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Light-emitting device using group III nitride group compound semiconductor

a semiconductor and group iii technology, applied in semiconductors, solid-state devices, lasers, etc., can solve the problems of device insufficient control of driving voltage, warpage and stress in the device, and inability to obtain light with high purity and narrow emission spectrum, etc., to achieve the effect of improving device efficiency

Inactive Publication Date: 2006-08-01
TOYODA GOSEI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0012]Accordingly, in light of the above problems, an object of the present invention is to improve purity of the luminous color, lengthen the performance life of the device, and lower the driving voltage (oscillation threshold).

Problems solved by technology

However, the following problems persist in the conventional light-emitting semiconductor device.
Because of this non-uniformity of compositions, light which has colors of high purity and narrow half-width in an emission spectrum cannot be obtained.
Problem 2: By cooling after crystal growth of the semiconductor layer, heat-shrinkage may occur in the light-emitting device that causes warpage and stress to remain in the device.
Because a conventional light-emitting device (an active layer) may be affected by residual stress, the device cannot sufficiently control the driving voltage (oscillation threshold).
Additionally, because of such stress and high driving voltage, the performance life of the device decreases.
Problem 3: Especially, when a quantum well layer having a thickness less than 50 nm is laminated in a light-emitting device (an active layer), the quantum well layer, which is relatively thin, may become easily affected by the internal stress.
As a result, especially when such a thin quantum well layer is laminated in the light-emitting device (an active layer), internal stress tends to become a significant problem.

Method used

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  • Light-emitting device using group III nitride group compound semiconductor
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first embodiment

[0139]An n-type contact layer (an n+-layer of high carrier concentration) 203, an n-type cladding layer 204, and an n-type optical guide layer 205 may include virtually the same structure as the semiconductor layers in the semiconductor laser 100 of the first embodiment, or the n-type contact layer 103, the n-type cladding layer 104 and the n-type optical guide layer 105, respectively.

[0140]An active layer 206 having a multiple quantum well (MQW) structure may be formed on the n-type optical guide layer 205. The active layer 206 may be formed to comprise thirteen (13) layers by laminating approximately 5 nm in thickness of Al0.95In0.05N quantum barrier layer 2061 and about 5 nm in thickness of Al0.70In0.30N quantum well layer 2062 together alternately. In other words, the active layer 206 may include a multiple quantum well (MQW) structure comprising six (6) pairs of a quantum barrier layer 2061 and a quantum well layer 2062, or comprising 7 quantum barrier layers 2061 and 6 quantum...

second embodiment

[0163]In the second embodiment, the mismatching relaxation layer 2021 may comprise AlN. Alternatively, the mismatching relaxation layer 2021 may be made of binary compounds such as GaN and InN, ternary compounds such as AlGaN, InGaN and AlInN, and quaternary compounds such as AlGaInN. In this case, the mismatching relaxation layer may be formed at a low temperature in which a single crystal does not grow, and its thickness is preferably in a range of 100 Å to 1000 Å.

[0164]A single crystal layer formed on a mismatching relaxation layer may be made of the same material with the same or different composition ratio used to form the mismatching relaxation layer or a different material from that of the mismatching relaxation layer. In this embodiment, the single crystal layer may be made of GaN. Alternatively, the single crystal layer may be made of a ternary compound such as AlGaN, InGaN and ALInN, a quaternary compound such as AlGaInN having an arbitrary composition ratio. A growth temp...

third embodiment

[0172]FIG. 5 illustrates the third embodiment as a group III nitride group compound semiconductor laser 300.

[0173]As shown in FIG. 5, the main characteristics of the semiconductor laser 300 may be as follows:

(1) A MQW active layer 306 (comprising five layers in total, two periods of MQW structure)

[0174](1) A quantum well layer 3062 (Al1-xInxN; x≈0.20, about 5 nm in thickness)[0175](2) A quantum barrier layer 3061 (Al1-yGayN; y≈0.80, about 5 nm in thickness)

[0176]In comparison, the first embodiment may employ only one Al0.15Ga0.85N buffer layer 102 as a buffer layer. However, in this third embodiment, a crystal growth in lateral direction of a buffer layer 302, which have no insulation layer and has two layer structure, may be used to laminate group III nitride group compound semiconductor layers in sequence in the semiconductor laser 300.

[0177]In short, a second characteristic of the semiconductor laser 300 may be used to form a buffer layer 302 as follows:[0178](2) A buffer layer 3...

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Abstract

A light-emitting semiconductor device provides an active layer which comprises thirteen (13) layers that includes six (6) pairs of quantum barrier layers made of Al0.95In0.05N and quantum well layers made of Al0.70In0.30N, which are laminated together alternately. The semiconductor device may also comprise a quantum well layer having a high composition ratio of indium (In). Forming the quantum barrier layer and the quantum well layer to have a high composition ratio of indium (In) increases the lattice constant of the active layer of the semiconductor device.

Description

BACKGROUND OF THE INVENTION[0001]1. Field of the Invention[0002]The present invention relates to a light-emitting semiconductor device having a substrate, on which multiple semiconductor layers made of group III nitride group compound semiconductor may be laminated.[0003]2. Description of the Related Art[0004]FIG. 8 illustrates a sectional view of a conventional semiconductor layer 900 made of group III nitride group compound. As shown in FIG. 8, the semiconductor layer 900 has a multiple quantum well structure.[0005]In a conventional light-emitting device using group III nitride group compound semiconductor, e.g., LD and LED, quantum well layers qwn (n=1, 2) formed in the multiple quantum well 900 are made of gallium indium nitride (Ga1-xbInxbN; 0.10<xb<0.25) and quantum barrier layers qbm (m=1, 2, 3) are made of gallium nitride (GaN).[0006]Especially, in order to form a blue-light-emitting quantum well layer, composition ratio x of indium is preferably around 0.15.[0007]Uppe...

Claims

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Application Information

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IPC IPC(8): H01L29/06H01L33/32H01S5/323H01S5/343
CPCB82Y20/00H01L33/007H01S5/32341H01L33/06H01L33/32
Inventor KOIKE, MASAYOSHIYAMAZAKI, SHIROKOJIMA, AKIRA
Owner TOYODA GOSEI CO LTD