The invention relates to a material diversion mechanism, which is used in a material diversion system of a roller conveyer line and comprises a first conveying roller path (4), a second conveying roller path (1) and a path separation mechanism. An angle of 90 degrees is formed between the first conveying roller path (4) and the second conveying roller path (1). The path separation mechanism is arranged at the turning point of the first conveying roller path (4) and the second conveying roller path (1), is arranged under the first conveying roller path (4) and comprises a fixed seat body (11), a bearing seat body (13), a driving shaft (12), a driving sprocket (2), a driving belt pulley (3), a belt bearing body (14), a belt bearing wheel (5), connecting rods (8), a lifting cylinder (7), a tension adjusting cylinder (9) and a tension adjusting wheel (10), wherein the belt bearing body (14), the belt bearing wheel (5), the driving belt pulley (3) and a belt (6) form a belt conveyor unit, and the fixed seat body (11), the two groups of connecting rods (8) and the belt conveyor unit jointly form a parallelogram mechanism. The material diversion mechanism improves the material diversion efficiency and can protect materials against damages during diversion.