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Semi-synthesized olefins conversion catalyst containing modified nano aluminium oxide

A nano-scale, alumina technology, applied in physical/chemical process catalysts, molecular sieve catalysts, catalytic cracking, etc., can solve problems such as limiting the processing capacity of catalytic cracking units, gasoline selectivity decline, catalyst surface area and activity decline, etc.

Inactive Publication Date: 2003-08-27
吉林省嘉孚化学工业股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the regenerator, V on the catalyst forms vanadium pentoxide, which will cause irreversible damage to the zeolite crystal structure in the water vapor atmosphere, resulting in a decrease in the surface area and activity of the catalyst, and a decrease in gasoline selectivity
Ni on the catalyst, as a deoxidizing component, will increase the H 2 and coke, reducing the yield of high-value products such as gasoline and limiting the processing capacity of catalytic cracking units

Method used

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  • Semi-synthesized olefins conversion catalyst containing modified nano aluminium oxide

Examples

Experimental program
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Effect test

example 1

[0023] Add 65L of mixed solution of cerium chloride, zirconium chloride and magnesium chloride to 23529g, n-m alumina. The content of cerium chloride in the solution is 21.5g / l, the concentration of zirconium chloride is 12g / l, and the concentration of magnesium chloride is 142g / l. Soak for 1.5 hours , and then filtered and dried to obtain modified nano-scale alumina A, which contains 4.0% Ce, 2.0% Zr, and 1% Mg.

example 2

[0025] To 23529g n-mAl 2 o 3 Add 65L of a solution containing 42.5g / L of cerium chloride, soak for 1.5 hours, filter, dry, and roast at 400°C for 2 hours, then add 65L of a solution containing 12.8g / l of magnesium sulfate, soak for 1.5 hours, filter, drying. The resulting modified n-mAl 2 o 3 The Ce content in B is 8.0%, and the Mg content is 3.5%.

example 3

[0027] To 23529g n-mAl 2 o 3 Add 80L of a solution containing 42.5g / L of zirconium sulfate solution, soak for 1.5 hours, filter and dry, and the obtained modified nano-alumina C has a Zr content of 12%.

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Abstract

The invention is a conversion catalyzer of half-synthetical hydrocarbon, containing denaturing nano alumina. It disperses synthetic molecular screen and denaturing nano alumina containing Ce, Zr and Mg to inorganic oxide clay and natural aluminium silicate clay, mixes into serum, and makes jet-drying shaping, washing and drying to get the conversion catalyzer. It is especially applied to process heavy raw materials with Ni and V.

Description

technical field [0001] The present invention relates to petroleum hydrocarbon conversion catalyst, more specifically, the catalyst is a semi-synthetic hydrocarbon cracking catalyst containing modified nanometer alumina. Background technique [0002] The development of deep conversion of heavy oil, the increase of light oil products, and the production of clean fuels are all closely related to the performance of catalytic cracking (FCC) catalysts. [0003] FCC feedstocks contain heavy metals Ni, V, which contaminate the catalyst. In the regenerator, V on the catalyst forms vanadium pentoxide, which will cause irreversible damage to the zeolite crystal structure in the water vapor atmosphere, resulting in a decrease in the surface area and activity of the catalyst, and a decrease in gasoline selectivity. Ni on the catalyst, as a deoxidizing component, will increase the H 2 and coke, reduce the yield of high-value products such as gasoline, and limit the processing capacity o...

Claims

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Application Information

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IPC IPC(8): B01J21/04B01J29/00C10G11/05
Inventor 张汉倬王军关穆容侯晓曦
Owner 吉林省嘉孚化学工业股份有限公司
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