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Sodium calcium silicon series fire-proofing glass

A technology of fire-resistant glass, soda-calcium-silicon, applied in the field of soda-lime-silicon fireproof glass, which can solve the problems of large area weight, high production cost, and resistance to ultraviolet light.

Active Publication Date: 2008-02-06
CHINA LUOYANG FLOAT GLASS GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Salt glass or tempered ordinary sodium-lime-silicate glass cannot be used as a single piece of fireproof glass because the expansion and softening temperature is lower than 650 ° C. It can only be used as the substrate of composite fireproof glass. Not only the weight per unit area Large, inconvenient for transportation and mass production, and not resistant to ultraviolet light, poor aging performance
Low-expansion borosilicate monolithic fireproof glass is a monolithic fireproof glass formed at one time, with light weight and high softening point, but high melting temperature, and because of boron content, special glass furnace structure and special refractory materials are required for production. High cost and complex process
Domestic physical-chemical tempered single-piece fire-resistant glass usually uses ordinary soda-lime-silicon float glass. In a specific tempering furnace, chemical tempering reagents are sprayed to improve the strength of the glass itself through physical-chemical tempering. For the purpose of fire prevention, the thermal expansion coefficient and softening point of the glass itself have not changed, and it cannot pass the fire prevention time required by the international fireproof glass standard

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] The contents of the following components are expressed in weight percent.

[0035] Silica sand 62.9%, feldspar 8.91%, limestone 11.74%, dolomite 9.05%

[0036] Soda Ash 3.8%, Glauber's Salt 1.04%, Fluorite 1.2%, Zircon Sand 1.52%

[0037] K 2 CO 3 7.48% BaCO 3 6.5% SrCO 3 2.88% C 0.05%

[0038] The balance is impurities brought in by mineral raw materials or clarifiers added.

[0039]According to the composition of the glass, sandstone, dolomite, limestone, soda ash, barium salt, strontium salt, aluminum oxide, lithium salt, boric acid, zircon sand, potassium salt and appropriate proportion of glass clarifiers are used to make glass batch materials. Use Glauber's salt+C powder or NaCl+KNO as clarifier. Put a batch of blended materials into the crucible, select the feeding temperature as 1400°C, keep it at this temperature for half an hour, then raise the temperature to 1520°C and keep it for 2 hours, take it out of the furnace and pour it into rectangular piec...

Embodiment 2

[0041] The contents of the following components are expressed in weight percent.

[0042] Silica Sand 60.5% Feldspar 10.3% Limestone 10.6% Dolomite 10.5%

[0043] Soda Ash 33% Glauber's Salt 1.04% Fluorite 1.2% Zircon Sand 1.4%

[0044] K 2 CO 3 6.9% BaCO 3 5.4% SrCO 3 3.6% C 0.05%

[0045] The balance is impurities brought in by mineral raw materials or clarifiers added.

[0046] According to the composition of the glass, sandstone, dolomite, limestone, soda ash, barium salt, strontium salt, aluminum oxide, lithium salt, boric acid, zircon sand, potassium salt and appropriate proportion of glass clarifiers are used to make glass batch materials. Use Glauber's salt+C powder or NaCl+KNO as clarifier. Put a batch of blended materials into the crucible, select the feeding temperature as 1400°C, keep it at this temperature for half an hour, then raise the temperature to 1520°C and keep it for 2 hours, take it out of the furnace and pour it into rectangular pieces, and im...

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Abstract

A fire-proof Na-Si-Ca glass based on float glass contains SiO2 (67-75 Wt%), Al2O3 (1.5-4), CaO (5-10), MgO (0.5-3), R2O (3-13), ZrO2 (0.2-2.5), BaO (2-6) and SrO (1-6). Its advantages are low thermal expansibility and high softening point, fire-proofing performance and chemical stability.

Description

technical field [0001] The invention belongs to the technical field of glass production and manufacturing, and mainly relates to a soda-calcium-silicon series fireproof glass which is applicable to the production process of common float glass. Background technique [0002] The known composite fire-resistant glass is made of borosilicate glass or tempered ordinary sodium-lime-silicate glass as a substrate, which is compounded with organic or inorganic materials. The expansion and softening temperature of ordinary sodium-lime-silicate glass is generally lower than 650°C. When the fire is baked at a fire site higher than 650°C, the glass on the contact surface with the fire often shortens the fire resistance time of the composite fireproof glass due to softening and deformation. Salt glass or tempered ordinary sodium-lime-silicate glass cannot be used as a single piece of fireproof glass because the expansion and softening temperature is lower than 650 ° C. It can only be used ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C3/087
CPCC03C3/087
Inventor 王桂荣赵会峰姜宏曹华赵晓敏薛建鹏李红霞肖晶郭晓丽有学军
Owner CHINA LUOYANG FLOAT GLASS GROUP
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