The invention relates to an environmental-friendly ecological vehicle leather process with low total volatile organic compounds (TVOC) and low odor, and belongs to the field of vehicle leather manufacturing. The environmental-friendly ecological vehicle leather process with the low TVOC and low odor is used for processing leather according to the processes such as leather blank sorting, splitting,milling, dedusting, lining-banding, prime coating, hanging and ventilating, embossing, processing a mixing layer, hanging and ventilating, top coating, and hanging and ventilating sequentially, so that the vehicle leather with the low TVOC and low odor is obtained. According to the environmental-friendly ecological vehicle leather process with the low TVOC and low odor provided by the invention,in the formula, a water-based material with the low TVOC for coating is adopted, so that the use of an organic solvent-containing cross-linking agent and an organic solvent-containing resin is avoided; in the coating engineering, the leather is ventilated and hung, so that the volatilization of the volatile organic compounds in the leather is accelerated, a leather TVOC emission test result is remarkably superior to leather produced by a conventional production process, the odor is remarkably improved, the limit value requirements of vehicle main engine plants on the volatile organic compoundsand the odor of a vehicle interior leather material can be met, a riding environment is improved, and the harm on a human body is reduced.