing at low temperature can fully mix sulfur iron and zeolite-based mineral restoration materials, thereby improving the stabilization effect of sulfur iron and zeolite-based mineral restoration materials on arsenic-contaminated soil.

Embodiment 3

[0050] This embodiment is basically the same as Embodiment 1, except that in the step S103, two sets of graphite electrodes are inserted after stirring and mixing, and a DC electric field is formed in the arsenic-contaminated soil through the two sets of graphite electrodes, wherein, the The applied voltage of the above-mentioned DC electric field is 750mV; the applied voltage of the above-mentioned DC electric field can effectively improve the stabilization rate of heavy metals such as arsenic in arsenic-contaminated soil by mixed particles and zeolite composite microspheres; Applying it can effectively promote the remediation effect of arsenic-contaminated soil and improve the stabilization effect on arsenic-contaminated soil, and the application of DC electric field will not cause secondary pollution to arsenic-contaminated soil.

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Abstract

The invention discloses a method for repairing arsenic-polluted soil by using a zeolite-based mineral repairing material. The method comprises the following steps: S101, preparing the zeolite-based mineral repairing material; s102, the zeolite-based mineral repairing material and iron sulfide are added into the arsenic-polluted soil according to the mass percentage of the zeolite-based mineral repairing material accounting for 6-8% of the arsenic-polluted soil and the mass percentage of the iron sulfide accounting for 2-4% of the arsenic-polluted soil; and S103, the water content of the arsenic-polluted soil is controlled to be 40% + / -1% through deionized water, and after uniform stirring and mixing are conducted, remediation treatment of the arsenic-polluted soil is conducted. The zeolite-based mineral repairing material has a rich microporous structure and a large specific surface area, is free of biotoxicity, is a green, efficient and safe environment repairing functional material, and can significantly improve the stabilization effect on arsenic-polluted soil.

Description

technical field [0001] The invention relates to the technical field of soil remediation, in particular to an arsenic-contaminated soil remediation method using zeolite-based mineral remediation materials. Background technique [0002] There are very few soils that naturally contain high concentrations of arsenic. Generally, the content of arsenic in each kilogram of soil is about 6 mg. The soil with high arsenic content is mainly due to the arsenic in the polluted soil from the application of arsenic-containing pesticides, and the arsenic-containing wastewater from mines and factories. Emissions and the fall of arsenic-containing fly ash from coal burning and smelting. [0003] The toxicity of elemental arsenic is extremely low, and all arsenic compounds are toxic. Trivalent arsenic compounds are more toxic than other arsenic compounds. Arsenic accumulates in the soil and thus enters crop tissues. It can generally enter through water, air and food. Human body, causing harm,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K17/02B09C1/08
CPCC09K17/02B09C1/085
Inventor 李群张胜田邓绍坡靳德成王祥赵远超万金忠周艳
Owner NANJING INST OF ENVIRONMENTAL SCI MINIST OF ECOLOGY & ENVIRONMENT OF THE PEOPLES REPUBLIC OF CHINA