Polishing slurry and polished substrate

a technology of polishing slurry and substrate, which is applied in the direction of polishing compositions, other chemical processes, manufacturing tools, etc., can solve the problems of increasing scratches or pits on the polished surface, difficult to polish with conventional abrasive compositions at a high polishing rate, and poor processability of glass substrates, etc., to achieve high-precision surface polishing performance, small surface roughness, and high flatness

Inactive Publication Date: 2005-12-29
SHOWA DENKO KK
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0012] In view of the foregoing, a primary object of the present invention is to provide a polishing slurry which satisfies high-precision surface polishing performance and provides a polished surface with a high flatness and a small surface roughness and having minimized number of minute scratches and minute pits, while a high rate of polishing is attained.

Problems solved by technology

These glass substrates have very poor processability, and are difficult to polish with conventional abrasive composition at a high polishing rate and with good productivity.
However, the addition of different kind of sol causes an increase of scratches or pits on a polished surface and hence high surface precision cannot be attained.
The alkaline ceric oxide sol containing an organic acid with at least two carboxyl groups in the abrasive composition has a small average particle diameter in the range of 2 nm to 200 nm, and hence, the rate of polishing is low, the polishing cost is high, and it is difficult to stably produce a polished substrate with high quality.
The above-mentioned CMP polishing liquid inevitably has a low pH value because it contains ceric oxide abrasive grains, and the rate of polishing is low and the surface roughness is large.
Thus, it is impossible to satisfy both of high-precision surface polishing performance and high rate of polishing with any of the hitherto proposed polishing techniques.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0052] 4 kg of a commercially available unrefined rare earth carbonate powder (ignition loss: 55.8%) was baked in a box oven. That is, the powder was heated to 900° C. at a temperature elevation rate of 1.7° C. / minute and maintained at 900° C. for 2 hours. The elementary analysis of the baked powder revealed that the content of rare earth oxides was 99% by mass, and the content of cerium oxide was 60% by mass based on the rare earth oxides. The baked powder had a specific surface area of 10 m2 / g as measured by the BET method. 1.7 kg of the baked powder was put into 2.5 kg of pure water with stirring. Then, 68 g (4% by mass based on the baked powder) of a specific carboxylic acid-type surfactant (tradename “DEMOL EP” available from Kao Corporation) as a carboxylic acid salt (anionic surfactant), and 0.17 g (0.01% by mass based on the baked poeder) of polyoxyalkylene alkyl ether (tradename “EMULGEN MS-110” available from Kao Corporation) (nonionic surfactant) were added with stirring ...

examples 2 to 7

[0055] Polishing slurries were prepared by the same procedures as described in Example 1 except that the amounts of the carboxylic acid salt (anionic surfactant) and polyoxyalkylene alkyl ether (nonionic surfactant) were varied as shown in Table 1. All other conditions remained the same. The pH values of the slurries are shown in Table 1.

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Abstract

A polishing slurry comprising an abrasive comprising as a basic ingredient rare earth oxides containing cerium oxide, which polishing slurry further comprises an anionic surfactant and a nonionic surfactant and has a pH value of at least 11. The polishing slurry is especially suitable for polishing a glass substrate for magnetic disc, and other substrates used in electronic field.

Description

CROSS-REFERENCE TO RELATED APPLICATION [0001] This application is an application filed under 35 U.S.C. § 111(a) claiming benefit pursuant to 35 U.S.C. § 119(e)(1) of the filing date of Provisional Application 60 / 423,376 filed Nov. 4, 2003, pursuant to 35 U.S.C. § 111(b).TECHNICAL FIELD [0002] This invention relates to a polishing slurry used for precision polishing of substrates with optical and electronic applications, such as glass substrates for optical lens, optical disc, magnetic disc, plasma display, liquid crystal display, and LSI photomask. This polishing slurry exhibits excellent polishing properties, namely, has a high rate of polishing and gives a polished surface with a reduced surface roughness and not having surface defects such as scratches to any appreciable extent. [0003] The invention further relates to a process for polishing a substrate with the above-mentioned polishing slurry, a process for producing a polished substrate, and a polished substrate. BACKGROUND AR...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): B24B1/00B24D3/02C09G1/02C09K3/14H01L21/768
CPCC09K3/1463C09G1/02
Inventor SAEGUSA, HIROSHIIMAI, FUMIOITO, KATSURA
Owner SHOWA DENKO KK
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