Polyurethane for bearing, preparation method of polyurethane and polyurethane bearing
A polyurethane prepolymer, polyurethane technology, applied in the cantilever mounted on the pivot, transportation and packaging, rolling resistance optimization, etc., can solve the problems of shortened bearing service life, collision damage between the bearing body and the thrust rod, etc. Improve friction, not easy to hydrolyze and soften, and not easy to be worn
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preparation example
[0046]S1, 50kg polycaprolactone diol, 70kg isophorone diisocyanate and 375kg tetrahydrofuran are mixed and heated to 45 ℃, and the reaction obtains a prepolymerized mixture;
[0047] S2, drop 0.1kg of dibutyltin dilaurate into the prepolymer mixture, heat to 60°C, and react at a constant temperature to obtain the prepolymer;
[0048] S3, add 6kg 1,4-butanediol to the prepolymer, and the reaction finishes to obtain a polyurethane prepolymer;
Embodiment 1
[0051] S1, the polyurethane prepolymer that 500kg above-mentioned preparation example makes, 1kg petroleum coke powder, 2kg aramid fiber, 2.5kg molybdenum trioxide and 1.5kg two chromium oxides are mixed and heated to 45 ℃, and constant temperature reaction obtains mixed material ;
[0052] S2, put 4kg MOFs into 2kg thioglycolic acid, mix evenly, dry and grind to obtain a composite protective agent, add the composite protective agent to the mixed material and mix evenly, dry and characterize, to obtain polyurethane for bearings.
Embodiment 2
[0054] S1, the polyurethane prepolymer that 550kg above-mentioned preparation example makes, 1.5kg petroleum coke powder, 3kg aramid fiber, 3kg molybdenum trioxide and 2kg two chromium oxides are mixed and heated to 45 ℃, and constant temperature reaction obtains mixed material;
[0055] S2, put 8kg MOFs into 4kg thioglycolic acid, mix evenly, dry and grind to obtain a composite protective agent, add the composite protective agent to the mixed material and mix evenly, dry and characterize, to obtain polyurethane for bearings.
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