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Technological process of producing fire retardant antiflux fiber

A process method and anti-melting technology, applied in the direction of fiber chemical characteristics, fire-proof and flame-retardant filament manufacturing, single-component cellulose artificial filament, etc., can solve the problem that the quality of flame retardants cannot meet the spinning requirements, and the handle feels astringent , poor alkali resistance and other problems

Active Publication Date: 2006-10-18
潍坊欣龙生物材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] There was a climax in the research and development of flame-retardant fibers in China around 1990. Many companies, scientific research institutes and universities participated in it. SandofLame5060 flame retardants were used, but due to the high import price of flame retardants The quality of domestically produced flame retardants did not meet the requirements for spinning, so industrial production was not carried out in the end
[0008] At present, flame-retardant fibers on the market generally have two major disadvantages: dripping or generating smoke
Molten droplets and falling objects can easily cause burns and even ignite substances with low ignition points; the smoke produced is generally toxic gas, which can easily cause suffocation
The current research focus on the flame retardant modification of regenerated cellulose fibers is the use of phosphate flame retardants and silicic acid flame retardants, which meet the requirements of flame retardants such as no chlorination, low toxicity, and smoke suppression, but flame retardant The addition of additives is relatively large, generally more than 30%, which further reduces the original low fiber strength and affects the filtration performance of the mixed viscose
Flame retardant fibers produced by silicic acid flame retardants have disadvantages such as poor alkali resistance, desulfurization treatment cannot be performed during fiber post-treatment, and the produced flame retardant fibers are yellow in color, astringent in hand, and poor in practical performance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Example 1: 1.67dtex*38mm flame-retardant and anti-melt fiber

[0019] Using cellulose pulp as raw material, through the known steps of dipping, pressing, pulverizing and aging, 36Kg of alkali cellulose is obtained, and the content of methyl cellulose or alpha cellulose in the alkali cellulose is 30%.

[0020] 20KgSiO Content is 21% sodium silicate nonahydrate (Na 2 SiO 3 9H 2 O) join in 60L yellowing dissolving water and make solution, join this solution in the alkali cellulose in 36Kg yellowing, make it fully dissolve, mix through stirring, make total solid content be 11.5% (mass), sodium hydroxide Viscose with a content of 7.24% is filtered and matured to obtain spinning glue, which is spun in a coagulation acid bath with a sulfuric acid content of 110g / l, sodium sulfate 330g / l, zinc sulfate 10g / l, and a temperature of 48°C. Stretching produces 1.67dtex*38mm short fibers. After the fibers are acid-washed and washed neutral, they are cross-linked in a cross-linking...

Embodiment 2

[0022] Example 2: 3.33dtex*60mm flame-retardant and anti-melt fiber

[0023] Using cellulose pulp as raw material, through known steps of soaking, pressing, pulverizing and aging, 36Kg of alkali cellulose is obtained, and the content of methyl cellulose or alpha cellulose in the alkali cellulose is 30%.

[0024] 10KgSiO 2 Potassium silicate (K 2 SiO 3 ) was added to 30L yellowing dissolved water to make a solution, the solution was added to the alkali cellulose in 36Kg yellowing, and it was fully dissolved and mixed by stirring to obtain a total solid content of 9.35% (mass), and the sodium hydroxide content 6.26% viscose, filtered and matured to obtain spinning glue, spun in a coagulation acid bath with a sulfuric acid content of 85g / l, sodium sulfate 320g / l, zinc sulfate 15g / l, and a temperature of 40°C. 3.33dtex*60mm short fibers are produced. After the fiber is neutralized by water washing, it is cross-linked in a potassium metaaluminate cross-linking bath with a conce...

Embodiment 3

[0026] Example 3: 2.78dtex*51mm flame-retardant and anti-melt fiber

[0027] Using cellulose pulp as raw material, through known steps of soaking, pressing, pulverizing and aging, 36Kg of alkali cellulose is obtained, and the content of methyl cellulose or alpha cellulose in the alkali cellulose is 30%.

[0028] 30KgSiO Content is 21% sodium silicate nonahydrate (Na 2 SiO 3 9H 2 O) this solution is added into 70L yellowing dissolving water to make solution, joins in the alkali cellulose in 36Kg yellowing, makes total solid content and is 8.20% (mass), the viscose of sodium hydroxide content 5.24%, after filtering , matured to obtain spinning glue, spun in a coagulation acid bath with a sulfuric acid content of 120g / l, sodium sulfate 330g / l, aluminum sulfate 6g / l, and a temperature of 48°C, and produced short fibers of 2.78dtex*51mm after proper drafting . After the fiber is neutralized by water washing, it is cross-linked in a sodium metaaluminate cross-linking bath with a...

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Abstract

The present invention discloses technological process of producing fire retardant antiflux fiber. The fire retardant antiflux fiber is produced with cellulose pulp as material, and the production process includes the steps of: dipping, squeezing, crushing, ageing, sulfidizing, maturating, spinning, refining and stoving. The refining step includes washing, cross-liking and dewatering and oiling; and in the sulfidizing step, the silicon fire retardant is compounded into solution added into the alkali cellulose through stirring for dissolving and mixing to produce viscose of fire retardant fiber. The fire retardant antiflux fiber of the present invention has high fire retardant antiflux effect, high fiber strength and excellent filtering performance.

Description

technical field [0001] The invention relates to a process for producing flame-retardant and anti-melt fibers, in particular to a method for producing flame-retardant and anti-melt fibers through steps such as dipping, pressing, crushing, aging, yellowing, filtering, ripening, spinning, scouring, and drying. process method. Background technique [0002] In vehicles, public buildings, homes and offices, people are increasingly concerned about the issue of fire prevention. In order to reduce the danger of fabric fires, various countries have formulated flame-retardant standards and usage regulations for various textiles. Non-flame-retardant fabrics are limited by fabric types and places of use. Therefore, flame-retardant and anti-melt fibers have been developed rapidly. [0003] There are two main manufacturing methods for flame retardant fibers. One is the addition method (blending method), which is to add the flame retardant to the spinning dope before spinning to make flam...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F2/10D01F1/07
Inventor 逄奉建田素峰王乐军马君志邢春花娄善好刘海洋
Owner 潍坊欣龙生物材料有限公司
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