Coated substrates

Abstract

A coated substrate, especially a glass substrate, such coated substrate having high photocatalytic activity and low visible light reflection as well as being highly abrasion resistant. Preferably, the coating is a titanium oxide coating, the photolytic activity is greater than 5×10−3 cm−1min−1, and coating side visible light reflection is 35% or lower.

Description

RELATED APPLICATION [0001] This application is a continuation application of U.S. Ser. No. 10 / 144,010, filed May 13, 2002, which is pending as of the filing date of the present application, and which is a divisional application of application Ser. No. 09 / 587,970, filed Jun. 6, 2000, and which has since issued as U.S. Pat. No. 6,840,061. U.S. Pat. No. 6,840,061 and U.S. application Ser. No. 10 / 144,010 are hereby incorporated by reference in their entirety.BACKGROUND OF THE INVENTION [0002] This invention relates to photocatalytically active coated substrates, in particular, but not exclusively, it relates to a photocatalytically active coated glass. [0003] It is known to deposit thin coatings having one or more layers, with a variety of properties, on to substrates including on to glass substrates. One property of interest is photocatalytic activity which arises by the photogeneration, in a semiconductor, of a hole-electron pair when the semiconductor is illuminated by light of a par...

AI Technical Summary

Benefits of technology

[0034] An advantage of the present invention is that the photocatalytically active titanium oxide coating is thin (contributing to the low visible reflection of the coated substrate) but the coated substrate still has excellent photocatalytic activity. Preferably, the titanium oxide coating has a thickness of 30 nm or lower, more preferably the titanium oxide coating has a thickness of 20 nm or lower and most preferably the titanium oxide coating has a thickness in the range 2 nm to about 20 nm.

[0035] The present invention is also advantageous because depositing thin titanium oxide coatings requires less precursor and the layers can be deposited in a relatively short time. A thin titanium oxide coating is also less likely to cause interference colors in reflection or transmission. However, a particular advantage is that the visible light reflection of a thin titanium oxide coating is low which is especially important when the coated substrate is coated glass. Usually the required visible light transmission of the coated glass will determine the thickness of the titanium oxide coating.

[0036] Preferably, the coated surface of the substrate has a static water contact angle of 20° or lower. Freshly prepared or cleaned glass has a hydrophilic surface (a static water contact angle of lower than about 40° indicates a hydrophilic surface), but organic contaminants rapidly adhere to the surface increasing the contact angle. A particular benefit of coated substrates (and especially coated glasses) of the present invention is that even if the coated surface is soiled, irradiation of the coated surface by UV light of the right wavelength will reduce the contact angle by reducing or destroying those contaminants. A further advantage is that water will spread out over the low contact angle surface reducing the distracting effect of droplets of water on the surface (e.g. from rain) and tending to wash away any grime or other contaminants that have not been destroyed by the photocatalytic activity of the surface. The static water contact angle is the angle subtended by the meniscus of a water droplet on a glass surface and may be determined in a known manner by measuring the diameter of a water droplet of known volume on a glass surface and calculated using an iterative procedure.

[0037] Preferably, the coated substrate has a haze of 1% or lower, which is beneficial because this allows clarity of view through a transparent coated substrate.

[0038] In preferred embodiments, the coated surface of the substrate is durable to abrasion, such that the coated surface remains photocatalytically active after it has been subjected to 300 strokes of the European standard abrasion test. Preferably, the coated surface remains photocatalytically active after it has been subjected to 500 strokes of the European standard abrasion test, and more preferably the coated surface remains photocatalytically active after it has been subjected to 1000 strokes of the European standard abrasion test.

[0039] This is advantageous because self-cleaning coated substrates of the present invention will often be used with the coated surface exposed to the outside (e.g. coated glasses with the coated surface of the glass as the outer surface of a window) where the coating is vulnerable to abrasion.

Problems solved by technology

However, a problem of relatively thick titanium oxide coatings is high visible light reflection and thus relatively low visible light transmission.

Images