Nano high-molecular microsphere with conductivity and magnetism and its preparation method

A technology of nano-polymers and nano-microspheres, which is applied in the field of magnetic polymer nano-spheres and its preparation, and can solve the problems of large particle size, non-conductivity and nano-effects of magnetic polymer microspheres
CN1515629AInactive Publication Date: 2004-07-28中国科学院成都有机化学研究所

Patent Information

Authority / Receiving Office
CN · China
Current Assignee / Owner
中国科学院成都有机化学研究所
Publication Date
2004-07-28
Estimated Expiration
Not applicable · inactive patent

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Abstract

The present invention discloses a nano high-molecular microsphere with electric conductivity and magnetism and its preparation method. It belongs to the field of functional material. The structure of microsphere is core-shell type, core is formed from magnetic matter and the shell layer is composed of any kind of polyaniline, cross-linked polyaniline, polypyrrole and polythiophene and copolymer of them and other monomer with reactive funcitonal group. Its preparation method includes the following steps: firstly, in the pressure of magnetic flow body and initiator making polymerization to obtain core-shell type magnetic high-molecular nano microsphere, then making adulteration reaction to make the above-mentioned microsphere have electric conductivity.
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Description

Technical field

[0001] The invention relates to the field of functional materials, in particular to a magnetic polymer nano-microsphere and a preparation method thereof. Background technique

[0002] At present, the preparation of magnetic microspheres mainly includes embedding method and monomer polymerization method. The embedding method is to disperse magnetic particles in a polymer solution, and obtain magnetic polymer microspheres by atomization, flocculation, deposition, evaporation and other means. As described in patents US 4 495 393,1987 and US 4 672 040,1987. The preparation of magnetic microspheres by embedding method is simple, but the obtained particles have a wide particle size distribution, irregular shape, difficult to control the particle size, and some impurities such as emulsifiers are mixed in the shell. The monomer polymerization method is to add initiators, stabilizers, etc. to polymerize core / shell magnetic polymer microspheres in the presence of mag...

Claims

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