Metal structural body-containing polymer film, method for manufacturing metal structural body-containing polymer film, and method for manufacturing patterned structural body
a technology of metal structural body and polymer film, which is applied in the direction of electrophoretic coating, transportation and packaging, synthetic resin layered products, etc., can solve the problem of small aspect ratio of the obtained patterned structural body
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example 1
[0097]1-(1) A total of 50 mL of a dichloroethane solution of chlorosulfonic acid (0.76 mL) was added to 200 mL of dichloroethane solution of 10.0 g of a commercial block copolymer (manufactured by Kuraray Co., Ltd., SEPTON SEEPS (SEPTON is a trade name registered by Kuraray Co., Ltd.)) represented by General Formula (0) and sulfonation was conducted for 2 h. The reaction solution was reprecipitated in hexane, washed, and dried to give a compound represented by General Formula (1).
[0098]1-(2) A total of 30 g of acetoxystyrene, 201 μL of dimethyl-2,6-dibromoheptanedioate, 386 μL of pentamethyldiethylenetriamine, and 265 mg of copper (I) bromide were mixed and a polymerization reaction was conducted at a temperature of 100° C. and stopped in 2.5 h. The product was diluted with chloroform, the catalyst was removed with an alumina column, and reprecipitation purification to cold methanol was performed. A total of 2.5 g of the compound obtained, 11.6 g of styrene, 232 μL of pentamethyldie...
reference example 1
[0101]The block copolymers represented by General Formulas (1)-(3) were dissolved in a solvent including methanol and tetrahydrofuran at a ratio of 8:2, the solvents were coated by a bar coating method on substrates obtained by sputtering Ti / Al on commercial slide glass, and polymer films including ion-conductive domains and non-ion-conductive domains were obtained. Phase images of the polymer films obtained under an atomic force microscope are shown in FIG. 5. FIG. 5(1) shows a polymer film formed by the block copolymer represented by General Formula (1), FIG. 5(2) shows a polymer film formed by the block copolymer represented by General Formula (2), and FIG. 5(3) shows a polymer film formed by the block copolymer represented by General Formula (3). In FIG. 5(1), relatively soft sites shown by a dark color indicate non-ion-conductive domains, and relatively hard sites represented by a light color indicate ion-conductive domains, whereas in FIGS. 5(2) and (3) relatively soft sites s...
example 2
[0103]The block copolymers represented by General Formulas (1)-(3) were dissolved in a solvent including methanol and tetrahydrofuran at a ratio of 8:2, the solvents were coated by a bar coating method on substrates obtained by sputtering Ti / Au on commercial slide glass, and polymer films including ion-conductive domains and non-ion-conductive domains were formed. Bipolar cells were then formed in which the substrate having the polymer film formed thereon was used as a working electrode (electrode surface area 0.48 cm2), and a metal wire was used as a counter electrode. Pt was used for the metal wire of the counter electrode, and a 0.05M aqueous solution of AgNO3 was used as an electrolytic solution injected into the cell.
[0104]The electrodes were connected to a potentio / galvanostat and electroplating was conducted for 20 sec at −2 V in the atmosphere at room temperature. In the electroplating, Ag was deposited on the polymer films including the block copolymers represented by Gener...
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