Anticorrosion cast multi-element Cu-alloy simulating golden colour and its preparing process

A manufacturing method and copper alloy technology, applied in the field of copper-based alloys, can solve problems such as patina, inability to cast golden yellow, ion plating and electroplating are not suitable for large-scale products, etc., and achieve the effect of inhibiting corrosion

Inactive Publication Date: 2002-12-04
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the background technology, large-scale open-air copper reliefs used in cities, bronze statues displayed indoors and outdoors, and handicrafts are generally cast with brass or bronze. These two copper alloys have black oxide skin on the outside. Although they are polished and bright, they are not durable. Living in the sun, rain, acid rain, and salt spray erosion, even if they are indoors, they will change color and blacken within a few months, and finally appear patina, which cannot be cast into golden yellow. Existing handicrafts often use electricity to obtain their golden yellow. ...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] The formula is Zn25, Al6, Ni3, Mn1, Ce0.005, and the rest is Cu.

[0016] The color of the cast copper lion is 18K imitation gold, and it will not change color after being immersed in 4% NaCl aqueous solution for 2 months. The casting method is investment casting.

Embodiment 2

[0018] The formula is Zn15, Al6, Ni2, Ti0.5, Mn0.5, Fe1, Sn0.1, Ce0.1, and the rest is Cu alloy cast into a copper ring, the color is 20K imitation gold, immersed in 1%, 5%, 10 %, 20% sulfuric acid aqueous solution or 4% NaCl aqueous solution does not change color day and night. The casting method is metal mold casting.

Embodiment 3

[0020] The formula is Zn10, Al5, Ni3, Ti0.1, Sn2, Mn1, Fe1, Ce0.1, and the rest is Cu alloy poured on the outside of the steel pipe to form a copper alloy clad steel pipe structure. The color is 22K imitation gold, and the alloy cast in the same furnace Pour into round cake, change color under the same conditions of embodiment 2. Sand casting is used for copper alloy clad steel pipes, and metal casting is used for round cakes.

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PUM

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Abstract

An anticorrosion golden Cu-alloy contains Cu (60-84 wt.%), Zn (0-35 wt.%), Al (0.5-10 wt.%), Ni (0.5-1.5 wt.%), Mn (0.1-8 wt.%), Fe (0-5 wt.%), Ti (0.01-15 wt.%), Ce (0.001-5 wt.%), and Sn (0-8 wt.%)and is prepared by conventional casting. Its advantages are golden colour without decolouring, and high resistance to atmosphere corrosion, NaCl solution, and sulfuric acid solution.

Description

technical field [0001] The invention relates to a copper-based alloy, in particular to a corrosion-resistant multi-element gold imitation casting alloy with zinc as the secondary main component and a manufacturing method thereof. Background technique [0002] In the background technology, large-scale open-air copper reliefs used in cities, bronze statues displayed indoors and outdoors, and handicrafts are generally cast with brass or bronze. These two copper alloys have black oxide skin on the outside. Although they are polished and bright, they are not durable. Living in the sun, rain, acid rain, and salt spray erosion, even if they are indoors, they will change color and blacken within a few months, and finally appear patina, which cannot be cast into golden yellow. Existing handicrafts often use electricity to obtain their golden yellow. Gold plating, gilding, gold foil, ion plating titanium nitride, electroplating copper-zinc-tin ternary alloy a...

Claims

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Application Information

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IPC IPC(8): C22C9/04
Inventor 徐斌鸿
Owner ZHEJIANG UNIV
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