The invention discloses an aspergillus niger strain of a complex enzyme for liquor making, and belongs to the technical field of fermentation. The aspergillus niger strain is collected in China general microbiological culture collection center in July 9, 2015, and the collection number is CGMCC No.11064. Through culture medium optimization, a crude enzyme fluid obtained after 48 hours of solid fermentation contains various enzymes, wherein esterifying enzyme activity is 615.8mg.100mL<-1>, saccharifying enzyme activity is 7828.9U.g<-1>, and cellulase activity is 106.68U.g<-1>. Distilled liquid of esterified liquid obtained through enzymatic synthesis of esterifying enzymes generated from the strain has a typically rich and pure aroma of Luzhou-flavor liquor, and the content of ethyl hexanoate reaches 82.04% of the total flavor component. By the enzymes of the complex enzyme, utilization rate of starch-type substances in liquor-making raw materials, liquor yield and the content of esters in liquor bodies can be increased, liquor body flavors can be improved, high-quality liquor rate can be increased, and development of the liquor making industry can be promoted.