Method for production and upgrading of oil

a technology of oil and oil sand, applied in the direction of hydrogen separation using liquid contact, sustainable manufacturing/processing, and well accessories, etc., can solve the problems of limited use of heavy oil (density20°, viscosity>100 cp), and extra heavy oil/bitumen (density10°, viscosity>100000 cp) to achieve the effect of maximising synergetic effects and increasing recovery and transportation of heavy oil

Inactive Publication Date: 2006-10-19
STATOIL ASA PETRO SA (NO)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0035] According to an embodiment geothermal heat is used to increase recovery and transport of the heavy or extra heavy oil.
[0036] As an alternative to traditional two-step upgrading of heavy oil (via synthetic crude), a potential advantages is seen at locations where natural gas can be made available in large quantities, to profit from large scale hydrogen production from natural gas, by upgrading / refining the heavy or extra-heavy crude oil to finished products in one step at a dedicated upgrader / refinery located so as to obtain maximum synergetic effects with the hydrogen production, which will take place so as to also obtain synergetic effects with respect to improved recovery of heavy or extra-heavy oil from the reservoir, by the use of energy such as steam in combination with by-products such as CO2 and / or N2, generated by the natural gas conversion step.

Problems solved by technology

Compared to conventional oil, the utilization of heavy oil (density100 cP) and extra heavy oil / bitumen (density100000 cP) is limited because of cost of production and upgrading.
Due to its high viscosity the primary recovery of heavy oils by conventional methods is low.
A subsequent refining of the synthetic crude is needed to produce finished products with the right quality, but this reprocessing is not very energy efficient since the synthetic crude oil has to be reheated and fractionated.
Moreover, new specification on the sulfur content in transportation fuels normally requires increased hydrotreating in the refineries, a type of processing that consumes hydrogen, thereby contributing to a hydrogen imbalance in the refineries.
The particular high content of residue in heavy oils requires particular refinery configurations to process these crudes, and the high content of metals and carbon residue / asphaltenes in the residue limits the use of catalytic processes available to upgrade the heavy ends of those heavy crudes.
Today, the change in demand pattern has created regional lack of sufficient upgrading capacity in the refining industry, the so-called bottom-of-the-barrel problem.
This, combined with limited hydrogen availability, will probably make it less attractive for conventional refineries to process heavier crudes.
Heavy oils are, due to their physical properties and particularly the high viscosity, difficult to produce and transport.
Due to its high viscosity the primary recovery of heavy oils by conventional methods is low.
Introduction of gases as mentioned above is not sufficient to produce and transport heavy oil and extra heavy oil / bitumen even if oil soluble gases like e.g. CO2 and methane will, dependent on the pressure and temperature of the mixture, reduce the viscosity somewhat.

Method used

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Examples

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example 1

Generation of Hydrogen by Steam Reforming of Natural Gas

[0040]FIG. 1 is a simplified flow diagram of a plant according to a first preferred embodiment and is based on the production of 200 000 barrels per day of Zuata Heavy (API=9) oil.

[0041] Natural gas, 115 ton per hour, is introduced into a steam reforming unit 2 via a gas line 1. Steam reforming is an endothermal reaction. The steam reforming unit comprises a conventional steam generation unit where water is heated and converted into hot steam by combustion of any suitable fuel such as natural gas, lower or higher hydrocarbons.

[0042] The natural gas from the gas line 1 and the hot steam is reacted in one or more reactors according to the following reactions:

Steam reforming CH4+H2O═CO+3H2

Water gas shift CO+H2O═CO2+H2

[0043] The product gas from the steam reformer is then sent to a shift converter (one or two step) in which CO is converted to CO2 by the water gas shift reaction, and hydrogen is then separated by means of well...

example 2

Generation of Hydrogen by Autothermal Reforming of Natural Gas

[0048]FIG. 2 illustrates a second preferred embodiment of the present invention, where hydrogen for the heavy oil upgrading and gas for injection into the reservoir is generated by autothermal reforming (ATR) of natural gas. The example is based on the same heavy oil and production volume of oil as Example 1.

[0049] Natural gas, 135 ton per hour (221.000 Sm3 per hour), is introduced through a gas line 10 and O2 (from an air separation unit) is introduced through a line 10′ into an ATR unit 11. The ATR unit 11 comprises one or more autothermal reforming reactors wherein natural gas is reformed by steam reforming combined with partial combustion. Steam reforming is, as mentioned above, an endothermal reaction and the energy required is supplied from partial combustion of a part of the natural gas in the same reactor according to the following reactions:

Steam reforming CH4+H2O═CO+3H2

Partial combustion CH4+ 3 / 2O2═CO+2H2O

[...

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Abstract

An integrated process for production and upgrading of heavy and extra-heavy crude oil, comprising (a) reforming of hydrocarbons such as natural gas to produce hydrogen, CO2 and steam (b) separating the produced hydrogen from the CO2, steam and any other gases to give a hydrogen rich fraction and a CO2 rich fraction and steam, (c) injecting the steam alone or in combination with the CO2 rich fraction into a reservoir containing heavy or extra heavy oil to increase the oil recovery, and (d) upgrading/refining of the heavy or extra heavy oil to finished products by extensive hydroprocessing, comprising several steps of hydrocracking and hydrotreating (sulfur, nitrogen and metals removal as well as hydrogenation of olefins and aromatics), using the hydrogen rich fraction.

Description

THE FIELD OF THE INVENTION [0001] The present invention relates to an enviromnental-friendly, integrated process for increased production and upgrading / refining of heavy and extra-heavy crude oil to finished products, based on extensive use of hydrogen to maximise the yield of liquid products, while cogenerating large amounts of steam, CO2 and optionally N2 produced by large-scale natural gas conversion, used for increased oil production. The finished products from upgrading / refining of heavy / extra heavy oils will be predominantly naphtha, kerosene, diesel and fuel oil, shipped separately or blended. THE BACKGROUND OF THE INVENTION [0002] Compared to conventional oil, the utilization of heavy oil (density<20° API, viscosity>100 cP) and extra heavy oil / bitumen (density<10° API, viscosity>100000 cP) is limited because of cost of production and upgrading. However, it is expected that the continued need for petroleum liquids such as transportation fuels will be met in the fu...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C10G63/02C10G57/00C01B3/38C01B3/52C01B32/50C10G45/00C10G47/00C10G49/00E21B43/16E21B43/24E21B43/243F25J3/04
CPCC01B3/382Y02C10/14C01B3/52C01B31/20C01B2203/0244C01B2203/0283C01B2203/0415C01B2203/0475C01B2203/065C01B2203/0844C01B2203/1241C01B2203/82C10G45/00C10G47/00C10G49/007E21B43/164E21B43/168E21B43/24E21B43/243F25J3/04018F25J3/04121F25J3/04521F25J3/04539F25J3/04569C01B3/386C01B32/50Y02C20/40Y02P20/10Y02P30/00Y02P90/70
Inventor OLSVIK, OLAMOLJORD, KJELL
Owner STATOIL ASA PETRO SA (NO)
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